Unconventional gas: potential energy market impacts in the European Union

In the interest of effective policymaking, this report seeks to clarify certain controversies and identify key gaps in the evidence-base relating to unconventional gas. The scope of this report is restricted to the economic impact of unconventional gas on energy markets. As such, it principally addresses such issues as the energy mix, energy prices, supplies, consumption, and trade flows. Whilst this study touches on coal bed methane and tight gas, its predominant focus is on shale gas, which the evidence at this time suggests will be the form of unconventional gas with the most growth potential in the short- to medium-term. This report considers the prospects for the indigenous production of shale gas within the EU-27 Member States. It evaluates the available evidence on resource size, extractive technology, resource access and market access. This report also considers the implications for the EU of large-scale unconventional gas production in other parts of the world. This acknowledges the fact that many changes in the dynamics of energy supply can only be understood in the broader global context. It also acknowledges that the EU is a major importer of energy, and that it is therefore heavily affected by developments in global energy markets that are largely out of its control.JRC.F.3-Energy securit

Trapping gases in metal-organic frameworks with a selective surface molecular barrier layer

The main challenge for gas storage and separation in nanoporous materials is that many molecules of interest adsorb too weakly to be effectively retained. Instead of synthetically modifying the internal surface structure of the entire bulk—as is typically done to enhance adsorption—here we show that post exposure of a prototypical porous metal-organic framework to ethylenediamine can effectively retain a variety of weakly adsorbing molecules (for example, CO, CO₂, SO₂, C₂H₂, NO) inside the materials by forming a monolayer-thick cap at the external surface of microcrystals. Furthermore, this capping mechanism, based on hydrogen bonding as explained by ab initio modelling, opens the door for potential selectivity. For example, water molecules are shown to disrupt the hydrogen-bonded amine network and diffuse through the cap without hindrance and fully displace/release the retained small molecules out of the metal-organic framework at room temperature. These findings may provide alternative strategies for gas storage, delivery and separation

Modeling Transportation Logistics, Water Use, and Surface Footprint for Shale Gas Field Developments

Abstract Optimizing operational efficiencies in unconventional resource developments is one of the key success drivers for improved economics. In this work, an approach for exactly that problem is presented, designed for a field development scenario in Germany. Starting with a model that captures all key parameters which are influencing a development program such as the gas market and prize scenarios, political situation, environmental regulations, logistical requirements, etc., it immediately turns out that the highly complex model has to be significantly simplified and a sub-model with clear and precise boundary conditions has to be generated. This sub-model is tuned to problems of particular interest, considering technological parameters such as the impact of various state of the art drilling technologies or different fracturing methodologies on the entire development program. It is possible to identify interrelations of various procedures and allows estimating project costs. Operational scenarios can also efficiently be tested, and validated and the financial key parameters of different scenarios can be compared. Moreover, short- and long-term benefits and drawbacks of various solutions can be assessed and optimized. Also, limitations of System Dynamics for that kind of simulation are pointed out, and it is shown how to solve the problem with an Agent Based Modeling approach.</jats:p