Theoretical aspects of vertical and lateral manipulation of atoms

Using total energy calculations, based on interaction potentials from the embedded atom method, we show that the presence of the tip not only lowers the barrier for lateral diffusion of the adatom towards it, but also shifts the corresponding saddle point. For a Cu adatom at a (100) microfacetted step on Cu(111) this shift is 0.6 A. The effect of the tip geometry and shape on the energetics of lateral manipulation was found to be subtle. In the case of vertical manipulation of a Cu adatom on flat, stepped, and kinked Cu surfaces we find an unusual but interesting result. It is found that as the tip approaches the surface, it becomes easier to extract the adatom from the stepped and kinked surfaces, as compared to the flat surface. This counter intuitive result can be explained in terms of tip induced changes in the bonding of the adatom to its low coordinated surroundings.Comment: 8figures, to appear in Surf. Sci., VAS10 proceeding

Swelling-collapse transition of self-attracting walks

We study the structural properties of self-attracting walks in d dimensions using scaling arguments and Monte Carlo simulations. We find evidence for a transition analogous to the \Theta transition of polymers. Above a critical attractive interaction u_c, the walk collapses and the exponents \nu and k, characterising the scaling with time t of the mean square end-to-end distance ~ t^{2 \nu} and the average number of visited sites ~ t^k, are universal and given by \nu=1/(d+1) and k=d/(d+1). Below u_c, the walk swells and the exponents are as with no interaction, i.e. \nu=1/2 for all d, k=1/2 for d=1 and k=1 for d >= 2. At u_c, the exponents are found to be in a different universality class.Comment: 6 pages, 5 postscript figure

The phase diagram of annealed Ge(111)/Ga

A study of the annealed phases of Ge(111)/Ga for coverages above 0.05 ML is presented. The surfaces are investigated by low-energy electron diffraction, scanning tunneling microscopy, and partly by photoemission and surface X-ray diffraction using synchrotron radiation. For Ga coverages beyond 0.05 ML and up to about 2 ML and annealing temperatures higher than 500 °C four different phases appear. They all can be characterized as being discommensurate. Surprisingly, no commensurate superstructure appears on annealed Ge(111)/Ga