The ligational behavior of a phenolic quinolyl hydrazone towards copper(II)- ions

<p>Abstract</p> <p>Background</p> <p>The heterocyclic hydrazones constitute an important class of biologically active drug molecules. The hydrazones have also been used as herbicides, insecticides, nematocides, redenticides, and plant growth regulators as well as plasticizers and stabilizers for polymers. The importance of the phenolic quinolyl hydrazones arises from incorporating the quinoline ring with the phenolic compound; 2,4-dihydroxy benzaldehyde. Quinoline ring has therapeutic and biological activities whereas, phenols have antiseptic and disinfectants activities and are used in the preparation of dyes, bakelite and drugs. The present study is planned to check the effect of the counter anions on the type and geometry of the isolated copper(II)- complexes as well as the ligational behavior of the phenolic hydrazone; 4-[(2-(4,8-dimethylquinolin-2-yl)hydrazono)methyl] benzene-1,3-diol; (H₂L).</p> <p>Results</p> <p>A phenolic quinolyl hydrazone (H₂L) was allowed to react with various copper(II)- salts (Cl‾, Br‾, NO₃‾, ClO₄‾, AcO‾, SO₄^2-). The reactions afforded dimeric complexes (ClO₄‾, AcO‾ ), a binuclear complex (NO₃‾ ) and mononuclear complexes (the others; Cl‾, Br‾, SO₄^2-). The isolated copper(II)- complexes have octahedral, square pyramid and square planar geometries. Also, they reflect the strong coordinating ability of NO₃‾, Cl‾, Br‾, AcO‾ and SO₄^2-anions. Depending on the type of the anion, the ligand showed three different modes of bonding <it>viz</it>. (NN)⁰for the mononuclear complexes (<b>3, 4, 6</b>), (NO)^-with O- bridging for the dimeric complexes (<b>1, 5</b>) and a mixed mode [(NN)⁰+ (NO)^-with O- bridging] for the binuclear nitrato- complex (<b>2</b>).</p> <p>Conclusion</p> <p>The ligational behavior of the phenolic hydrazone (H₂L) is highly affected by the type of the anion. The isolated copper(II)- complexes reflect the strong coordinating power of the SO₄^2-, AcO‾, Br‾, Cl‾ and NO₃‾ anions. Also, they reflect the structural diversity (octahedral, square pyramid and square planar) depending on the type of the counter anion.</p

Innovative irrigation strategies for rice in the Mediterranean areas

Rice is the world's most important food crop, as it is a staple food for more than half of the world's population, and the global demand for rice is expected to increase. More than 1,000,000 hectares in the Mediterranean basin are devoted to rice cultivation. The most important producing countries are Italy (IT) and Spain (SP) in Europe (over 310,000 ha), and Egypt (EG) and Turkey (TR) among non-EU countries (over 600,000 ha). In the Mediterranean region, rice production is of great socio-economic and environmental importance, as rice is often a crucial product for internal consumption and export, especially in Egypt, where it is considered strategic for food security. Despite of this, the peculiar flooding conditions in which rice is traditionally grown lead to the use of huge water volumes, as well as to the potential release of greenhouse gases and pesticides into the environment. For this reason, the introduction of water-saving irrigation strategies could reduce water consumption and decrease the harmful environmental impacts associated with rice flooding, while maintaining yield and rice grain quality. In the context of the MEDWATERICE project (https://www.medwaterice.org/; PRIMA-2018), alternative irrigation methods to WFL were tested in case studies implemented in five Mediterranean countries (Italy, Spain, Portugal, Turkey, Egypt). Irrigation strategies for each CS were selected with the support of local Stake-Holder groups and applied in experimental fields measuring/estimating all the water balance terms on a daily basis. Wet seeding and alternate wetting and drying (AWD), dry seeding and delayed flooding (DFL), reduction of inlet/outlet discharges (WIR), a better control of ponding water level irrigation (SDI) were implemented for at least two years in the period 2019-2021 alongside the traditional WFL, to investigate their environmental and economic sustainability and social acceptability. through automated gates (DFL-aut), hybrid irrigation (HYBRID), sprinkler irrigation (SPRINKLER), surface drip (DRIP) and subsurface dri

Irrigation strategies alternative to continuous flooding to decrease water use and increase water productivity in Mediterranean rice-based agroecosystems

In the Mediterranean basin, rice is cultivated over an area of 1,300,000 hectares. The most important rice-producing countries are Italy and Spain in Europe (72% of the EU production; 345,000 ha), and Egypt and Turkey among the extra-EU countries (almost totality of the production; 789,000 ha). Traditionally, in these areas, rice is cultivated under continuous flooding; thus, it requires much more irrigation than non-ponded crops. On the other hand, rice is strategic for food security in some countries and its consumption in the whole Mediterranean basin is steadily increasing. The MEDWATERICE project (https://www.medwaterice.org/) includes 7 case studies (CSs) representative of different rice agroecosystems in 5 Mediterranean countries (Italy, Spain, Portugal, Egypt and Turkey). Innovative irrigation strategies alternative to the traditional wet-seeding and continuous flooding (WFL) were tested and tailored to local conditions in each CS, including: alternate wetting and drying (AWD), dry-seeding and delayed flooding (DFL), subsurface drip irrigation (SDI), surface drip irrigation (DRIP), reduction of water input (RWI), hybrid irrigation (HYBRID) and multi-nozzle sprinkler irrigation (SPRINKLER). In each CS, strategies were compared to WFL and field trials were carried out at least for two years during the period 2019-2021. A minimum dataset including agroclimatic data, soil physico-chemical properties, groundwater depth and salinity, irrigation water inflow and outflow, irrigation water salinity, grain yield and quality was collected and analyzed in all case studies. Results suggest that AWD and DFL might be sound alternatives to WFL in Lomellina (IT), Baix Ter (SP), Lower Mondego and Lis Valleys (PT), and Bafra Valley (TR), leading to an increase in water productivity up to 30%. SPRINKLER and HYBRID irrigation tested in the Nile Delta (EG) resulted in an increase in water productivity of about 50% in both cases. Surface and subsurface drip irrigation systems have a great potential in reducing water use, while maintaining yield production as demonstrated in the Nile Delta (EG), Bafra Valley (TK), and Baix Ter (ES), where water productivity increased from 40 to 100% compared to WFL. Nevertheless, when adopting drip irrigation techniques, special attention must be paid to the irrigation system design and management, by considering the site-specific soil hydraulic properties and agroclimatic conditions. This communication describes the main aspects affecting rice production in each area participating in the MEDWATERICE project, and quantifies the water use and the quantity and quality of the rice production achieved with the traditional irrigation method (WFL) and the innovative irrigation solutions tested in each CS

The ligational behavior of an isatinic quinolyl hydrazone towards copper(II)- ions

<p>Abstract</p> <p>Background</p> <p>The importance of the isatinic quinolyl hydrazones arises from incorporating the quinoline ring with the indole ring. Quinoline ring has therapeutic and biological activities whereas, the indole ring occurs in Jasmine flowers and Orange blossoms. As a ligand, the isatin moiety is potentially ambidentate and can coordinate the metal ions either through its lactam or lactim forms. In a previous study, the ligational behavior of a phenolic quinolyl hydrazone towards copper(II)- ions has been studied. As continuation of our interest, the present study is planned to check the ligational behavior of an isatinic quinolyl hydrazone.</p> <p>Results</p> <p>New homo- and heteroleptic copper(II)- complexes were obtained from the reaction of an isatinic quinolyl hydrazone (HL) with several copper(II)- salts <it>viz. </it>Clˉ, Brˉ, NO₃ˉ, ClO₄^-, SO₄^2-and AcO^-. The obtained complexes have O_h, T_dand D_4h- symmetry and fulfill the strong coordinating ability of Clˉ, Brˉ, NO₃ˉ and SO₄^2-anions. Depending on the type of the anion, the ligand coordinates the copper(II)- ions either through its lactam (NO₃ˉ and ClO₄^-) or lactim (the others) forms.</p> <p>Conclusion</p> <p>The effect of anion for the same metal ion is obvious from either the geometry of the isolated complexes (O_h, T_dand D_4h) or the various modes of bonding. Also, the obtained complexes fulfill the strong coordinating ability of Clˉ, Brˉ, NO₃ˉ and SO₄^2-anions in consistency with the donor ability of the anions. In case of copper(II)- acetate, a unique homoleptic complex (<b>5</b>) was obtained in which the AcO^-anion acts as a base enough to quantitatively deprotonate the hydrazone. The isatinic hydrazone uses its lactim form in most complexes.</p

Multisource Data Analysis for Gold Potentiality Mapping of Atalla Area and Its Environs, Central Eastern Desert, Egypt

In this research, airborne geophysical and remote sensing datasets were integrated for gold potentiality mapping (GPM) over the Atalla area in Central Eastern Desert, Egypt. Utilizing aeromagnetic data, detailed structural complexity maps were constructed using the center for exploration targeting (CET) procedure. Then, spectrometric gamma-ray data primarily located hydrothermally altered tracts with discriminating various rock units. The latter are precisely outlined by implementing various techniques (false-color composite (FCC), band ratio (BR), relative absorption band depth (RBD), directed principal component analysis (DPCA), and constrained energy minimization (CEM)) to ASTER, Sentinel 2 and ALOS PRISM datasets, with reference to the geological maps. The study exhibits that gold mineralization is structurally controlled by NW-SE direction. The findings of structural complexity and hydrothermal alteration (argillic, advanced argillic, phyllic, and propylitic) were used as weighted inputs for contouring gold potentiality. The resultant GPM accentuated five gold-promising zones; two are confirmed via locations of ancient gold mines, while the remaining three zones are strongly recommended for their gold potentiality.</jats:p