Quenching of fluorescence of aromatic molecules by graphene due to electron transfer

Investigations on the fluorescence quenching of graphene have been carried out with two organic donor molecules, pyrene butanaoic acid succinimidyl ester (PyBS, I) and oligo(p-phenylenevinylene) methyl ester (OPV-ester, II). Absorption and photoluminescence spectra of I and II recorded in mixture with increasing the concentrations of graphene showed no change in the former, but remarkable quenching of fluorescence. The property of graphene to quench fluorescence of these aromatic molecules is shown to be associated with photo-induced electron transfer, on the basis of fluorescence decay and time-resolved transient absorption spectroscopic measurements.Comment: 18 pages, 6 figure

Novel magnetic properties of graphene: Presence of both ferromagnetic and antiferromagnetic features and other aspects

Investigations of the magnetic properties of graphenes prepared by different methods reveal that dominant ferromagnetic interactions coexist along with antiferromagnetic interactions in all the samples. Thus, all the graphene samples exhibit room-temperature magnetic hysteresis. The magnetic properties depend on the number of layers and the sample area, small values of both favoring larger magnetization. Molecular charge-transfer affects the magnetic properties of graphene, interaction with a donor molecule such as tetrathiafulvalene having greater effect than an electron-withdrawing molecule such as tetracyanoethyleneComment: 16 pges, 5 figure

Influencia de la concentración de sacarosa en el medio, sobre la respuesta de material de vid "in vitro"

7 páginas, 8 figuras y 16 referencias.-- Trabajo presentado en el VI Simposium Nacional - II Ibérico sobre nutrición mineral de las plantas, Sevilla, del 12 al 15 de Noviembre de 1996.-- Entidades colaboradoras Junta de Andalucía, Universidad de Sevilla, Consejo Superior de Investigaciones Científicas, Sociedad Española de Fisiología Vegetal, El Monte, Caja de Huelva y Sevilla y Gat Fertilíquido. Editores científicos: Rafael Sarmiento Solís, Eduardo O. Leidi Montes y Antonio Troncoso de Arce.-- (Instituto de Recursos Naturales y Agrobiología de Sevilla).[EN]: The effects of two sucrose amounts, 20 and 30 gl(elevado a -1), added to the nutrient medium on the in vitro development of grapevine rootstocks 4 lB, 110 Richter, 196-17, 161-49 de Couderc and Rupestris de Lot, of Superior cultivar and of CH-I ,and CH-2 clones from Chile was studied. Medium with the lowest amount of sucrose favoured the aerial part growth of varieties ) 61-49, Rupestris de Lot, Superior and 196-17. This major growth of aerial part of explant (organs with clhorophyll), did not produce it in radical system. Development of this system was independent of sugar concentration in substrat and more in relation with grape variety Substrat with 20 gl(elevado a -1) of sucrose also shown a light major inclination to vitrification of in vitro plant. material[ES]: Se estudia el efecto de dos concentraciones (20 y 30 gl(elevado a -1)) de sacarosa en el medio de cultivo, sobre el desarrollo in vitro de los portainjertos de vid 41B, 110 de ichter,) 96-17, 161-49 de Couderc y Rupestris de Lot, del cultivar Superior y de los clones CH-) y CH-2 procedentes de Chile. El medio con la concentración mas baja de sacarosa favoreció, en general el crecimiento de la parte aérea del material de vid in vitro, en especial de las variedades 161-49, Rupestris de Lot, Superior y 196-17. Este mayor crecimiento de la parte aérea del explanto (órganos con clorofila), no se produjo en el sistema radical, cuyo desarrollo fue independiente de la concentración de azúcar en el medio y mas relacionable con la variedad de vid. El medio con 20 gl(elevado a -1) de sacarosa también mostró una ligera mayor predisposición a.la vitrificacón del material vegetal in vitro.Peer reviewe

Sistema Agrossilvipastoril na região sudoeste do Estado do Rio Grande do Sul.

bitstream/item/24472/1/Sistema-agrossilvipastoril-na-regiao-sudoeste-do-estado-do-Rio-Grande-do-Sul.pd

Exponential localization of hydrogen-like atoms in relativistic quantum electrodynamics

We consider two different models of a hydrogenic atom in a quantized electromagnetic field that treat the electron relativistically. The first one is a no-pair model in the free picture, the second one is given by the semi-relativistic Pauli-Fierz Hamiltonian. We prove that the no-pair operator is semi-bounded below and that its spectral subspaces corresponding to energies below the ionization threshold are exponentially localized. Both results hold true, for arbitrary values of the fine-structure constant, $e^2$, and the ultra-violet cut-off, $\Lambda$, and for all nuclear charges less than the critical charge without radiation field, $Z_c=e^{-2}2/(2/\pi+\pi/2)$. We obtain similar results for the semi-relativistic Pauli-Fierz operator, again for all values of $e^2$ and $\Lambda$ and for nuclear charges less than $e^{-2}2/\pi$.Comment: 37 page

Pesticide spraying for West Nile virus control and emergency department asthma visits in New York City, 2000

Pyrethroid pesticides were applied via ground spraying to residential neighborhoods in New York City during July–September 2000 to control mosquito vectors of West Nile virus (WNV). Case reports link pyrethroid exposure to asthma exacerbations, but population-level effects on asthma from large-scale mosquito control programs have not been assessed. We conducted this analysis to determine whether widespread urban pyrethroid pesticide use was associated with increased rates of emergency department (ED) visits for asthma. We recorded the dates and locations of pyrethroid spraying during the 2000 WNV season in New York City and tabulated all ED visits for asthma to public hospitals from October 1999 through November 2000 by date and ZIP code of patients’ residences. The association between pesticide application and asthma-related emergency visits was evaluated across date and ZIP code, adjusting for season, day of week, and daily temperature, precipitation, particulate, and ozone levels. There were 62,827 ED visits for asthma during the 14-month study period, across 162 ZIP codes. The number of asthma visits was similar in the 3-day periods before and after spraying (510 vs. 501, p = 0.78). In multivariate analyses, daily rates of asthma visits were not associated with pesticide spraying (rate ratio = 0.92; 95% confidence interval, 0.80–1.07). Secondary analyses among children and for chronic obstructive pulmonary disease yielded similar null results. This analysis shows that spraying pyrethroids for WNV control in New York City was not followed by population-level increases in public hospital ED visit rates for asthma

Weak Gravitational Field in Finsler-Randers Space and Raychaudhuri Equation

The linearized form of the metric of a Finsler - Randers space is studied in relation to the equations of motion, the deviation of geodesics and the generalized Raychaudhuri equation are given for a weak gravitational field. This equation is also derived in the framework of a tangent bundle. By using Cartan or Berwald-like connections we get some types "gravito - electromagnetic" curvature. In addition we investigate the conditions under which a definite Lagrangian in a Randers space leads to Einstein field equations under the presence of electromagnetic field. Finally, some applications of the weak field in a generalized Finsler spacetime for gravitational waves are given.Comment: 22 pages, matches version published in GER

Complete classification of purely magnetic, non-rotating and non-accelerating perfect fluids

Recently the class of purely magnetic non-rotating dust spacetimes has been shown to be empty (Wylleman, Class. Quant. Grav. 23, 2727). It turns out that purely magnetic rotating dust models are subject to severe integrability conditions as well. One of the consequences of the present paper is that also rotating dust cannot be purely magnetic when it is of Petrov type D or when it has a vanishing spatial gradient of the energy density. For purely magnetic and non-rotating perfect fluids on the other hand, which have been fully classified earlier for Petrov type D (Lozanovski, Class. Quant. Grav. 19, 6377), the fluid is shown to be non-accelerating if and only if the spatial density gradient vanishes. Under these conditions, a new and algebraically general solution is found, which is unique up to a constant rescaling, which is spatially homogeneous of Bianchi type $VI_0$, has degenerate shear and is of Petrov type I($M^\infty)$ in the extended Arianrhod-McIntosh classification. The metric and the equation of state are explicitly constructed and properties of the model are briefly discussed. We finally situate it within the class of normal geodesic flows with degenerate shear tensor.Comment: 12 pages; introduction partly rewritten, notation made more clear, table of results adde

Theorems on shear-free perfect fluids with their Newtonian analogues

In this paper we provide fully covariant proofs of some theorems on shear-free perfect fluids. In particular, we explicitly show that any shear-free perfect fluid with the acceleration proportional to the vorticity vector (including the simpler case of vanishing acceleration) must be either non-expanding or non-rotating. We also show that these results are not necessarily true in the Newtonian case, and present an explicit comparison of shear-free dust in Newtonian and relativistic theories in order to see where and why the differences appear.Comment: 23 pages, LaTeX. Submitted to GR