NONLINEAR POLARIZATION SPECTROSCOPY (FREQUENCY DOMAIN) STUDIES OF EXCITED STATE PROCESSES: THE B800–850ANTENNA OF RHODOBACTER SPHAEROIDES

Nonlinear polarization spectroscopy in the frequency domain allows rate constant determinations of fast electronic energy and phase relaxations together with characterization of the type of line broadening. Application of this method to the B850 component of the isolated B800–850antenna ofRhodobacter sphaeroides at room temperature shows that B850 is inhomogeneously broadened, with homogeneous widths between 30 and 200 cm−1, depending on the spectral position of the subforms. The corresponding phase relaxation times are clearly in the subpicosecond range. There is also indication of an up-to-now unspecified1–5 ps energy relaxation channel per subunit

Multiple Andreev reflections as a transport problem in energy space

We present an approach for analyzing the dc current in voltage biased quantum superconducting junctions. By separating terms from different $n$-particle processes, we find that the $n$-particle current can be mapped on the problem of wave transport through a potential structure with $n$ barriers. We discuss the relation between resonances in such structures and the subgap structures in the current-voltage characteristics. At zero temperature we find, exactly, that only processes creating real excitations contribute to the current. Our results are valid for a general SXS-junction, where the X-region is an arbitrary non-superconducting region described by an energy-dependent transfer matrix.Comment: 11 pages, 4 figures, submitted to Superlattices and Microstructure

Transitions between "π\pi" and "0" states in superconductor -- ferromagnet -- superconductor junctions

Experimental and theoretical study of superconductor (S) -- ferromagnet (F) -- superconductor junctions showed that in certain range of parameters (e.g., the length of the ferromagnet $d_F$, the exchange field, $E_{\rm ex}$) the ground state of a SFS junction corresponds to superconducting phase difference $\pi$ or 0. The phase diagram of a SFS junction with the respect to $\pi$ and 0 states is investigated in this letter in $E_{\rm ex}, d_{F}, T$ space. It is shown that the phase diagram is very sensitive to the geometry of the system, in particular, to the amount of disorder.Comment: Minor changes. References adde

Non-equilibrium current noise in mesoscopic disordered SNS junctions

Current noise in superconductor-normal metal-superconductor (SNS) junctions is calculated within the scattering theory of multiple Andreev reflections (MAR). It is shown that the noise exhibits subharmonic gap singularities at $eV=2\Delta/n$, $n=1,2,...$ both in single-mode junctions with arbitrary transparency $D$ and in multi-mode disordered junctions. The subharmonic structure is superimposed with monotonic increase of the effective transferred charge $q^*=S_I(0)/2I$ with decreasing bias voltage. Other features of the noise include a step-like increase of $q^*$ in junctions with small $D$, and a divergence $S_I(0) \propto V^{-1/2}$ at small voltages and excess noise $S_{ex} = 2eI_{ex}$, where $I_{ex}$ is the excess current, at large voltages, in junctions with diffusive transport.Comment: 5 page

PHOTOCHEMISTRY OF PHYCOBILIPROTEINS

Native PEC from the cyanobacterium, Mastigocladus laminosus, and its isolated α-subunit show photoreversibly photochromic reactions with difference-maxima around 502 and 570 nm in the spectral region of the α-84 phycoviolobilin chromophore. (b) Native PEC and its β-subunit show little if any reversible photochemistry in the 600–620 nm region, where the phycocyanobilin chromophores on the β-subunit absorb maximally, (c) Reversible photochemistry is retained in ureadenatured PEC at pH = 7.0 or pH ≤ 3. The difference maxima are shifted to 510 and 600 nm, and the amplitudes are decreased. An irreversible absorbance increase occurs around 670 nm (pH ≤ 3). (d) The amplitude of the reversible photoreaction difference spectrum is maximum in the presence of 4–5 M urea or 1 M KSCN, conditions known to dissociate phycobiliprotein aggregates into monomers. At the same time, the phycocyanobilin chromophore(s) are bleached irreversibly, (e) The amplitude becomes very small in high aggregates, e.g. in phycobilisomes. (f) In a reciprocal manner, the phototransformation of native PEC leads to a reversible shift of its aggregation equilibrium between trimer and monomer. The latter is favored by orange, the former by green light, (g) It is concluded that the phycoviolobilin chromophore of PEC is responsible for reversible photochemistry in PEC, and that there is not only an influence of aggregation state on photochemistry, but also vice versa an effect of the status of the chromophore on aggregation state. This could constitute a primary signal in the putative function as sensory pigment, either directly, or indirectly via the release of other polypeptides, via photodynamic effects, or the like

Regionale voedselketen : eindrapportage fase I

Sinds 2005 wordt door Ruraal Park en Groene Hoed gewerkt aan het opzetten van een volledige regionale keten voor versproducten in de regio Amsterdam. Ter realisatie van het regionale keten concept hebben Ruraal Park en Groene Hoed samengewerkt met verswinkel Marqt. Inmiddels is de opening van een eerste winkel in Amsterdam bewerkstelligd. Producenten zijn hiermee niet langer de uitwisselbare factor in de productieketen. Agrarische producenten zijn verenigd in een stichting, die partner is binnen een marktformule waar met name verse producten uit de regio worden aangeboden. Er is een nieuwe, stabiele productieketen van regionaal geproduceerde producten gerealiseerd. Deze rapportage beschrijft de opzet van het project ‘Regionale keten versproducten’ en beschrijft welke werkzaamheden zijn verricht. Speciale aandacht wordt geschonken aan opgedane ervaringen, lessen en inzichten die generiek en daarmee overdraagbaar zijn

FLUORESCENCE AND CIRCULAR DICHROISM STUDIES ON THE PHYCOERYTHROCYANINS FROM THE CYANOBACTERIUM

Two phycoerythrocyanin (PEC) fractions have been obtained from the phycobilisomes of the cyanobac-terium Westiellopsis prolifica ARM 365. They have been characterized by absorption, fluorescence and circular dichroism spectroscopy. One of them is spectroscopically similar to a PEC trimer known from other organisms. Whereas efficient energy transfer from its violin (α-84) to the cyanin (β-84, 155) chromophores is efficient in the trimer (αβ it is impeded after dissociation to the monomer (α,β). A second fraction of PEC which we earlier termed PEC(X) (Maruthi Sai et al., Photochem. Photobiol. 55,119–124, 1992), exhibited the spectral properties similar to that of the α-subunit of PEC from Mastigocladus laminosus. With this highly photoactive fraction, the circular dichroism spectra of the violobilin chromophore in both photoreversible states were obtained