Revisiting Mt. Kilimanjaro : Do n-alkane biomarkers in soils reflect the δ2H isotopic composition of precipitation?

Abstract. During the last decade compound-specific deuterium (δ2H) analysis of plant leaf wax-derived n-alkanes has become a promising and popular tool in paleoclimate research. This is based on the widely accepted assumption that n-alkanes in soils and sediments generally reflect δ2H of precipitation (δ2Hprec). Recently, several authors suggested that δ2H of n-alkanes (δ2H,sub&gt;n-alkanes) can also be used as proxy in paleoaltimetry studies. Here we present results from a δ2H transect study (~1500 to 4000 m a.s.l.) carried out on precipitation and soil samples taken from the humid southern slopes of Mt. Kilimanjaro. Contrary to earlier suggestions, a distinct altitude effect in δ2Hprec is present above ~2000 m a.s.l., i.e. δ2Hprec values become more negative with increasing altitude. The compound-specific δ2H values of nC27 and nC29 do not confirm this altitudinal trend, but rather become more positive both in the O-layers (organic layers) and the Ah-horizons (mineral topsoils). Although our δ2Hn-alkane results are in agreement with previously published results from the southern slopes of Mt. Kilimanjaro (Peterse et al., 2009, BG, 6, 2799–2807), a major re-interpretation is required given that the δ2Hn-alkane results do not reflect the δ2Hprec results. The theoretical framework for this re-interpretation is based on the evaporative isotopic enrichment of leaf water associated with transpiration process. Modelling results show that relative humidity, decreasing considerably along the southern slopes of Mt. Kilimanjaro (from 78% at ~ 2000 m a.s.l. to 51% at 4000 m a.s.l.), strongly controls δ2Hleaf water. The modelled δ2H leaf water enrichment along the altitudinal transect matches well the measured 2H leaf water enrichment as assessed by using the δ2Hprec and δ2Hn-alkane results and biosynthetic fractionation during n-alkane biosynthesis in leaves. Given that our results clearly demonstrate that n-alkanes in soils do not simply reflect δ2Hprec but rather δ2Hleaf water, we conclude that care has to be taken not to over-interpret δ2Hn-alkane records from soils and sediments when reconstructing δ2H of paleoprecipitation. Both in paleoaltimetry and in paleoclimate studies changes in relative humidity and consequently in δ2Hn-alkane values can completely mask altitudinally or climatically-controlled changes in δ2Hprec. </jats:p

ERP hoch 3: Energieraumplanung entlang von ÖV-Achsen

Im Rahmen des national geförderten Forschungsprojekt „ERP_hoch3“ wird der Themenschwerpunkt Energieraumplanung in drei Fokusebenen betrachtet, untersucht und simuliert. Während „ERP“ für Energieraum-planung steht, steht die „3“ für drei verschiedene Raumbezüge – Stadtquartiere, öffentliche Verkehrsachsen und interkommunale Flächenpotenziale erneuerbarer Energien (Region). ERP_hoch3 ist ein zweijähriges Grundlagenforschungsprojekt, gefördert vom österreichischen Klimafonds. Das Forschungsteam besteht aus 14 Expertinnen und Experten der Fachbereiche für Regionalplanung und für örtliche Raumplanung (TU Wien, Department für Raumplanung) und der Institute für Städtebau und Prozess- und Partikeltechnik (TU Graz)

Novel methodological approaches in loess research – interrogating biomarkers and compound-specific stable isotopes

Löss-Paläoboden Sequenzen sind wichtige terrestrische Archive für die Rekonstruktion der quartären Landschafts- und Klimageschichte. Die Entwicklung neuer, quantitativerer Paläoklima-Proxies könnte in den kommenden Jahren eine neue Ära in der Lössforschung einleiten. Dieser Review-Artikel stellt die Prinzipien, die zugrunde liegende Analytik, und erste Anwendungsbeispiele für einige dieser Proxies vor, welche derzeit entwickelt werden. Wir diskutieren das Potential von (i) pflanzenwachsbürtigen n-Alkanen als Biomarker für die Rekonstruktion der Vegetationsgeschichte, (ii) Aminosäure Razemisierung und Glycerin-Dialkyl-Glycerin-Tetraether (GDGT) Indizes als Proxies für die Rekonstruktion der Paläotemperatur und (iii) substanzspezifischen δD and δ18O Analysen an pflanzenbürtigen n-Alkanen bzw. Zuckern für die Entwicklung von Proxies zur Rekonstruktion von Paläoklima/-aridität. Während wir versuchen, die Leserschaft für die methodischen und analytischen Neuentwicklungen und deren Potential für die Lössforschung zu begeistern, verweisen wir gleichzeitig auch auf die Limitierungen und Schwächen der jeweiligen Methoden. So müssen beispielsweise Degradationseffekte oder postsedimentäre ‚Kontamination’ bei der Interpretation von Biomarker-Rekords berücksichtigt und weiter untersucht werden. Des Weiteren könnte sich die Quantifizierung der unterschiedlichen Einflussfaktoren auf Deuterium- und 18O-Rekords als herausfordernd erweisen.researc

Next-generation sequencing and bioinformatics in rare movement disorders

The ability to sequence entire exomes and genomes has revolutionized molecular testing in rare movement disorders, and genomic sequencing is becoming an integral part of routine diagnostic workflows for these heterogeneous conditions. However, interpretation of the extensive genomic variant information that is being generated presents substantial challenges. In this Perspective, we outline multidimensional strategies for genetic diagnosis in patients with rare movement disorders. We examine bioinformatics tools and computational metrics that have been developed to facilitate accurate prioritization of disease-causing variants. Additionally, we highlight community-driven data-sharing and case-matchmaking platforms, which are designed to foster the discovery of new genotype-phenotype relationships. Finally, we consider how multiomic data integration might optimize diagnostic success by combining genomic, epigenetic, transcriptomic and/or proteomic profiling to enable a more holistic evaluation of variant effects. Together, the approaches that we discuss offer pathways to the improved understanding of the genetic basis of rare movement disorders. In this Perspective, Zech and Winkelmann outline multidimensional strategies for genetic diagnosis in patients with rare movement disorders and highlight community-driven data-sharing and case-matchmaking platforms designed to foster the discovery of new genotype-phenotype relationships

Two possible source regions for Central Greenland last glacial dust

Dust in Greenland ice cores is used to reconstruct the activity of dust-emitting regions and atmospheric circulation. However, the source of dust material to Greenland over the last glacial period is the subject of considerable uncertainty. Here we use new clay mineral and <10 µm Sr–Nd isotopic data from a range of Northern Hemisphere loess deposits in possible source regions alongside existing isotopic data to show that these methods cannot discriminate between two competing hypothetical origins for Greenland dust: an East Asian and/or central European source. In contrast, Hf isotopes (<10 µm fraction) of loess samples show considerable differences between the potential source regions. We attribute this to a first-order clay mineralogy dependence of Hf isotopic signatures in the finest silt/clay fractions, due to absence of zircons. As zircons would also be absent in Greenland dust, this provides a new way to discriminate between hypotheses for Greenland dust sources

Dopant clustering, electronic inhomogeneity, and vortex pinning in iron-based superconductors

We use scanning tunneling microscopy to map the surface structure, nanoscale electronic inhomogeneity, and vitreous vortex phase in the hole-doped superconductor Sr0.75K0.25Fe2As2 with Tc=32 K. We find that the low-T cleaved surface is dominated by a half Sr/K termination with 1×2 ordering and ubiquitous superconducting gap, while patches of gapless, unreconstructed As termination appear rarely. The superconducting gap varies by σ/Δ¯=16% on a ∼3 nm length scale, with average 2Δ¯/kBTc=3.6 in the weak-coupling limit. The vortex core size provides a measure of the superconducting coherence length ξ=2.3 nm. We quantify the vortex lattice correlation length at 9 T in comparison to several iron-based superconductors. The comparison leads us to suggest the importance of dopant size mismatch as a cause of dopant clustering, electronic inhomogeneity, and strong vortex pinning.Physic

Coupled Requirements-driven Testing of CPS: From Simulation To Reality

Failures in safety-critical Cyber-Physical Systems (CPS), both software and hardware-related, can lead to severe incidents impacting physical infrastructure or even harming humans. As a result, extensive simulations and field tests need to be conducted, as part of the verification and validation of system requirements, to ensure system safety. However, current simulation and field testing practices, particularly in the domain of small Unmanned Aerial Systems (sUAS), are ad-hoc and lack a thorough, structured testing process. Furthermore, there is a dearth of standard processes and methodologies to inform the design of comprehensive simulation and field tests. This gap in the testing process leads to the deployment of sUAS applications that are: (a) tested in simulation environments which do not adequately capture the real-world complexity, such as environmental factors, due to a lack of tool support; (b) not subjected to a comprehensive range of scenarios during simulation testing to validate the system requirements, due to the absence of a process defining the relationship between requirements and simulation tests; and (c) not analyzed through standard safety analysis processes, because of missing traceability between simulation testing artifacts and safety analysis artifacts. To address these issues, we have developed an initial framework for validating CPS, specifically focusing on sUAS and robotic applications. We demonstrate the suitability of our framework by applying it to an example from the sUAS domain. Our preliminary results confirm the applicability of our framework. We conclude with a research roadmap to outline our next research goals along with our current proposal

ExHaLe-jet: Modeling blazar jets with an extended hadro-leptonic radiation code

Blazars emit across all electromagnetic wavelengths. While the so-called one-zone model has described well both quiescent and flaring states, it cannot explain the radio emission and fails in more complex data sets, such as AP Librae. In order to self-consistently describe the entire electromagnetic spectrum emitted by the jet, extended radiation models are necessary. Notably, kinetic descriptions of extended jets can provide the temporal and spatial evolution of the particle species and the full electromagnetic output. Here, we present the initial results of a newly developed hadro-leptonic extended-jet code: ExHaLe-jet. As protons take much longer than electrons to lose their energy, they can transport energy over much larger distances than electrons and are therefore essential for the energy transport in the jet. Furthermore, protons induce injection of additional pairs through pion and Bethe-Heitler pair production, which can explain a dominant leptonic radiation signal while still producing neutrinos. In this talk, we discuss the differences between leptonic and hadronic dominated SED solutions, the SED shapes, evolution along the jet flow, and jet powers. We also highlight the important role of external photon fields, such as the accretion disk and the BLR.Comment: Proceedings paper to the GAMMA2022 conference held in Barcelona, Spain. To appear as PoS(Gamma2022)18