Molar mass and solution conformation of branched alpha(1 - 4), alpha(1 - 6) Glucans. Part I: Glycogens in water

Solution molar masses and conformations of glycogens from different sources (rabbit, oyster, mussel and bovine) were analysed using sedimentation velocity in the analytical ultracentrifuge, size-exclusion chromatography coupled to multi-angle laser light scattering (SEC-MALLS), size-exclusion chromatography coupled to a differential pressure viscometer and dynamic light scattering. Rabbit, oyster and mussel glycogens consisted of one population of high molar mass (weight averages ranging from 4.6 x 106 to 1.1 x 107 g/mol) as demonstrated by sedimentation velocity and SEC-MALLS, whereas bovine glycogen had a bimodal distribution of significantly lower molar mass (1.0 x 105 and 4.5 x 105 g/mol). The spherical structure of all glycogen molecules was demonstrated in the slopes of the Mark-Houwink-Kuhn-Sakurada-type power-law relations for sedimentation coefficient (s20,wo), intrinsic viscosity ([η]), radius of gyration (rg,z) and radius of hydration (rH,z), respectively, and was further supported by the � (=rg,z/rH,z) function, the fractal dimension and the Perrin function. The degree of branching was estimated to be ∼10% from the shrinking factors, g′ (=[η]branched/[η]linear) and also h (=(f/fo)branched/(f/fo)linear), respectively, where (f/fo) is the translational frictional ratio, consistent with expectation. © 2007 Elsevier Ltd. All rights reserved

The Near-Infrared Broad Emission Line Region of Active Galactic Nuclei -- I. The Observations

We present high quality (high signal-to-noise ratio and moderate spectral resolution) near-infrared (near-IR) spectroscopic observations of 23 well-known broad-emission line active galactic nuclei (AGN). Additionally, we obtained simultaneous (within two months) optical spectroscopy of similar quality. The near-IR broad emission line spectrum of AGN is dominated by permitted transitions of hydrogen, helium, oxygen, and calcium, and by the rich spectrum of singly-ionized iron. In this paper we present the spectra, line identifications and measurements, and address briefly some of the important issues regarding the physics of AGN broad emission line regions. In particular, we investigate the excitation mechanism of neutral oxygen and confront for the first time theoretical predictions of the near-IR iron emission spectrum with observations.Comment: 45 pages, 17 figures, accepted by ApJ

Assessment of Variable-cycle Engines for Mach 2.7 Supersonic Transports

Three proposed SCAR propulsion systems in terms of aircraft range for a fixed payload and take-off gross weight with a design cruise Mach number 2.7 are evaluated. The effects of various noise and operational restraints are determined and sensitivities to some of the more important performance variables are presented for the most probable design noise and operational restraint case. Critical areas requiring new or improved technology for each cycle are delineated

Adaptive Optics Near-Infrared Spectroscopy of the Sgr A* Cluster

We present K-band $\lambda/\Delta\lambda$ ~ 2600 spectroscopy of five stars (K ~ 14 - 16 mag) within 0.''5 of Sgr A*, the radio source associated with the compact massive object suspected to be a 2.6 x 10$^{6}$ \msun black hole at the center of our Galaxy. High spatial resolution of ~ 0.''09, and good strehl ratios of ~ 0.2 achieved with adaptive optics on the 10-meter Keck telescope make it possible to measure moderate-resolution spectra of these stars individually for the first time. Two stars (S0-17 and S0-18) are identified as late-type stars by the detection of CO bandhead absorption in their spectra. Their absolute K magnitudes and CO bandhead absorption strengths are consistent with early K giants. Three stars (S0-1, S0-2, and S0-16), with r$_{proj}$ $<$ 0.0075 pc (~ 0.''2) from Sgr A*, lack CO bandhead absorption, confirming the results of earlier lower spectral and lower spatial resolution observations that the majority of the stars in the Sgr A* Cluster are early-type stars. The absolute K magnitudes of the early-type stars suggest that they are late O - early B main sequence stars of ages $<$ 20 Myr. The presence of young stars in the Sgr A* Cluster, so close to the central supermassive black hole, poses the intriguing problem of how these stars could have formed, or could have been brought, within its strong tidal field.Comment: 19 pages, 8 figures, 2 tables. Accepted for publication in Ap

Observations of ozone production in a dissipating tropical convective cell during TC4

From 13 July–9 August 2007, 25 ozonesondes were launched from Las Tablas, Panama as part of the Tropical Composition, Cloud, and Climate Coupling (TC4) mission. On 5 August, a strong convective cell formed in the Gulf of Panama. World Wide Lightning Location Network (WWLLN) data indicated 563 flashes (09:00–17:00 UTC) in the Gulf. NO2 data from the Ozone Monitoring Instrument (OMI) show enhancements, suggesting lightning production of NOx. At 15:05 UTC, an ozonesonde ascended into the southern edge of the now dissipating convective cell as it moved west across the Azuero Peninsula. The balloon oscillated from 2.5–5.1 km five times (15:12–17:00 UTC), providing a unique examination of ozone (O3) photochemistry on the edge of a convective cell. Ozone increased at a rate of 1.6–4.6 ppbv/hr between the first and last ascent, resulting cell wide in an increase of (2.1–2.5)×106 moles of O3. This estimate agrees to within a factor of two of our estimates of photochemical lightning O3 production from the WWLLN flashes, from the radar-inferred lightning flash data, and from the OMI NO2 data (1.2, 1.0, and 1.7×106 moles, respectively), though all estimates have large uncertainties. Examination of DC-8 in situ and lidar O3 data gathered around the Gulf that day suggests 70–97% of the O3 change occurred in 2.5–5.1 km layer. A photochemical box model initialized with nearby TC4 aircraft trace gas data suggests these O3 production rates are possible with our present understanding of photochemistry

Hyperfast Interstellar Travel in General Relativity

The problem is discussed of whether a traveller can reach a remote object and return back sooner than a photon would when taken into account that the traveller can partly control the geometry of his world. It is argued that under some reasonable assumptions in globally hyperbolic spacetimes the traveller cannot hasten reaching the destination. Nevertheless, it is perhaps possible for him to make an arbitrarily long round-trip within an arbitrarily short (from the point of view of a terrestrial observer) time.Comment: The final version, close to (but better than) what will be published in Phys. Rev. D. The explanatory part is made more detaile

Measurement of Antenna Surfaces from In- and Out-Of-Focus Beam Maps using Astronomical Sources

We present a technique for the accurate estimation of large-scale errors in an antenna surface using astronomical sources and detectors. The technique requires several out-of-focus images of a compact source and the signal-to-noise ratio needs to be good but not unreasonably high. For a given pattern of surface errors, the expected form of such images can be calculated directly. We show that it is possible to solve the inverse problem of finding the surface errors from the images in a stable manner using standard numerical techniques. To do this we describe the surface error as a linear combination of a suitable set of basis functions (we use Zernike polynomials). We present simulations illustrating the technique and in particular we investigate the effects of receiver noise and pointing errors. Measurements of the 15-m James Clerk Maxwell telescope made using this technique are presented as an example. The key result is that good measurements of errors on large spatial scales can be obtained if the input images have a signal-to-noise ratio of order 100 or more. The important advantage of this technique over transmitter-based holography is that it allows measurements at arbitrary elevation angles, so allowing one to characterise the large scale deformations in an antenna as a function of elevation.Comment: 6 pages, 5 figures (accepted by Astronomy & Astrophysics

QSO hosts and environments at z=0.9 to 4.2: JHK images with adaptive optics

We have observed nine QSOs with redshifts 0.85 to 4.16 at near-IR wavelengths with the adaptive optics bonnette of the Canada-France-Hawaii telescope. Exposure times ranged from 1500 to 24000s (mostly near 7000s) in J, H, or K bands, with pixels 0.035 arcsec on the sky. The FWHM of the co-added images at the location of the quasars are typically 0.16 arcsec. Including another QSO published previously, we find associated QSO structure in at least eight of ten objects, including the QSO at z = 4.16. The structures seen in all cases include long faint features which appear to be tidal tails. In four cases we have also resolved the QSO host galaxy, but find them to be smooth and symmetrical: future PSF removal may expand this result. Including one object previously reported, of the nine objects with more extended structure, five are radio-loud, and all but one of these appear to be in a dense small group of compact galaxy companions. The radio-quiet objects do not occupy the same dense environments, as seen in the NIR. In this small sample we do not find any apparent trends of these properties with redshift, over the range 0.8 < z < 2.4. The colors of the host galaxies and companions are consistent with young stellar populations at the QSO redshift. Our observations suggest that adaptive optic observations in the visible region will exhibit luminous signatures of the substantial star-formation activity that must be occurring.Comment: 22 pages including 10 tables, plus 11 figures. To appear in A

Galactic Center Youth: Orbits and Origins of the Young Stars in the Central Parsec

We present new proper motions for the massive, young stars at the Galactic Center, based on 10 years of diffraction limited data from the Keck telescopes. Our proper motion measurements now have uncertainties of only 1-2 km/s and allow us to explore the origin of the young stars that reside within the sphere of inflience of the supermassive black hole whose strong tidal forces make this region inhospitable for star formation. Their presence, however, may be explained either by in situ star formation in an accretion disk or as the remnants of a massive stellar cluster which spiraled in via dynamical friction. Earlier stellar velocity vectors were used to postulate that all the young stars resided in two counter-rotating stellar disks, which is consistent with both of the above formation scenarios. Our precise proper motions allow us, for the frst time, to determine the orbital parameters of each individual star and thereby to test the hypothesis that the massive stars reside in two stellar disks. Of the 26 young stars in this study that were previously proposed to lie on the inner, clockwise disk, we find that nearly all exhibit orbital constraints consistent with such a disk. On the other hand, of the 7 stars in this study previously proposed to lie in the outer, less well-defhed counter-clockwise disk, 6 exhibit inclinations that are inconsistent with such a disk, bringing into question the existence of the outer disk. Furthermore, for stars in the inner disk that have eccentricity constraints, we find several that have lower limits to the eccentricity of more than 0.4, implying highly eccentric orbits. This stands in contrast to simple accretion disk formation scenarios which typically predict predominantly circular orbits