CO adsorption on (111) and (100) surfaces of the Pt sub 3 Ti alloy. Evidence for parallel binding and strong activation of CO

The CO adsorption on a 40 atom cluster model of the (111) surface and a 36 atom cluster model of the (100) surface of the Pt3Ti alloy was studied. Parallel binding to high coordinate sites associated with Ti and low CO bond scission barriers are predicted for both surfaces. The binding of CO to Pt sites occurs in an upright orientation. These orientations are a consequence of the nature of the CO pi donation interactions with the surface. On the Ti sites the orbitals donate to the nearly empty Ti 3d band and the antibonding counterpart orbitals are empty. On the Pt sites, however, they are in the filled Pt 5d region of the alloy band, which causes CO to bond in a vertical orientation by 5 delta donation from the carbon end

Preliminary testing of a prototype portable X-ray fluorescence spectrometer

A portable X-ray fluorescence spectrometer for use as an analyzer in mineral resource investigative work was built and tested. The prototype battery powered spectrometer, measuring 11 by 12 by 5 inches and weighing only about 15 pounds, was designed specifically for field use. The spectrometer has two gas proportional counters and two radioactive sources, Cd (10a) and Fe (55). Preliminary field and laboratory tests on rock specimens and rock pulps have demonstrated the capability of the spectrometer to detect 33 elements to date. Characteristics of the system present some limitations, however, and further improvements are recommended

Determining the underlying Fermi surface of strongly correlated superconductors

The notion of a Fermi surface (FS) is one of the most ingenious concepts developed by solid state physicists during the past century. It plays a central role in our understanding of interacting electron systems. Extraordinary efforts have been undertaken, both by experiment and by theory, to reveal the FS of the high temperature superconductors (HTSC), the most prominent strongly correlated superconductors. Here, we discuss some of the prevalent methods used to determine the FS and show that they lead generally to erroneous results close to half filling and at low temperatures, due to the large superconducting gap (pseudogap) below (above) the superconducting transition temperature. Our findings provide a perspective on the interplay between strong correlations and superconductivity and highlight the importance of strong coupling theories for the characterization as well as the determination of the underlying FS in ARPES experiments

International Stock Market Efficiency: A Non-Bayesian Time-Varying Model Approach

This paper develops a non-Bayesian methodology to analyze the time-varying structure of international linkages and market efficiency in G7 countries. We consider a non-Bayesian time-varying vector autoregressive (TV-VAR) model, and apply it to estimate the joint degree of market efficiency in the sense of Fama (1970, 1991). Our empirical results provide a new perspective that the international linkages and market efficiency change over time and that their behaviors correspond well to historical events of the international financial system.Comment: 21 pages, 2 tables, 6 figure

Development and evaluation of the elastic recovery concept for expandable space structures

Elastic recovery of expandable space structure

X-ray Insights into the Nature of Quasars with Redshifted Broad Absorption Lines

We present $Chandra$ observations of seven broad absorption line (BAL) quasars at $z=0.863$-2.516 with redshifted BAL troughs (RSBALs). Five of our seven targets were detected by $Chandra$ in 4-13 ks exposures with ACIS-S. The $\alpha_{\rm ox}$ values, $\Delta\alpha_{\rm ox}$ values, and spectral energy distributions of our targets demonstrate they are all X-ray weak relative to expectations for non-BAL quasars, and the degree of X-ray weakness is consistent with that of appropriately-matched BAL quasars generally. Furthermore, our five detected targets show evidence for hard X-ray spectral shapes with a stacked effective power-law photon index of $\Gamma_{\rm eff}=0.5^{+0.5}_{-0.4}$. These findings support the presence of heavy X-ray absorption ($N_{\rm H}\approx 2 \times 10^{23}$ cm$^{-2}$) in RSBAL quasars, likely by the shielding gas found to be common in BAL quasars more generally. We use these X-ray measurements to assess models for the nature of RSBAL quasars, finding that a rotationally-dominated outflow model is favored while an infall model also remains plausible with some stipulations. The X-ray data disfavor a binary quasar model for RSBAL quasars in general.Comment: 11 pages, 5 figures, and 3 table

The physical gravitational degrees of freedom

When constructing general relativity (GR), Einstein required 4D general covariance. In contrast, we derive GR (in the compact, without boundary case) as a theory of evolving 3-dimensional conformal Riemannian geometries obtained by imposing two general principles: 1) time is derived from change; 2) motion and size are relative. We write down an explicit action based on them. We obtain not only GR in the CMC gauge, in its Hamiltonian 3 + 1 reformulation but also all the equations used in York's conformal technique for solving the initial-value problem. This shows that the independent gravitational degrees of freedom obtained by York do not arise from a gauge fixing but from hitherto unrecognized fundamental symmetry principles. They can therefore be identified as the long-sought Hamiltonian physical gravitational degrees of freedom.Comment: Replaced with published version (minor changes and added references

The Arecibo 430-MHz Intermediate Galactic Latitude Survey: Discovery of Nine Radio Pulsars

We have used the Arecibo Radio Telescope to search for millisecond pulsars in two intermediate Galactic latitude regions (7 deg < | b | < 20 deg) accessible to this telescope. For these latitudes the useful millisecond pulsar search volume achieved by Arecibo's 430-MHz beam is predicted to be maximal. Searching a total of 130 square degrees, we have discovered nine new pulsars and detected four previously known objects. We compare the results of this survey with those of other 430-MHz surveys carried out at Arecibo and of an intermediate latitude survey made at Parkes that included part of our search area; the latter independently found two of the nine pulsars we have discovered. At least six of our discoveries are isolated pulsars with ages between 5 and 300 Myr; one of these, PSR J1819+1305, exhibits very marked and periodic nulling. We have also found a recycled pulsar, PSR J2016+1948. With a rotational period of 65 ms, this is a member of a binary system with a 635-day orbital period. We discuss some of the the properties of this system in detail, and indicate its potential to provide a test of the Strong Equivalence Principle. This pulsar and PSR J0407+16, a similar system now being timed at Arecibo, are by far the best systems known for such a test.Comment: Accepted for publication in ApJ Referee format: 22 pages, 7 figure

Evolution of rarefaction pulses into vortex rings

The two-dimensional solitary waves of the Gross-Pitaevskii equation in the Kadomtsev-Petviashvili limit are unstable with respect to three-dimensional perturbations. We elucidate the stages in the evolution of such solutions subject to perturbations perpendicular to the direction of motion. Depending on the energy (momentum) and the wavelength of the perturbation different types of three-dimensional solutions emerge. In particular, we present new periodic solutions having very small energy and momentum per period. These solutions also become unstable and this secondary instability leads to vortex ring nucleation.Comment: 5 pages, 5 figure