Synthesis of molybdenum oxide nanoparticles by nanosecond laser ablation

Phothermal therapy (PTT) is one of the most promising techniques to treat cancer. Finding the ideal PTT agent nanomaterial has remained a challenge and has brought the interest of several researchers. In this work, we report the synthesis of molybdenum oxide (MoOx) nanoparticles (NPs), which exhibit absorption in the biological optical window ~840 nm, by using the laser ablation of solids in liquids (LASL) technique with nanosecond (ns) pulses. A Nd:YAG laser was used to synthesize the NPs in deionized (DI) water, free of surfactants or additives, which were optically characterized by absorption spectroscopy and TEM-EDX microscopy. Semi spherical NPs with a suitable average size and shape for potential use as PTT agents were obtained by laser ablation and ablation + fragmentation. The calculated band gap is 3.1 eV, which corresponds to MoO3. Micro-Raman spectroscopy studies determined that these NPs are composed of amorphous molybdenum oxide hydrates (MoO3 · xH2O)

Influence of oxygen pressure on the fs laserinduced oxidation of molybdenum thin films

We present a study of femtosecond (1028 nm, 230 fs, 54.7 MHz) laser processing on molybdenum (Mo) thin films. Irradiations were done under ambient air as well as pure oxygen (O2) at various gauge pressures (4, 8, 12 and 16 psi). Our results indicate that the high heating rates associated with laser processing allow the production of different molybdenum oxides. Raman spectroscopy and scanning electron microscopy are used to characterize the molybdenum oxidation for the different irradiation and oxygen pressures parameters chosen showing a high correlation between well-defined oxidation zones and the oxygen pressure surrounding the samples during the irradiation of the Mo thin films

Long-range correlations and trends in Colombian seismic time series

We study long-range correlations and trends in time series extracted from the data of seismic events occurred from 1973 to 2011 in a rectangular region that contains mainly all the continental part of Colombia. The long-range correlations are detected by the calculation of the Hurst exponents for the time series of interevent intervals, separation distances, depth differences and magnitude differences. By using a modification of the classical $R/S$ method that has been developed to detect short-range correlations in time series, we find the existence of persistence for all the time series considered except for magnitude differences. We find also, by using the $DFA$ until the third order, that the studied time series are not influenced by trends. Additionally, an analysis of the Hurst exponent as a function of the number of events in the time and the maximum window size is presented.Comment: 21 pages, 6 figures, 2 figures added, types corrected, accepted to be published in Physica

Realization of an all-optical zero to π cross-phase modulation jump

We report on the experimental demonstration of an all-optical π cross-phase modulation jump. By performing a preselection, an optically induced unitary transformation, and then a postselection on the polarization degree of freedom, the phase of the output beam acquires either a zero or π phase shift (with no other possible values). The postselection results in optical loss in the output beam. An input state may be chosen near the resulting phase singularity, yielding a pi phase shift even for weak interaction strengths. The scheme is experimentally demonstrated using a coherently prepared dark state in a warm atomic cesium vapor

Path integral approach to no-Coriolis approximation in heavy-ion collisions

We use the two time influence functional method of the path integral approach in order to reduce the dimension of the coupled-channels equations for heavy-ion reactions based on the no-Coriolis approximation. Our method is superior to other methods in that it easily enables us to study the cases where the initial spin of the colliding particle is not zero. It can also be easily applied to the cases where the internal degrees of freedom are not necessarily collective coordinates. We also clarify the underlying assumptions in our approach.Comment: 11 pages, Latex, Phys. Rev. C in pres

Estimaci?n de par?metros para un modelo de regresi?n difusa simple

88 p. Recurso Electr?nic