Catalytic behavior of chromium oxide supported on nanocasting-prepared mesoporous alumina in dehydrogenation of propane

Mesoporous alumina with narrow pore size distribution centered in the range of 4.4–5.0 nm and with a specific surface area as high as 270 m2·g−1 was prepared via the nanocasting approach using a CMK-3 carbon replica as a hard template. Based on this support, a series of catalysts containing 1, 5, 10, 20 and 30 wt % of chromium was prepared by incipient wetness impregnation, characterized, and studied in the dehydrogenation of propane to propene (PDH). Cr species in three oxidation states—Cr(III), Cr(V) and Cr(VI)—were found on the oxidized surface of the catalysts. The concentration of these species varied with the total Cr loading. Temperature-programmed reduction (H2-TPR) and UV-Vis diffuse reflectance spectroscopy (UV-Vis-DRS) studies revealed that Cr(VI) species dominated at the lowest Cr content. An increase in the Cr loading resulted in an appearance of an increasing amount of Cr(III) oxide. UV-Vis-DRS measurements performed in situ during the PDH process showed that at the beginning of the catalytic test Cr(VI) species were reduced to Cr(III) redox species. A crucial role of the redox species in the PDH process over the catalysts with the low Cr content was confirmed. The stability test for the catalyst containing 20 wt % of Cr showed that this sample exhibited the reproducible catalytic performance after the first four regeneration–dehydrogenation cycles. Moreover, this catalyst had higher resistance on deactivation during the PDH process as compared to the reference catalyst with the same Cr loading, but was supported on commercially available alumina

Influence of Co₂ on the Catalytic Performance Of La₂O₃/CeO₂ and CaO/CeO₂ Catalysts in the Oxidative Coupling of Methane

In this work the La2O3/CeO2 (33 mol % of La) and CaO/CeO2 (33 mol % of Ca) catalysts were prepared by the impregnation method and characterized by XRD and CO2-TPD. The catalytic properties of the catalysts were tested in the OCM process at 1073 K using the methane/oxygen mixture of the mole ratio 3.7 or 2.5 additionally containing CO2 and helium balance. It was found that in the presence of both catalysts an addition of CO2 enhances the selectivity to the ethylene and ethane and it does not have any negative influence on methane conversion. In the case of the CaO/CeO2 catalyst the promoting effect of CO2 was the highest. When the partial pressure of CO2 equals to 39 kPa the increase in selectivity from 36 to 41% was noted while the conversion of methane equal to 19.4-19.7 %.</jats:p

High-performance Cr–Zr–O and Cr–Zr–K–O catalysts prepared by nanocasting for dehydrogenation of propane to propene

Controlling the porosity and surface chemistry of Cr–Zr–O and Cr–Zr–K–O catalysts by nanocasting improved the yield of propene and their stability in the dehydrogenation of propane to propene.</p

Effect of dealumination on the catalytic performance of Cr-containing Beta zeolite in carbon dioxide assisted propane dehydrogenation

International audienceNew active and selective catalysts for propane to propene dehydrogenation in assistance of CO 2 (CO 2-PDH) were prepared by chromium incorporation in siliceous SiBeta. The Cr-containing SiBeta zeolite catalysts were obtained by two-step postsynthesis preparation procedure which consist, in the first step, removal of aluminum from TEABeta zeolite with Si/Al of 17 by treatment with nitric acid solution to obtain an aluminium-free Si-Beta support with Si/Al ratio of 1000 and, in the second step, various amounts of Cr were introduced into the siliceous SiBeta zeolite structure by wet impregnation. The well correlation between the number of redox Cr sites and propene yield up to 2 wt % of Cr has been determined. Comparing of catalytic activity of Cr-containing Beta zeolite catalysts with the identical Cr content (2 wt % of Cr) supported on SiBeta and AlBeta revealed that the dealumination has great impact on catalytic properties. Low acidity of SiBeta is suitable for achieving high selectivity to propene (above 80 %) while high acidity of starting AlBeta promotes propane cracking to lighter hydrocarbons. Moreover, in switch operation mode between propane dehydrogenation in presence and absence of CO 2 the formation rate of propene raises in mode with CO 2 only over Cr-containing SiBeta zeolite catalyst, while over Cr-containing AlBeta zeolite catalyst a negative effect on the rate of propene formation was observed