Alkaline fuel cell performance investigation

An exploratory experimental fuel cell test program was conducted to investigate the performance characteristics of alkaline laboratory research electrodes. The objective of this work was to establish the effect of temperature, pressure, and concentration upon performance and evaluate candidate cathode configurations having the potential for improved performance. The performance characterization tests provided data to empirically establish the effect of temperature, pressure, and concentration upon performance for cell temperatures up to 300 F and reactant pressures up to 200 psia. Evaluation of five gold alloy cathode catalysts revealed that three doped gold alloys had more that two times the surface areas of reference cathodes and therefore offered the best potential for improved performance

Asymptotically exponential hitting times and metastability: a pathwise approach without reversibility

We study the hitting times of Markov processes to target set $G$, starting from a reference configuration $x_0$ or its basin of attraction. The configuration $x_0$ can correspond to the bottom of a (meta)stable well, while the target $G$ could be either a set of saddle (exit) points of the well, or a set of further (meta)stable configurations. Three types of results are reported: (1) A general theory is developed, based on the path-wise approach to metastability, which has three important attributes. First, it is general in that it does not assume reversibility of the process, does not focus only on hitting times to rare events and does not assume a particular starting measure. Second, it relies only on the natural hypothesis that the mean hitting time to $G$ is asymptotically longer than the mean recurrence time to $x_0$ or $G$. Third, despite its mathematical simplicity, the approach yields precise and explicit bounds on the corrections to exponentiality. (2) We compare and relate different metastability conditions proposed in the literature so to eliminate potential sources of confusion. This is specially relevant for evolutions of infinite-volume systems, whose treatment depends on whether and how relevant parameters (temperature, fields) are adjusted. (3) We introduce the notion of early asymptotic exponential behavior to control time scales asymptotically smaller than the mean-time scale. This control is particularly relevant for systems with unbounded state space where nucleations leading to exit from metastability can happen anywhere in the volume. We provide natural sufficient conditions on recurrence times for this early exponentiality to hold and show that it leads to estimations of probability density functions

Sum of exit times in series of metastable states in probabilistic cellular automata

Reversible Probabilistic Cellular Automata are a special class of automata whose stationary behavior is described by Gibbs--like measures. For those models the dynamics can be trapped for a very long time in states which are very different from the ones typical of stationarity. This phenomenon can be recasted in the framework of metastability theory which is typical of Statistical Mechanics. In this paper we consider a model presenting two not degenerate in energy metastable states which form a series, in the sense that, when the dynamics is started at one of them, before reaching stationarity, the system must necessarily visit the second one. We discuss a rule for combining the exit times from each of the metastable states

Metastability for reversible probabilistic cellular automata with self--interaction

The problem of metastability for a stochastic dynamics with a parallel updating rule is addressed in the Freidlin--Wentzel regime, namely, finite volume, small magnetic field, and small temperature. The model is characterized by the existence of many fixed points and cyclic pairs of the zero temperature dynamics, in which the system can be trapped in its way to the stable phase. %The characterization of the metastable behavior %of a system in the context of parallel dynamics is a very difficult task, %since all the jumps in the configuration space are allowed. Our strategy is based on recent powerful approaches, not needing a complete description of the fixed points of the dynamics, but relying on few model dependent results. We compute the exit time, in the sense of logarithmic equivalence, and characterize the critical droplet that is necessarily visited by the system during its excursion from the metastable to the stable state. We need to supply two model dependent inputs: (1) the communication energy, that is the minimal energy barrier that the system must overcome to reach the stable state starting from the metastable one; (2) a recurrence property stating that for any configuration different from the metastable state there exists a path, starting from such a configuration and reaching a lower energy state, such that its maximal energy is lower than the communication energy

Relaxation Height in Energy Landscapes: an Application to Multiple Metastable States

The study of systems with multiple (not necessarily degenerate) metastable states presents subtle difficulties from the mathematical point of view related to the variational problem that has to be solved in these cases. We introduce the notion of relaxation height in a general energy landscape and we prove sufficient conditions which are valid even in presence of multiple metastable states. We show how these results can be used to approach the problem of multiple metastable states via the use of the modern theories of metastability. We finally apply these general results to the Blume--Capel model for a particular choice of the parameters ensuring the existence of two multiple, and not degenerate in energy, metastable states

BeppoSAX Observations of the Radio Galaxy Centaurus A

We present preliminary results from two observations of the radio galaxy Centaurus A performed by the BeppoSAX satellite. We did not detect any spectral variation of the nuclear continuum in spite of the long-term flux change (by a factor 1.3) between the two observations. At both epochs, the nuclear point-like emission was well fitted with a strongly absorbed power law with an exponential cutoff at high energies (E_cutoff>200 keV). We also observed a significant flux variation of the iron line between the two observations. The flux of the line and of the continuum changed in the opposite sense. The line is more intense at the first epoch, when the nuclear source was at the lower intensity level. The implied delay between the continuum and line variations strongly suggests that the cold material responsible for the iron line production is not located very near to the primary X-ray source. There is also evidence that the line profile changed between the two epochs, being broader and slightly blueshifted when the source was fainter. It is possible that the emission feature is a blend of cold and ionized iron lines produced in separate regions surrounding the nuclear source.Comment: 4 pages, 4 figures, accepted for publication in Advances in Space Research, proceedings of 32nd COSPAR Symposium (1998

Simultaneous BeppoSAX and RXTE observations of the X-ray burst sources GX 3+1 and Ser X-1

We have obtained spectral and timing data on GX 3+1 and Ser X-1. Both sources were observed simultaneously with BeppoSAX and RXTE. The RXTE data is used to provide power spectra and colour-colour diagrams in order to constrain the state (and thus track $\dot M$) the sources are in. The BeppoSAX data provide the broad-band spectra. The spectra of both sources are reasonably well-fit using a model consisting of a disk-blackbody, a comptonized component and a Fe line, absorbed by interstellar absorption. The electron temperature (kT$_{\rm e}$) of the Comptonizing plasma is in both cases $\sim$2.5 keV. This implies that no strong high-energy tail from the Comptonized component is present in either of the sources. We discuss the similarities between these burst sources and the luminous X-ray sources located in globular clusters. We find that the spectral parameters of the comptonized component provide information about the mass-accretion rate, which agrees well with estimates from the timing and spectral variations.Comment: 8 pages, accepted by A&

High Energy Properties of X-ray Sources observed with BeppoSAX

We report on highlight results on celestial sources observed in the high energy band (>20 keV) with BeppoSAX. In particular we review the spectral properties of sources that belong to different classes of objects, i.e. stellar coronae (Algol), supernova remnants (Cas A), low mass X-ray binaries (Cygnus X-2 and the X-ray burster GS1826-238), black hole candidates (Cygnus X-1) and Active Galactic Nuclei (Mkn 3). We detect, for the first time, the broad-band spectrum of a stellar corona up to 100 keV; for Cas A we report upper limits to the ^44Ti line intensities that are lower than those available to date; for Cyg X-2 we report the evidence of a high energy component; we report a clear detection of a broad Fe K line feature from Cygnus X-1 in soft state and during its transition to hard state; Mkn 3 is one of several Seyfert 2 galaxies detected with BeppoSAX at high energies, for which Compton scattering process is important.Comment: To appear in the Proceedings of the 1997 Conference on 'The Active X-ray Sky: Results from BeppoSAX and Rossi-XTE' eds. L. Scarsi, F. Fiore and P. Giomm

The complex behaviour of the microquasar GRS 1915+105 in the rho class observed with BeppoSAX. I: Timing analysis

GRS 1915+105 was observed by BeppoSAX for about 10 days in October 2000. For about 80% of the time, the source was in the variability class $\rho$, characterised by a series of recurrent bursts. We describe the results of the timing analysis performed on the MECS (1.6--10 keV) and PDS (15--100 keV) data. The X-ray count rate from \grss showed an increasing trend with different characteristics in the various energy bands. Fourier and wavelet analyses detect a variation in the recurrence time of the bursts, from 45--50 s to about 75 s, which appear well correlated with the count rate. From the power distribution of peaks in Fourier periodograms and wavelet spectra, we distinguished between the {\it regular} and {\it irregular} variability modes of the $\rho$ class, which are related to variations in the count rate in the 3--10 keV range. We identified two components in the burst structure: the slow leading trail, and the pulse, superimposed on a rather stable level. We found that the change in the recurrence time of the regular mode is caused by the slow leading trails, while the duration of the pulse phase remains far more stable. The evolution in the mean count rates shows that the time behaviour of both the leading trail and the baseline level are very similar to those observed in the 1.6--3 and 15--100 keV ranges, while that of the pulse follows the peak number. These differences in the time behaviour and count rates at different energies indicate that the process responsible for the pulses must produce the strongest emission between 3 and 10 keV, while that associated with both the leading trail and the baseline dominates at lower and higher energiesComment: Astronomy and Astrophysics, in pres