Electronic and structural properties of alkali doped SWNT

Comprehensive experiments on structural and transport properties of alkali intercalated single walled carbon nanotubes (SWNT) are presented. The increasing electron density was measured as a shift of the Drude-edge in optical reflectivity in-situ with progressive doping. In saturation-doped samples the Drude-edge shifts into the visible (to 25,000 - 30,000 cm— 1 for potassium and rubidium doped samples) and the samples have a golden-brown color, similar to stage I graphite. X-ray diffraction reveals a crystalline rope structure with expanded lattice constant, similar to results of Duclaux et al. The change in the low temperature divergence of the resistivity after degassing at high temperature and high vacuum and after K-doping is studied in-situ

Ordered low-temperature structure in K4C60 detected by infrared spectroscopy

Infrared spectra of a K4C60 single-phase thin film have been measured between room temperature and 20 K. At low temperatures, the two high-frequency T1u modes appear as triplets, indicating a static D2h crystal-field stabilized Jahn-Teller distortion of the (C60)4- anions. The T1u(4) mode changes into the known doublet above 250 K, a pattern which could have three origins: a dynamic Jahn-Teller effect, static disorder between "staggered" anions, or a phase transition from an orientationally-ordered phase to one where molecular motion is significant.Comment: 4 pages, 2 figures submitted to Phys. Rev.

Semiclassical analysis of defect sine-Gordon theory

The classical sine-Gordon model is a two-dimensional integrable field theory, with particle like solutions the so-called solitons. Using its integrability one can define its quantum version without the process of canonical quantization. This bootstrap method uses the fundamental propterties of the model and its quantum features in order to restrict the structure of the scattering matrix as far as possible. The classical model can be extended with integrable discontinuities, purely transmitting jump-defects. Then the quantum version of the extended model can be determined via the bootstrap method again. But the outcoming quantum theory contains the so-called CDD uncertainity. The aim of this article is to carry throw the semiclassical approximation in both the classical and the quantum side of the defect sine-Gordon theory. The CDD ambiguity can be restricted by comparing the two results. The relation between the classical and quantum parameters as well as the resoncances appeared in the spectrum are other objectives

Charge transfer and Fermi level shift in p-doped single-walled carbon nanotubes

The electronic properties of p-doped single-walled carbon nanotube (SWNT) bulk samples were studied by temperature-dependent resistivity and thermopower, optical reflectivity, and Raman spectroscopy. These all give consistent results for the Fermi level downshift (Delta E(F)) induced by doping. We find Delta E(F) approximate to 0.35 eV and 0.50 eV for concentrated nitric and sulfuric acid doping respectively. With these values, the evolution of Raman spectra can be explained by variations in the resonance condition as E(F) moves down into the valence band. Furthermore, we find no evidence for diameter-selective doping, nor any distinction between doping responses of metallic and semiconducting tubes

Some aspects of mathematical and chemical modeling of complex chemical processes

Some theoretical questions involved in the mathematical modeling of the kinetics of complex chemical process are discussed. The analysis is carried out for the homogeneous oxidation of ethylbenzene in the liquid phase. Particular attention is given to the determination of the general characteristics of chemical systems from an analysis of mathematical models developed on the basis of linear algebra

Small oscillations of a chiral Gross-Neveu system

We study the small oscillations regime (RPA approximation) of the time-dependent mean-field equations, obtained in a previous work, which describe the time evolution of one-body dynamical variables of a uniform Chiral Gross-Neveu system. In this approximation we obtain an analytical solution for the time evolution of the one-body dynamical variables. The two-fermion physics can be explored through this solution. The condition for the existence of bound states is examined.Comment: 21pages, Latex, 1postscript figur