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    Palladium catalyzed transfer of allylic groups

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    Synthesis of 5-Isovaleryl-3,3-Dimethyl-1,2,4-Cyclopentanetrione, A Homologue of Tetrahydrohulupone

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    3,3-Dimethyl-1,2,4-cyclopentanetrione is prepared in high yield by hydrolysis and debromination of the easily accessible 2,3,5,5-tetrabromo-4,4-dimethyl-2-cyclopentanone. Acylation with isovaleric anhydride affords the title compound
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