Phase-Locked Spatial Domains and Bloch Domain Walls in Type-II Optical Parametric Oscillators

We study the role of transverse spatial degrees of freedom in the dynamics of signal-idler phase locked states in type-II Optical Parametric Oscillators. Phase locking stems from signal-idler polarization coupling which arises if the cavity birefringence and/or dichroism is not matched to the nonlinear crystal birefringence. Spontaneous Bloch domain wall formation is theoretically predicted and numerically studied. Bloch walls connect, by means of a polarization transformation, homogeneous regions of self-phase locked solutions. The parameter range for their existence is analytically found. The polarization properties and the dynamics of walls in one- and two transverse spatial dimensions is explained. Transition from Bloch to Ising walls is characterized, the control parameter being the linear coupling strength. Wall dynamics governs spatiotemporal dynamical states of the system, which include transient curvature driven domain growth, persistent dynamics dominated by spiraling defects for Bloch walls, and labyrinthine pattern formation for Ising walls.Comment: 27 pages, 16 figure

Predictor Design for Altitude Control of a Seaweed Harvester

In this paper, the predictor design, for altitude control of a seaweed harvester, is investigated. The harvesting system consists of a vessel and a suspended harvester device, the altitude of which is controlled by a winch. The control approach of Gallieri and Ringwood (2010), including a feedforward action, which requires a single step disturbance prediction, is investigated further, focusing on the disturbance prediction, for noisy sensors. The prediction is performed using AR and ARMA models, identified online, by using the Recursive Least Squared with Forgetting Factor (RLSFF) algorithm and the Kalman Filter (KF). The dependance between the error spectrum and the quality of the control is shown, and the prediction performances are evaluated, using an FFT-based criterion, oriented to the feedforward application. The control performances are then evaluated, and the results are compared to Gallieri and Ringwood (2010)

Predictor Design for Altitude Control of a Seaweed Harvester

In this paper, the predictor design, for altitude control of a seaweed harvester, is investigated. The harvesting system consists of a vessel and a suspended harvester device, the altitude of which is controlled by a winch. The control approach of Gallieri and Ringwood (2010), including a feedforward action, which requires a single step disturbance prediction, is investigated further, focusing on the disturbance prediction, for noisy sensors. The prediction is performed using AR and ARMA models, identified online, by using the Recursive Least Squared with Forgetting Factor (RLSFF) algorithm and the Kalman Filter (KF). The dependance between the error spectrum and the quality of the control is shown, and the prediction performances are evaluated, using an FFT-based criterion, oriented to the feedforward application. The control performances are then evaluated, and the results are compared to Gallieri and Ringwood (2010)

Circularly polarized luminescence of natural products lycorine and narciclasine: role of excited-state intramolecular proton-transfer and test of pH sensitivity

: Circularly polarized luminescence (CPL) is increasingly gaining interest not only for its applicative potentialities but also for providing an understanding of the excited state properties of chiral molecules. However, applications of CPL are mainly in the field of materials science: special organic molecules and polymers, metal (lanthanide) complexes, and organic dyes are actively and intensely studied. So far natural compounds have not been investigated much. We fill the gap here by measuring circular dichroism (CD) and CPL of lycorine and narciclasine, the most abundant known alkaloid and isocarbostyril from Amaryllidaceae, which exhibit a large spectrum of biological activities and are promising anticancer compounds. Dual fluorescence detection in narciclasine led us to unveil an occurring excited-state intramolecular proton transfer (ESIPT) process, this mechanism well accounts for the Stokes shift and CPL spectra observed in narciclasine. The same molecule is interesting also as a pH chiroptical switch. Both in absorption and emission, lycorine and narciclasine are also studied computationally via density functional theory (DFT) calculations further shedding light on their properties

Pushing measurements and interpretation of VCD spectra in the IR, NIR and visible ranges to the detectability and computational complexity limits

(R)-Limonene VCD and IR absorption spectra for neat liquid samples are considered from 900 to 16,000 cm−1, using mostly data by Nafie et al. up to 10,000 cm−1 and from previous investigations of the Brescia group. New VCD data are recorded in the merely overtone and combination region between 1800 and 2400 cm−1 and for the Δn = 6 overtone CH-stretching region above 15,000 cm−1. The GVPT2 anharmonic DFT calculations permit satisfactory interpretation of the fundamental + overtone/combination of deformation modes in the mid-IR up to 3500 cm−1. The GVPT2 approach is also used for the first CH-stretching overtone regions together with their combination with deformation modes up to 9000 cm−1. Then the local-mode approach developed within the DFT protocol is employed in all the CH-stretching regions (fundamental + overtones) and is found to satisfactorily account for the observed spectra, justifying the constant VCD pattern observed for all overtones. On the basis of the local-mode model the components of the bisignate VCD spectrum are attributed to the stretchings of the axial and equatorial CH bonds in α-position with respect to the ring CC double bond

Scaling-up VPT2: A feasible route to include anharmonic correction on large molecules

Vibrational analysis plays a crucial role in the investigation of molecular systems. Though methodologies like second-order vibrational perturbation theory (VPT2) have paved the way to more accurate simulations, the computational cost remains a difficult barrier to overcome when the molecular size increases. Building upon recent advances in the identification of resonances, we propose an approach making anharmonic simulations possible for large-size systems, typically unreachable by standard means. This relies on the fact that, often, only portions of the whole spectra are of actual interest. Therefore, the anharmonic corrections can be included selectively on subsets of normal modes directly related to the regions of interest. Starting from the VPT2 equations, we evaluate rigorously and systematically the impact of the truncated anharmonic treatment onto simulations. The limit and feasibility of the reduced-dimensionality approach are detailed, starting on a smaller model system. The methodology is then challenged on the IR absorption and vibrational circular dichroism spectra of an organometallic complex in three different spectral ranges

CO2 and CH4 fluxes across a Nuphar lutea (L.) Sm. stand

Floating-leaved rhizophytes can significantly alter net carbon dioxide (CO 2) and methane (CH 4) exchanges with the atmosphere in freshwater shallow environments. In particular, CH 4 efflux can be enhanced by the aerenchyma-mediated mass flow, while CO 2 release from supersaturated waters can be reversed by the plant uptake. Additionally, the floating leaves bed can hamper light penetration and oxygen (O 2) diffusion from the atmosphere, thus altering the dissolved gas dynamics in the water column. In this study, net fluxes of CO 2 and CH 4 were measured seasonally across vegetated [Nuphar lutea (L.) Sm.] and free water surfaces in the Busatello wetland (Northern Italy). Concomitantly, dissolved gas concentrations were monitored in the water column and N. lutea leaf production was estimated by means of biomass harvesting. During the vegetative period (May-August), the yellow waterlily stand resulted a net sink for atmospheric carbon (from 97.5 to 110.6 g C-CO 2 m -2), while the free water surface was a net carbon source (166.3 g C-CO 2 m -2). Both vegetated and plant-free areas acted as CH 4 sources, with an overall carbon release comprised between 71.6 and 113.3 g C-CH 4 m -2. On the whole, water column chemistry was not affected by the presence of the floating leaves; moreover, no significant differences in CH4 efflux were evidenced between the vegetated and plant-free areas. In general, this study indicates that the colonization of shallow aquatic ecosystems by N. lutea might not have the same drastic effect reported for free-floating macrophytes

Scaling-up VPT2: a feasible route to include anharmonic correction on large molecules

Vibrational analysis plays a crucial role in the investigation of molecular systems. Though methodologies like second-order vibrational perturbation theory (VPT2) have paved the way to more accurate simulations, the computational cost remains a difficult barrier to overcome when the molecular size increases. Building upon recent advances in the identification of resonances, we propose an approach making anharmonic simulations possible for large-size systems, typically unreachable by standard means. This relies on the fact that, often, only portions of the whole spectra are of actual interest. Therefore, the anharmonic corrections can be included selectively on subsets of normal modes directly related to the regions of interest. Starting from the VPT2 equations, we evaluate rigorously and systematically the impact of the truncated anharmonic treatment onto simulations. The limit and feasibility of the reduced-dimensionality approach are detailed, starting on a smaller model system. The methodology is then challenged on the IR absorption and vibrational circular dichroism spectra of an organometallic complex in three different spectral ranges

Ultralow-Power Digital Control and Signal Conditioning in GaAs MMIC Core Chip for X-Band AESA Systems

This work presents the design and characterization of an ultralow-power core chip for electronically scanned arrays at X-band, implemented in 0.25-/0.5-μm E-/D-mode gallium arsenide (GaAs) pHEMT technology. In particular, design details are given about the two core functional blocks embedded in the microwave monolithic integrated circuit (MMIC): a 12-bit phase and amplitude control circuit and an 18-bit serial-to-parallel (S2P) interface. The S2P interface was designed resorting to a custom symmetric device model, expressly conceived for the time-domain simulations required for digital circuits. Due to the adoption of a differential structure with resistive pull-ups, it achieves a state-of-the-art power consumption of 2.2 mW/bit and nearly 87% yield. The analog circuit includes a 6-bit phase shifter (PS) and a 6-bit attenuator. To mitigate risks, two different PS architectures have been developed and are compared in this work, discussing advantages and drawbacks of the different solutions. Since the two designs share the same target specifications, a truly fair comparison can be made not only in terms of performance but also concerning robustness and repeatability, thus providing useful guidelines for the selection of the most appropriate strategy. In particular, it is shown that one architecture outperforms the other by about 2 dB and 1.5° in terms of insertion loss and rms phase error, respectively

Metodologias ativas: uma proposta de biologia e matemática para o ensino médio / Active methodologies: a biology and mathematics proposal for high school

Este relato apresenta um estudo de construção de conceitos relacionados à nutrição e à matemática financeira, em turma de 1º Ensino Médio de uma escola particular, em São Paulo. O objetivo foi verificar a apropriação conceitual e o desenvolvimento de habilidades de Biologia e de Matemática. A metodologia envolveu uma postura ativa e investigativa dos estudantes, com montagem de e-portfólio; revisão entre pares com rubricas e por estudantes de graduação em Nutrição; criação de um protótipo para divulgação de um produto alimentício, com avaliação do projeto por técnicos e empresários do setor. Envolvendo etapas presenciais e remotas, forçados pela situação pandêmica, os resultados obtidos por questionários mostraram apropriação conceitual e 73,7% dos alunos afirmarem que a metodologia favoreceu a construção coletiva e a aprendizagem significativa