Preparation of Nanocomposites from Styrene and Modified Graphite Oxides

Graphite oxide was prepared and modified with several ammonium salts and these modified graphite oxides were used to prepare nanocomposites with polystyrene by in situ polymerization of styrene monomer and by melt blending with polystyrene. Nanocomposites were characterized by X-ray diffraction, cone calorimetry, thermogravimetric analysis and the evaluation of mechanical properties. Nanocomposites are formed by in situ polymerization but not by melt blending; the graphite oxide undergoes thermal degradation at the temperature of melt blending so nanocomposite formation would be unlikely. Mechanical properties of the melt blended nanocomposites are improved relative to the virgin polystyrene while those prepared by in situ polymerization are decreased, except in the case of Young\u27s Modulus, where melt blended and in situ polymerized materials show similar results

Parenting Latino Toddlers and Preschoolers: Clinical and Nonclinical Samples

Parenting practices contribute significantly to the social-emotional development of young children. There is limited literature that addresses the role of culture in parenting, particularly among Latino families who have very young children with significant behavior problems. The current study compared the parenting practices of 30 low-income Latino mothers whose young children had been referred for mental health services for their behavior problems with a similar group of 30 mothers of children without behavior problems. Results showed that mothers in the clinical sample nurtured their children less often and used more frequent verbal and corporal punishment as discipline than the nonclinical sample. The clinical sample also had a significantly higher incidence of mental health problems in their families. Results also showed the significant toll that raising young children with challenging behaviors takes on their mothers. The implications of these findings for the early identification of these children are discussed

On a price formation free boundary model by Lasry & Lions: The Neumann problem

We discuss local and global existence and uniqueness for the price formation free boundary model with homogeneous Neumann boundary conditions introduced by Lasry & Lions in 2007. The results are based on a transformation of the problem to the heat equation with nonstandard boundary conditions. The free boundary becomes the zero level set of the solution of the heat equation. The transformation allows us to construct an explicit solution and discuss the behavior of the free boundary. Global existence can be verified under certain conditions on the free boundary and examples of non-existence are given

Polybutadiene Cross-Linked With Various Diols – Effect On Thermal Stability

The relationship between cross-linking and thermal stability as related to polybutadiene is the focus of current research. Cross-linked polybutadienes have been prepared using various diols as the cross-linking agent. Cross-linked polymers have been characterized by gel content, swelling ratios, infrared spectroscopy, and thermal analysis. These polymers are not highly cross-linked, as seen by gel content and swelling ratios, and cross-linking does not have a large effect on the onset temperature of the degradation. Nonetheless, extensive formation of a non-volatile residue occurs

The Gender Pay Gap for Private Sector Employees in Canada and Britain

This paper uses British and Canadian linked employer-employee data to investigate the importance of the workplace for the gender wage gap. Implementing a novel decomposition approach, we find high levels of unexplained wage inequality in the private sector of both countries, which is related to women receiving relatively lower wages within workplaces than do men. Whilst this inequality is partially offset by women, on average, receiving a workplace specific return which is relatively higher than that paid to men, a substantial and significant unexplained within workplace wage gap remains which is considerably higher in Britain than in Canada. The results are consistent with a prima facie argument that country-specific factors, such as the wage setting environment, are important determinants in explaining the relative size of the gender wage gap.workplaces, gender earnings gap, Britain, Canada