Cretaceous tectonics and gold mineralisation in the Otago Schist, New Zealand

This paper provides a regional-scale background for understanding gold-mineralising processes in the Otago Schist during the Cretaceous. At this time the schist belt was in the latter stages of formation as an accretionary complex with 2000 km strike length on the Pacific margin of Gondwana. The Otago Schist is interpreted as an exhumed accretionary wedge of structurally stacked clastic metasedimentary rocks with minor metabasic rocks. Metamorphic grade reached upper greenschist facies. Gold and other related elements were mobilised from the metasedimentary rocks during metamorphism, and these elements contributed to the high levels of orogenic gold endowment (>18 million ounces in the schist belt. Mesozoic Gold deposits were emplaced in two distinct pulses, one at the beginning of the Early Cretaceous (~140-135 Ma) and the other at the end of the Early Cretaceous (~112-100 Ma). These mineralising pulses were driven by regional tectonic events that may have involved episodic underplating of subducting material, and/or subduction of spreading ridges. The earlier event was most closely associated with metamorphic processes that mobilised gold from the accreted metasediments during convergent tectonics, and appears to have been the more economically significant. The later event took place as accretionary processes ceased and the Zealandia portion of Gondwana began to undergo intracontinental rifting

Noble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New Zealand

The world-class Macraes orogenic gold deposit (∼10 Moz resource) formed during the late metamorphic uplift of a metasedimentary schist belt in southern New Zealand. Mineralising fluids, metals and metalloids were derived from within the metasedimentary host. Helium and argon extracted from fluid inclusions in sulphide mineral grains (three crush extractions from one sample) have crustal signatures, with no evidence for mantle input (R/Ra = 0.03). Xenon extracted from mineralised quartz samples provides evidence for extensive interaction between fluid and maturing organic material within the metasedimentary host rocks, with 132Xe/36Ar ratios up to 200 times greater than air. Similarly, I/Cl ratios for fluids extracted from mineralised quartz are similar to those of brines from marine sediments that have interacted with organic matter and are ten times higher than typical magmatic/mantle fluids. The Macraes mineralising fluids were compositionally variable, reflecting either mixing of two different crustal fluids in the metasedimentary pile or a single fluid type that has had varying degrees of interaction with the host metasediments. Evidence for additional input of meteoric water is equivocal, but minor meteoric incursion cannot be discounted. The Macraes deposit formed in a metasedimentary belt without associated coeval magmatism, and therefore represents a purely crustal metamorphogenic end member in a spectrum of orogenic hydrothermal processes that can include magmatic and/or mantle fluid input elsewhere in the world. There is no evidence for involvement of minor intercalated metabasic rocks in the Macraes mineralising system. Hydrothermal fluids that formed other, smaller, orogenic deposits in the same metamorphic belt have less pronounced noble gas and halogen evidence for crustal fluid-rock interaction than at Macraes, but these deposits also formed from broadly similar metamorphogenic processes

Grain boundary dissolution porosity in quartzofeldspathic ultramylonites: Implications for permeability enhancement and weakening of mid-crustal shear zones

Quartzofeldspathic ultramylonites from the Alpine Fault Zone, one of the world's major, active plate boundary-scale fault zones have quartz crystallographic preferred orientations (CPO) and abundant low-angle (10° misorientation) are decorated by faceted pores, commonly with uniformly-oriented pyramidal shapes. Only grain boundaries with >10° misorientation angles in polymineralic aggregates are decorated by pores. Mean grain boundary pore densities are ~5 × 108 cm-2. Grain boundary pores are dissolution pits generated during syn-deformational transient grain boundary permeability, nucleating on dislocation traces at dilatant grain boundary interfaces. They have not been removed by subsequent grain boundary closure or annealing. Pore decoration could have led to grain boundary pinning, triggering a switch in the dominant deformation mechanism to grain boundary sliding, which is supported by evidence of CPO destruction in matrix quartz. Pore-decorated grain boundaries have significantly reduced surface area available for adhesion and cohesion, which would reduce the tensile and shear strength of grain boundaries, and hence, the bulk rock. Grain boundary decoration also significantly decreased the mean distance between pores, potentially facilitating dynamic permeability. Consequently, these microstructures provide a new explanation for strain weakening and evidence of fluid flow along grain boundaries in mylonites at mid-crustal conditions