28,491 research outputs found

    Assessing lidar-based classification schemes for polar stratospheric clouds based on 16 years of measurements at Esrange, Sweden

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    This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License CC BY-NC-ND 3.0 https://creativecommons.org/licenses/by-nc-nd/3.0/, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.Lidar measurements of polar stratospheric clouds (PSCs) are commonly analyzed in classification schemes that apply the backscatter ratio and the particle depolarization ratio. This similarity of input data suggests comparable results of different classification schemes - despite measurements being performed with a variety of mostly custom-made instruments. Based on a time series of 16 years of lidar measurements at Esrange (68°N, 21°E), Sweden, we show that PSC classification differs substantially depending on the applied scheme. The discrepancies result from varying threshold values of lidar-derived parameters used to define certain PSC types. The resulting inconsistencies could impact the understanding of long-term PSC observations documented in the literature. We identify two out of seven considered classification schemes that are most likely to give reliable results and should be used in future lidar-based studies. Using polarized backscatter ratios gives the advantage of increased contrast for observations of weakly backscattering and weakly depolarizing particles. Improved confidence in PSC classification can be achieved by a more comprehensive consideration of the effect of measurement uncertainties. The particle depolarization ratio is the key to a reliable identification of different PSC types. Hence, detailed information on the calibration of the polarization-sensitive measurement channels should be provided to assess the findings of a study. Presently, most PSC measurements with lidar are performed at 532 nm only. The information from additional polarization-sensitive measurements in the near infrared could lead to an improved PSC classification. Coincident lidar-based temperature measurements at PSC level might provide useful information for an assessment of PSC classification. Key Points Assessment of PSC classification schemes Statistical analysis of PSC observations Recommendations for lidar-based PSC studiesPeer reviewe

    Transient stress evolution in repulsion and attraction dominated glasses

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    We present results from microscopic mode coupling theory generalized to colloidal dispersions under shear in an integration-through-transients formalism. Stress-strain curves in start-up shear, flow curves, and normal stresses are calculated with the equilibrium static structure factor as only input. Hard spheres close to their glass transition are considered, as are hard spheres with a short-ranged square-well attraction at their attraction dominated glass transition. The consequences of steric packing and physical bond formation on the linear elastic response, the stress release during yielding, and the steady plastic flow are discussed and compared to experimental data from concentrated model dispersions.Comment: J. Rheol., 58, in prin

    The Theory of Parity Violation in Few-Nucleon Systems

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    We review recent progress in the theoretical description of hadronic parity violation in few-nucleon systems. After introducing the different methods that have been used to study parity-violating observables we discuss the available calculations for reactions with up to five nucleons. Particular emphasis is put on effective field theory calculations where they exist, but earlier and complementary approaches are also presented. We hope this review will serve as a guide for those who wish to know what calculations are available and what further calculations need to be completed before we can claim to have a comprehensive picture of parity violation in few nucleon systems.Comment: 69 pages, 10 figures, accepted for publication in Prog. Part. Nucl. Phy

    First-principles statistical mechanics study of the stability of a sub-nanometer thin surface oxide in reactive environments: CO oxidation at Pd(100)

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    We employ a multiscale modeling approach to study the surface structure and composition of a Pd(100) model catalyst in reactive environments. Under gas phase conditions representative of technological CO oxidation (~1 atm, 300-600 K) we find the system on the verge of either stabilizing sub-nanometer thin oxide structures or CO adlayers at the surface. Under steady-state operation this suggests the presence or continuous formation and reduction of oxidic patches at the surface, which could be key to understand the observable catalytic function.Comment: 4 pages including 2 figures; related publications can be found at http://www.fhi-berlin.mpg.de/th/th.htm

    Overshoots in stress strain curves: Colloid experiments and schematic mode coupling theory

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    The stress versus strain curves in dense colloidal dispersions under start-up shear flow are investigated combining experiments on model core-shell microgels, computer simulations of hard disk mixtures, and mode coupling theory. In dense fluid and glassy states, the transient stresses exhibit first a linear increase with the accumulated strain, then a maximum ('stress overshoot') for strain values around 5%, before finally approaching the stationary value, which makes up the flow curve. These phenomena arise in well-equilibrated systems and for homogeneous flows, indicating that they are generic phenomena of the shear-driven transient structural relaxation. Microscopic mode coupling theory (generalized to flowing states by integration through the transients) derives them from the transient stress correlations, which first exhibit a plateau (corresponding to the solid-like elastic shear modulus) at intermediate times, and then negative stress correlations during the final decay. We introduce and validate a schematic model within mode coupling theory which captures all of these phenomena and handily can be used to jointly analyse linear and large-amplitude moduli, flow curves, and stress-strain curves. This is done by introducing a new strain- and time-dependent vertex into the relation between the the generalized shear modulus and the transient density correlator.Comment: 21 pages, 13 figure
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