Geochemical analysis of bulk marine sediment by Inductively Coupled Plasma–Atomic Emission Spectroscopy on board the JOIDES Resolution

Geochemical analyses on board the JOIDES Resolution have been enhanced with the addition of a Jobin-Yvon Ultrace inductively coupled plasma-atomic emission spectrometer (ICP-AES) as an upgrade from the previous X-ray fluorescence facility. During Leg 199, we sought to both challenge and utilize the capabilities of the ICP-AES in order to provide an extensive bulk-sediment geochemical database during the cruise. These near real-time analyses were then used to help characterize the recovered sedimentary sequences, calculate mass accumulation rates of the different sedimentary components, and assist with cruise and postcruise sampling requests. The general procedures, sample preparation techniques, and basic protocol for ICP-AES analyses on board ship are outlined by Murray et al. (2000) in Ocean Drilling Program Tech Note, 29. We expand on those concepts and offer suggestions for ICP-AES methodology, calibration by standard reference materials, data reduction procedures, and challenges that are specific to the analysis of bulk-sediment samples. During Leg 199, we employed an extensive bulk-sediment analytical program of ~600 samples of varying lithologies, thereby providing several opportunities for refinement of techniques. We also discuss some difficulties and challenges that were faced and suggest how to alleviate such occurrences for sedimentary chemical analyses during future legs

The use of dynamic elastomeric fabric orthosis suits as an orthotic intervention in the management of children with neuropathic onset scoliosis: A retrospective audit of routine clinical case notes

BACKGROUND: To date the main treatment approach for neuropathic onset scoliosis has utilised thoracic lumbar sacral orthoses (TLSO) to stabilize the spine and enable stable sitting. Dynamic elastomeric fabric orthoses (DEFOs) may achieve both of these aims if used as an early intervention. Due to a lack of evidence in this area, a retrospective audit of case notes was undertaken to understand current orthotic practice investigating the usage, outcomes and clinical characteristics of treated children with neuropathic onset scoliosis. Clinical notes of 180 children at risk for, or identified with, scoliosis were audited using a search matrix to identify diagnostic group, spinal muscle tone, Gross Motor Functional Classification Scale (GMFCS) level, orthotic treatment modalities, scoliosis specific data, surgical interventions, adaptive technologies used, and outcome measurements reported. RESULTS: Of the 180 notes examined, 85 were male; mean age nine years one month [SD four years seven months]. Spinal muscle tone was reported in 137 cases: 122/137 presented as low tone, 4/137 high tone, 6/137 fluctuating tone and 5/137 typical tone. Scoliosis was confirmed in (77/180) of whom (39/77) used a DEFO. Another (43/180) had a spinal curve developing, of whom (22/43) used a DEFO. The remaining (60/180) had no report of spinal curvature, but used a DEFO as a preventative measure. GMFCS scores were reported for 49 children of whom 14/49 were graded as level 4 and 17/49 level 5. Of the children with scoliosis who had spinal curve shapes reported, 48/60 had a C-shape presentation and 12/60 had an S-shape. CONCLUSIONS: The findings confirm previously reported papers in children with neuropathic onset scoliosis in relation to curve shape and GMFCS levels. It provides some evidence of the role DEFOs may have in the management of these children, and highlights the need for further research in this area due to the lack of peer-reviewed publications

The leading digit distribution of the worldwide Illicit Financial Flows

Benford's law states that in data sets from different phenomena leading digits tend to be distributed logarithmically such that the numbers beginning with smaller digits occur more often than those with larger ones. Particularly, the law is known to hold for different types of financial data. The Illicit Financial Flows (IFFs) exiting the developing countries are frequently discussed as hidden resources which could have been otherwise properly utilized for their development. We investigate here the distribution of the leading digits in the recent data on estimates of IFFs to look for the existence of a pattern as predicted by Benford's law and establish that the frequency of occurrence of the leading digits in these estimates does closely follow the law.Comment: 13 pages, 10 figures, 6 tables, additional data analyi

Diversité des familles de radiolaires au cours du temps

L’examen de la biodiversité des radiolaires, au niveau de la famille au cours du Phanérozoïque révèle quelques tendances générales connues chez d’autres groupes d’organismes, surtout dans le plancton, alors que d’autres tendances leur sont particulières. La crise permo-triasique, l’une des plus importantes dans l’évolution des organismes marins, est marquée chez les radiolaires par l’extinction de deux familles (Albaillellaria et Latentifistularia) vers la fin du Permien, mais surtout par une énorme diversification des spumellaires et nassellaires au Trias inférieur et moyen. La diversité des radiolaires s’accroît du Cambrien au Jurassique, reste relativement stable au Crétacé et décroît légèremen

Sediment mixing in the tropical Pacific and radiolarian stratigraphy

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/95542/1/ggge2290.pd

Benford's law predicted digit distribution of aggregated income taxes: the surprising conformity of Italian cities and regions

The yearly aggregated tax income data of all, more than 8000, Italian municipalities are analyzed for a period of five years, from 2007 to 2011, to search for conformity or not with Benford's law, a counter-intuitive phenomenon observed in large tabulated data where the occurrence of numbers having smaller initial digits is more favored than those with larger digits. This is done in anticipation that large deviations from Benford's law will be found in view of tax evasion supposedly being widespread across Italy. Contrary to expectations, we show that the overall tax income data for all these years is in excellent agreement with Benford's law. Furthermore, we also analyze the data of Calabria, Campania and Sicily, the three Italian regions known for strong presence of mafia, to see if there are any marked deviations from Benford's law. Again, we find that all yearly data sets for Calabria and Sicily agree with Benford's law whereas only the 2007 and 2008 yearly data show departures from the law for Campania. These results are again surprising in view of underground and illegal nature of economic activities of mafia which significantly contribute to tax evasion. Some hypothesis for the found conformity is presented.Comment: 18 pages, 5 tables, 4 figures, 61 references, To appear in European Physical Journal

CEO Profile and Earnings Quality

This paper introduces the PSCORE, which aggregates nine personal characteristics of chief executive officers (CEOs), to signal the quality of earnings. The PSCORE is a composite score based on publicly available data on CEOs. The study reports strong positive relationships between the PSCORE and two different proxies for earnings quality, (i) discretionary accruals and (ii) financial statement errors, measured by deviations of the first digits of figures reported in financial statements from those expected by Benford’s Law. Further analyses indicate that the relationships between the PSCORE and the proxies for earnings quality become more pronounced when CEOs have high equity-based compensation incentives. The findings have some implications for practitioners

Seismic interpretation of pelagic sedimentation regimes in the 18–53 Ma eastern equatorial Pacific : basin-scale sedimentation and infilling of abyssal valleys

Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 12 (2011): Q03004, doi:10.1029/2010GC003347.Understanding how pelagic sediment has been eroded, transported, and deposited is critical to evaluating pelagic sediment records for paleoceanography. We use digital seismic reflection data from an Integrated Ocean Drilling Program site survey (AMAT03) to investigate pelagic sedimentation across the eastern-central equatorial Pacific, which represents the first comprehensive record published covering the 18–53 Ma eastern equatorial Pacific. Our goals are to quantify (1) basin-hill-scale primary deposition regimes and (2) the extent to which seafloor topography has been subdued by abyssal valley-filling sediments. The eastern Pacific seafloor consists of a series of abyssal hills and basins, with minor late stage faulting in the basement. Ocean crust rarely outcrops at the seafloor away from the rise crest; both hills and basins are sediment covered. The carbonate compensation depth is identified at 4440 m by the appearance of acoustically transparent clay intervals in the seismic data. Overall, we recognized three different sedimentation regimes: depositional (high sedimentation rate), transitional, and minimal sedimentation (low sedimentation rate) regimes. In all areas, the sedimented seafloor mimics the underlying basement topography, although the degree to which topography becomes subdued varies. Depositional regimes result in symmetric sedimentation within basins and subdued topography, whereas minimal sedimentation regimes have more asymmetric distribution of sediments within topographic lows and higher seafloor relief. Regardless of sedimentation regime, enhanced sediment deposition occurs within basins. However, we observe that basin infill is rarely more than twice as thick as sediment cover over abyssal hills. If this variation is due to sediment focusing, the focusing factor in the basins, as measured by 230Th, is no more than a factor of ∼1.3 of the total vertical particulate rain.This research is supported by NSF grants OCE‐07253011 and OCE‐0851056 (M. Lyle and M. Tominaga) and NERC grant NE/C508985/2 (N. C. Mitchell)