Retrieving Temperatures and Abundances of Exoplanet Atmospheres with High-Resolution Cross-Correlation Spectroscopy

Hi-resolution spectroscopy (R > 25,000) has recently emerged as one of the leading methods to detect atomic and molecular species in the atmospheres of exoplanets. However, it has so far been lacking in a robust method to extract quantitative constraints on temperature structure and molecular/atomic abundances. In this work we present a novel Bayesian atmospheric retrieval framework applicable to high resolution cross-correlation spectroscopy (HRCCS) that relies upon the cross-correlation between data and models to extract the planetary spectral signal. We successfully test the framework on simulated data and show that it can correctly determine Bayesian credibility intervals on atmospheric temperatures and abundances allowing for a quantitative exploration of the inherent degeneracies. Furthermore, our new framework permits us to trivially combine and explore the synergies between HRCCS and low-resolution spectroscopy (LRS) to provide maximal leverage on the information contained within each. This framework also allows us to quantitatively assess the impact of molecular line opacities at high resolution. We apply the framework to VLT CRIRES K-band spectra of HD 209458 b and HD 189733 b and retrieve abundant carbon monoxide but sub-solar abundances for water, largely invariant under different model assumptions. This confirms previous analysis of these datasets, but is possibly at odds with detections of water at different wavelengths and spectral resolutions. The framework presented here is the first step towards a true synergy between space observatories and ground-based hi-resolution observations.Comment: Accepted Version (01/16/19

On the Detection of Molecules in the Atmosphere of HD189733b using HST NICMOS Transmission Spectroscopy

The HST/NICMOS transmission spectrum measurements of HD 189733b that suggest the detection of methane (CH$_{4}$) in an exoplanet atmosphere have been a source of significant controversy. With what is probably the best analyzed exoplanet spectroscopy data set to date, different teams, using different methods, have claimed evidence both contradicting and supporting the original findings. Here, we report results from a uniform spectral retrieval analysis of the three, independent, published spectra together with null hypothesis testing. Based on Bayesian model comparison, we find that two of the three spectra show strong evidence ($\geq$ 3.6$\sigma$) for the detection of molecular features mainly due to water and methane while the third is consistent with a weak molecular detection at the 2.2$\sigma$ level. We interpret the agreement in the spectral modulation established by previous authors and the atmospheric retrieval results presented here, as a confirmation of the original detection of molecular absorbers in the atmosphere of HD 189733b.Comment: Accepted to Ap

Water, High-Altitude Condensates, and Possible Methane Depletion in the Atmosphere of the Warm Super-Neptune WASP-107b

The super-Neptune exoplanet WASP-107b is an exciting target for atmosphere characterization. It has an unusually large atmospheric scale height and a small, bright host star, raising the possibility of precise constraints on its current nature and formation history. We report the first atmospheric study of WASP-107b, a Hubble Space Telescope measurement of its near-infrared transmission spectrum. We determined the planet's composition with two techniques: atmospheric retrieval based on the transmission spectrum and interior structure modeling based on the observed mass and radius. The interior structure models set a $3\,\sigma$ upper limit on the atmospheric metallicity of $30\times$ solar. The transmission spectrum shows strong evidence for water absorption ($6.5\,\sigma$ confidence), and the retrieved water abundance is consistent with expectations for a solar abundance pattern. The inferred carbon-to-oxygen ratio is subsolar at $2.7\,\sigma$ confidence, which we attribute to possible methane depletion in the atmosphere. The spectral features are smaller than predicted for a cloud-free composition, crossing less than one scale height. A thick condensate layer at high altitudes (0.1 - 3 mbar) is needed to match the observations. We find that physically motivated cloud models with moderate sedimentation efficiency ($f_\mathrm{sed} = 0.3$) or hazes with a particle size of 0.3 $\mu$m reproduce the observed spectral feature amplitude. Taken together, these findings serve as an illustration of the diversity and complexity of exoplanet atmospheres. The community can look forward to more such results with the high precision and wide spectral coverage afforded by future observing facilities.Comment: 10 pages, 4 figures; accepted to ApJ

A Systematic Retrieval Analysis of Secondary Eclipse Spectra III: Diagnosing Chemical Disequilibrium in Planetary Atmospheres

Chemical disequilibrium has recently become a relevant topic in the study of the atmospheres of of transiting extrasolar planets, brown dwarfs, and directly imaged exoplanets. We present a new way of assessing whether or not a Jovian-like atmosphere is in chemical disequilibrium from observations of detectable or inferred gases such as H_2 O, CH_4, CO, and H _2. Our hypothesis, based on previous kinetic modeling studies, is that cooler atmospheres will show stronger signs of disequilibrium than hotter atmospheres. We verify this with chemistry-transport models and show that planets with temperatures less than ~ 1200 K are likely to show the strongest signs of disequilibrium due to the vertical quenching of CO, and that our new approach is able to capture this process. We also find that in certain instances a planetary composition may appear in equilibrium when it actually is not due to the degeneracy in the shape of the vertical mixing ratio profiles. We determine the state of disequilibrium in eight exoplanets using the results from secondary eclipse temperature and abundance retrievals. We find that all of the planets in our sample are consistent with thermochemical equilibrium to within 3-sigma. Future observations are needed to further constrain the abundances in order to definitively identify disequilibrium in exoplanet atmospheres