Contact-line pinning controls how quickly colloidal particles equilibrate with liquid interfaces

Previous experiments have shown that spherical colloidal particles relax to equilibrium slowly after they adsorb to a liquid-liquid interface, despite the large interfacial energy gradient driving the adsorption. The slow relaxation has been explained in terms of transient pinning and depinning of the contact line on the surface of the particles. However, the nature of the pinning sites has not been investigated in detail. We use digital holographic microscopy to track a variety of colloidal spheres---inorganic and organic, charge-stabilized and sterically stabilized, aqueous and non-aqueous---as they breach liquid interfaces. We find that nearly all of these particles relax logarithmically in time over timescales much larger than those expected from viscous dissipation alone. By comparing our results to theoretical models of the pinning dynamics, we infer the area per defect to be on the order of a few square nanometers for each of the colloids we examine, whereas the energy per defect can vary from a few $kT$ for non-aqueous and inorganic spheres to tens of $kT$ for aqueous polymer particles. The results suggest that the likely pinning sites are topographical features inherent to colloidal particles---surface roughness in the case of silica particles and grafted polymer "hairs" in the case of polymer particles. We conclude that the slow relaxation must be taken into account in experiments and applications, such as Pickering emulsions, that involve colloids attaching to interfaces. The effect is particularly important for aqueous polymer particles, which pin the contact line strongly.Comment: 26 pages, 7 figure

Multi-frequency scatter broadening evolution of pulsars - I

We present multi-wavelength scatter broadening observations of 47 pulsars, made with the Giant Metre-wave Radio Telescope (GMRT), Ooty Radio Telescope (ORT) and Long Wavelength Array (LWA). The GMRT observations have been made in the phased array mode at 148, 234, and 610 MHz and the ORT observations at 327 MHz. The LWA data sets have been obtained from the LWA pulsar data archive. The broadening of each pulsar as a function of observing frequency provides the frequency scaling index, $\alpha$. The estimations of $\alpha$ have been obtained for 39 pulsars, which include entirely new estimates for 31 pulsars. This study increases the total sample of pulsars available with $\alpha$ estimates by $\sim$50\%. The overall distribution of $\alpha$ with the dispersion measure (DM) of pulsar shows interesting variations, which are consistent with the earlier studies. However, for a given value of DM a range of $\alpha$ values are observed, indicating the characteristic turbulence along each line of sight. For each pulsar, the estimated level of turbulence, $C^{2}_{n_e}$, has also been compared with $\alpha$ and DM. Additionally, we compare the distribution of $\alpha$ with the theoretically predicated model to infer the general characteristics of the ionized interstellar medium (ISM). Nearly 65\% of the pulsars show a flatter index (i.e., $\alpha < 4.4$) than that is expected from the Kolmogorov turbulence model. Moreover, the group of pulsars having flatter index is typically associated with an enhanced value of $C^{2}_{n_e}$ than those with steeper index.Comment: 13 pages, 4 figures, 3 tables. Accepted for publication in Ap

The Effect of Spin Splitting on the Metallic Behavior of a Two-Dimensional System

Experiments on a constant-density two-dimensional hole system in a GaAs quantum well reveal that the metallic behavior observed in the zero-magnetic-field temperature dependence of the resistivity depends on the symmetry of the confinement potential and the resulting spin-splitting of the valence band

PONDER - A Real time software backend for pulsar and IPS observations at the Ooty Radio Telescope

This paper describes a new real-time versatile backend, the Pulsar Ooty Radio Telescope New Digital Efficient Receiver (PONDER), which has been designed to operate along with the legacy analog system of the Ooty Radio Telescope (ORT). PONDER makes use of the current state of the art computing hardware, a Graphical Processing Unit (GPU) and sufficiently large disk storage to support high time resolution real-time data of pulsar observations, obtained by coherent dedispersion over a bandpass of 16 MHz. Four different modes for pulsar observations are implemented in PONDER to provide standard reduced data products, such as time-stamped integrated profiles and dedispersed time series, allowing faster avenues to scientific results for a variety of pulsar studies. Additionally, PONDER also supports general modes of interplanetary scintillation (IPS) measurements and very long baseline interferometry data recording. The IPS mode yields a single polarisation correlated time series of solar wind scintillation over a bandwidth of about four times larger (16 MHz) than that of the legacy system as well as its fluctuation spectrum with high temporal and frequency resolutions. The key point is that all the above modes operate in real time. This paper presents the design aspects of PONDER and outlines the design methodology for future similar backends. It also explains the principal operations of PONDER, illustrates its capabilities for a variety of pulsar and IPS observations and demonstrates its usefulness for a variety of astrophysical studies using the high sensitivity of the ORT.Comment: 25 pages, 14 figures, Accepted by Experimental Astronom