Optical signatures of molecular particles via mass-selected cluster spectroscopy

A new molecular beam apparatus was developed to study optical absorption in cold (less than 100 K) atomic clusters and complexes produced by their condensation with simple molecular gases. In this instrument, ionized clusters produced in a laser vaporization nozzle source are mass selected and studied with photodissociation spectroscopy at visible and ultraviolet wavelengths. This new approach can be applied to synthesize and characterize numerous particulates and weakly bound complexes expected in planetary atmospheres and in comets

Parallel Lives: Birth, Childhood and Adolescent Influences on Career Paths

This paper uses sequence methods and cluster analysis to create a typology of career paths for a cohort of British 29 year olds born in 1970. There are clear ‘types’ identified by these techniques including several paths dominated by various forms of non-employment. These types are strongly correlated with individual characteristics and parental background factors observed at birth, age ten and age sixteen. By estimating a multinomial logit model of career types we show how policy makers might identify early those young people likely to experience long term non-employment as adults, enabling better targeted preventative policy intervention.careers, cluster analysis, optimal matching

A wall-function approach to incorporating Knudsen-layer effects in gas micro flow simulations

For gas flows in microfluidic configurations, the Knudsen layer close to the wall can comprise a substantial part of the entire flow field and has a major effect on quantities such as the mass flow rate through micro devices. The Knudsen layer itself is characterized by a highly nonlinear relationship between the viscous stress and the strain rate of the gas, so even if the Navier-Stokes equations can be used to describe the core gas flow they are certainly inappropriate for the Knudsen layer itself. In this paper we propose a "wall-function" model for the stress/strain rate relations in the Knudsen layer. The constitutive structure of the Knudsen layer has been derived from results from kinetic theory for isothermal shear flow over a planar surface. We investigate the ability of this simplified model to predict Knudsen-layer effects in a variety of configurations. We further propose a semi-empirical Knudsen-number correction to this wall function, based on high-accuracy DSMC results, to extend the predictive capabilities of the model to greater degrees of rarefaction

Pariah moonshine

Finite simple groups are the building blocks of finite symmetry. The effort to classify them precipitated the discovery of new examples, including the monster, and six pariah groups which do not belong to any of the natural families, and are not involved in the monster. It also precipitated monstrous moonshine, which is an appearance of monster symmetry in number theory that catalysed developments in mathematics and physics. Forty years ago the pioneers of moonshine asked if there is anything similar for pariahs. Here we report on a solution to this problem that reveals the O'Nan pariah group as a source of hidden symmetry in quadratic forms and elliptic curves. Using this we prove congruences for class numbers, and Selmer groups and Tate--Shafarevich groups of elliptic curves. This demonstrates that pariah groups play a role in some of the deepest problems in mathematics, and represents an appearance of pariah groups in nature.Comment: 20 page

Moonshine

Monstrous moonshine relates distinguished modular functions to the representation theory of the monster. The celebrated observations that 196884=1+196883 and 21493760=1+196883+21296876, etc., illustrate the case of the modular function j-744, whose coefficients turn out to be sums of the dimensions of the 194 irreducible representations of the monster. Such formulas are dictated by the structure of the graded monstrous moonshine modules. Recent works in moonshine suggest deep relations between number theory and physics. Number theoretic Kloosterman sums have reappeared in quantum gravity, and mock modular forms have emerged as candidates for the computation of black hole degeneracies. This paper is a survey of past and present research on moonshine. We also compute the quantum dimensions of the monster orbifold, and obtain exact formulas for the multiplicities of the irreducible components of the moonshine modules. These formulas imply that such multiplicities are asymptotically proportional to dimensions.Comment: 67 pages; a number of revisions and corrections in v.2, including a new result (Cor. 8.3) on the quantum dimensions of the monster orbifold, obtained following a suggestion of an anonymous refere

Capturing the Knudsen layer in continuum-fluid models of non-equilibrium gas flows

In hypersonic aerodynamics and microflow device design, the momentum and energy fluxes to solid surfaces are often of critical importance. However, these depend on the characteristics of the Knudsen layer - the region of local non-equilibrium existing up to one or two molecular mean free paths from the wall in any gas flow near a surface. While the Knudsen layer has been investigated extensively using kinetic theory, the ability to capture it within a continuum-fluid formulation (in conjunction with slip boundary conditions) suitable for current computational fluid dynamics toolboxes would offer distinct and practical computational advantages