204 research outputs found

    The A/A-bar distinction and movement theory

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    Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Linguistics and Philosophy, 1990.Includes bibliographical references (leaves [195]-200).by Anoop Kumar Mahajan.Ph.D

    Iodine oxide in the global marine boundary layer

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    Prados-Roman, C. ... et. al.-- 11 pages, 7 figures, 2 tables, The Supplement related to this article is available online at https://doi.org/10.5194/acp-15-583-2015-supplementEmitted mainly by the oceans, iodine is a halogen compound important for atmospheric chemistry due to its high ozone depletion potential and effect on the oxidizing capacity of the atmosphere. Here we present a comprehensive data set of iodine oxide (IO) measurements in the open marine boundary layer (MBL) made during the Malaspina 2010 circumnavigation. Results show IO mixing ratios ranging from 0.4 to 1 pmol mol-1 (30% uncertainty) and, complemented with additional field campaigns, this data set confirms through observations the ubiquitous presence of reactive iodine chemistry in the global marine environment. We use a global model with organic (CH3I, CH2ICl, CH2I2 and CH2IBr) and inorganic (HOI and I2) iodine ocean emissions to investigate the contribution of the different iodine source gases to the budget of IO in the global MBL. In agreement with previous estimates, our results indicate that, globally averaged, the abiotic precursors contribute about 75 % to the IO budget. However, this work reveals a strong geographical pattern in the contribution of organic vs. inorganic precursors to reactive iodine in the global MBL. © Author(s) 2015The Indian Institute of Tropical Meteorology is supported by the Ministry of Earth Sciences, Government of India. R. P. Fernandez would like to thank ANPCyT (PICT-PRH 2009-0063) for financial supportPeer Reviewe

    Linguistics

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    Contains table of contents for Section 4, an introduction and abstracts on eight doctoral dissertations

    Glyoxal observations in the global marine boundary layer

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    Glyoxal is an important intermediate species formed by the oxidation of common biogenic and anthropogenic volatile organic compounds such as isoprene, toluene and acetylene. Although glyoxal has been shown to play an important role in urban and forested environments, its role in the open ocean environment is still not well understood, with only a few observations showing evidence for its presence in the open ocean marine boundary layer (MBL). In this study, we report observations of glyoxal from ten field campaigns in different parts of the world's oceans. These observations together represent the largest database of glyoxal in the MBL. The measurements are made with similar instruments that have been used in the past, although the open ocean values reported here, average of about 25 pptv with an upper limit of 40 pptv, are much lower than previously reported observations that were consistently higher than 40 pptv and had an upper limit of 140 pptv, highlighting the uncertainties in the Differential Optical Absorption Spectroscopy (DOAS) method for the retrieval of glyoxal. Despite retrieval uncertainties, the results reported in this work support previous suggestions that the currently known sources of glyoxal are insufficient to explain the average MBL concentrations. This suggests that there is an additional missing source, more than a magnitude larger than currently known sources, which is necessary to account for the observed atmospheric levels of glyoxal. Therefore it could play a more important role in the MBL than previously considered

    Editorial: The Marine Iodine Cycle, Past, Present, and Future

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    In this Research Topic, we bring together ten articles from the diverse research communities interested in the marine iodine cycle, including paleoceanographers, atmospheric chemists, and biogeochemists. The physical chemistry underpinning iodine’s chemical speciation and transformations in the ocean is reviewed by Luther; this paper provides a theoretical basis for the field observations presented in this Research Topic

    High Plasma Glucagon Levels Correlate with Waist-to-Hip Ratio, Suprailiac Skinfold Thickness, and Deep Subcutaneous Abdominal and Intraperitoneal Adipose Tissue Depots in Nonobese Asian Indian Males with Type 2 Diabetes in North India

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    We aimed to correlate plasma glucagon levels with anthropometric measures and abdominal adipose tissue depots. Nonobese males (n=81; BMI < 25 kg/m2) with T2DM of less than one-year duration and nonobese males without diabetes (n=30) were evaluated for the following: anthropometry (BMI, waist circumference, W-HR, and truncal skinfolds), whole-body DEXA (for body fat and fat-free mass), and MRI scan (for volumes of subcutaneous abdominal adipose tissue (SCAT) including superficial and deep, intra-abdominal visceral adipose tissue (including intraperitoneal adipose tissue (IPAT), retroperitoneal adipose tissue, liver span and fatty liver, and pancreatic volume)). Plasma glucose and glucagon, serum insulin, hepatic transaminases, and lipid profile were measured. Significantly higher levels of fasting and postprandial glucagon (p<0.001) and fasting and postprandial insulin (p<0.001) were seen in patients with T2DM. The mean values of fasting and postprandial plasma glucagon levels were higher in T2DM patients with NAFLD (n=37) as compared to T2DM patients without NAFLD (n=44). Four independent predictors were derived for fasting glucagon levels in patients with T2DM, namely, W-HR, suprailiac skinfold thickness, IPAT, and deep SCAT (p<0.05; r2=0.84). These observations in Asian Indians may have significance for diabetes therapies which impact glucagon levels

    Global analysis of the controls on seawater dimethylsulfide spatial variability

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    Dimethylsulfide (DMS) emitted from the ocean makes a significant global contribution to natural marine aerosol and cloud condensation nuclei, and therefore our planet&rsquo;s climate. Oceanic DMS concentrations show large spatiotemporal variability, but observations are sparse, so products describing global DMS distribution rely on interpolation or modelling. Understanding the mechanisms driving DMS variability, especially at local scales, is required to reduce uncertainty in large scale DMS estimates. We present a study of mesoscale and sub-mesoscale (&lt;100 km) seawater DMS variability that takes advantage of the recent expansion in high frequency seawater DMS observations and uses all available data to investigate the typical distances over which DMS varies in all major ocean basins. These DMS spatial variability lengthscales (VLS) are uncorrelated with DMS concentrations. DMS concentrations and VLS can therefore be used separately to help identify mechanisms underpinning DMS variability. When data are grouped by sampling campaigns, almost 80 % of the DMS VLS can be explained using the VLS of sea surface height anomalies, density, and chlorophyll-a. Our global analysis suggests that both physical and biogeochemical processes play an equally important role in controlling DMS variability, in contrast with previous results based on data from the low&ndash;mid latitudes. The explanatory power of sea surface height anomalies indicates the importance of mesoscale eddies in driving DMS variability, previously unrecognised at a global scale and in agreement with recent regional studies. DMS VLS differs regionally, including surprisingly high frequency variability in low latitude waters. Our results independently confirm that relationships used in the literature to parameterise DMS at large scales appear to be considering the right variables. However, contrasts in regional DMS VLS highlight that important driving mechanisms remain elusive. The role of sub-mesoscale features should be resolved or accounted for in DMS process models and parameterisations. Future attempts to map DMS distributions should consider the length scale of variability.</p

    Editorial: The marine iodine cycle, past, present and future

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    In this Research Topic, we bring together ten articles from the diverse research communities interested in the marine iodine cycle, including paleoceanographers, atmospheric chemists, and biogeochemists. The physical chemistry underpinning iodine’s chemical speciation and transformations in the ocean is reviewed by Luther; this paper provides a theoretical basis for the field observations presented in this Research Topic
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