A zero dimensional model of lithium-sulfur batteries during charge and discharge

Lithium-sulfur cells present an attractive alternative to Li-ion batteries due to their large energy density, safety, and possible low cost. Their successful commercialisation is dependent on improving their performance, but also on acquiring sufficient understanding of the underlying mechanisms to allow for the development of predictive models for operational cells. To address the latter, we present a zero dimensional model that predicts many observed features in the behaviour of a lithium-sulfur cell during charge and discharge. The model accounts for two electrochemical reactions via the Nernst formulation, power limitations through Butler-Volmer kinetics, and precipitation/dissolution of one species, including nucleation. It is shown that the precipitation/dissolution causes the flat shape of the low voltage plateau, typical of the lithium-sulfur cell discharge. During charge, it is predicted that the dissolution can act as a bottleneck, as for large enough currents smaller amounts dissolve. This results in reduced charge capacity and an earlier onset of the high plateau reaction, such that the two plateaus merge. By including these effects, the model improves on the existing zero dimensional models, while requiring considerably fewer input parameters and computational resources. The model also predicts that, due to precipitation, the customary way of experimentally measuring the open circuit voltage from a low rate discharge might not be suitable for lithium-sulfur. This model can provide the basis for mechanistic studies, identification of dominant effects in a real cell, predictions of operational behaviour under realistic loads, and control algorithms for applications

Additive manufacturing for solid oxide cell electrode fabrication

© The Electrochemical Society.Additive manufacturing can potentially offer a highly-defined electrode microstructure, as well as fast and reproducible electrode fabrication. Selective laser sintering is an additive manufacturing technique in which three-dimensional structures are created by bonding subsequent layers of powder using a laser. Although selective laser sintering can be applied to a wide range of materials, including metals and ceramics, the scientific and technical aspects of the manufacturing parameters and their impact on microstructural evolution during the process are not well understood. In the present study, a novel approach for electrode fabrication using selective laser sintering was evaluated by conducting a proof of concept study. A Ni-patterned fuel electrode was laser sintered on an yttria-stabilized zirconia substrate. The optimization process of laser parameters (laser sintering rate and laser power) and the electrochemical results of a full cell with a laser sintered electrode are presented. The challenges and prospects of using selective laser sintering for solid oxide cell fabrication are discussed

Climate change and rising energy costs: a threat but also an opportunity for a healthier future?

Health problems caused by overconsumption, growing inequalities and diminished well-being are issues that have been attributed to the prioritization of economic growth as the central purpose of society. It is also known that climate change and rising energy prices will inevitably bring changes to the globe's economic models. Doctors and the wider public health community have campaigned successfully in the past on issues such as the threat of nuclear war. Is it now time for this constituency to make its distinctive contribution to these new threats to health

Methanol and excited OH masers towards W51: I - Main and South

MERLIN phase-referenced polarimetric observations towards the W51 complex were carried out in March 2006 in the Class II methanol maser transition at 6.668 GHz and three of the four excited OH maser hyperfine transitions at 6 GHz. Methanol maser emission is found towards both W51 Main and South. We did not detect any emission in the excited OH maser lines at 6.030 and 6.049 GHz down to a 3 sigma limit of ~20 mJy per beam. Excited OH maser emission at 6.035 GHz is only found towards W51 Main. This emission is highly circularly polarised (typically 45% and up to 87%). Seven Zeeman pairs were identified in this transition, one of which contains detectable linear polarisation. The magnetic field strength derived from these Zeeman pairs ranges from +1.6 to +6.8 mG, consistent with the previously published magnetic field strengths inferred from the OH ground-state lines. The bulk of the methanol maser emission is associated with W51 Main, sampling a total area of ~3"x2.2" (i.e., ~16200x11900 AU), while only two maser components, separated by ~2.5", are found in the W51 South region. The astrometric distributions of both 6.668-GHz methanol and 6.035-GHz excited-OH maser emission in the W51 Main/South region are presented here. The methanol masers in W51 Main show a clear coherent velocity and spatial structure with the bulk of the maser components distributed into 2 regions showing a similar conical opening angle with of a central velocity of ~+55.5 km/s and an expansion velocity of =<5 km/s. The mass contained in this structure is estimated to be at least 22 solar masses. The location of maser emission in the two afore-mentioned lines is compared with that of previously published OH ground-state emission. Association with the UCHII regions in the W51 Main/South complex and relationship of the masers to infall or outflow in the region are discussed.Comment: 19 pages, 16 figures and 4 tables, accepted for publication in MNRA

The Regeneration Games: Commodities, Gifts and the Economics of London 2012

This paper considers contradictions between two concurrent and tacit conceptions of the Olympic ‘legacy’, setting out one conception that understands the games and their legacies as gifts alongside and as counterpoint to the prevailing discourse, which conceives Olympic assets as commodities. The paper critically examines press and governmental discussion of legacy, in order to locate these in the context of a wider perspective contrasting ‘gift’ and ‘commodity’ Olympics – setting anthropological conceptions of gift-based sociality as a necessary supplement to contractual and dis-embedded socioeconomic organizational assumptions underpinning the commodity Olympics. Costbenefit planning is central to modern city building and mega-event delivery. The paper considers the insufficiency of this approach as the exclusive paradigm within which to frame and manage a dynamic socio-economic and cultural legacy arising from the 2012 games

In-Operando X-ray Tomography Study of Lithiation Induced Delamination of Si Based Anodes for Lithium-Ion Batteries

Silicon-Lithium based rechargeable batteries offer high gravimetric capacity. However cycle life and electrode microstructure failure mechanisms remain poorly understood. Here we present an X-ray tomography method to investigate in-operando lithiation induced stress cracking leading to the delamination of a composite Si based electrode. Simultaneous voltage measurements show increased cell resistance correlating with severe delamination and microstructural changes. 3D analysis revealed 44.1% loss of the initial electrode-current collector area after 1 hour of operation at 2.4 mA/cm 2 and a 21.2% increase in new anode surface area. The work represents a new basis for future investigation of Si based anodes. © 2014 The Electrochemical Society

HI Narrow Self-Absorption in Dark Clouds: Correlations with Molecular Gas and Implications for Cloud Evolution and Star Formation

We present the results of a comparative study of HI narrow self-absorption (HINSA), OH, 13CO, and C18O in five dark clouds. The HINSA follows the distribution of the emission of the carbon monoxide isotopologues, and has a characteristic size close to that of 13CO. This confirms that the HINSA is produced by cold HI which is well mixed with molecular gas in well-shielded regions. The ratio of the atomic hydrogen density to total proton density for these sources is 5 to 27 x 10^{-4}. Using cloud temperatures and the density of HI, we set an upper limit to the cosmic ray ionization rate of 10^{-16} s^{-1}. Comparison of observed and modeled fractional HI abundances indicates ages for these clouds to be 10^{6.5} to 10^{7} yr. The low values of the HI density we have determined make it certain that the time scale for evolution from an atomic to an almost entirely molecular phase, must be a minimum of several million years. This clearly sets a lower limit to the overall time scale for star formation and the lifetime of molecular clouds

Environmental impact of hybrid and electric vehicles

Hybrid and electric vehicles play a critical role in reducing global greenhouse gas emissions, with transport estimated to contribute to 14% of the 49 GtCO2eq produced annually. Analysis of only the conversion efficiency of powertrain technologies can be misleading, with pure battery electric and hybrid vehicles reporting average efficiencies of 92% and 35% in comparison with 21% for internal combustion engine vehicles. A fairer comparison would be to consider the well-to-wheel efficiency, which reduces the numbers to 21–67%, 25% and 12%, respectively. The large variation in well-to-wheel efficiency of pure battery electric vehicles highlights the importance of renewable energy generation in order to achieve true environmental benefits. When calculating the energy return on investment of the various technologies based on the current energy generation mix, hybrid vehicles show the greatest environmental benefits, although this would change if electricity was made with high amounts of renewables. In an extreme scenario with heavy coal generation, the CO2eq return on investment can actually be negative for pure electric vehicles, highlighting the importance of renewable energy generation further. The energy impact of production is generally small (∼6% of lifetime energy) and, similarly, recycling is of a comparable magnitude, but it is less well studied

In-operando high-speed tomography of lithium-ion batteries during thermal runaway

Prevention and mitigation of thermal runaway presents one of the greatest challenges for the safe operation of lithium-ion batteries. Here, we demonstrate for the first time the application of high-speed synchrotron X-ray computed tomography and radiography, in conjunction with thermal imaging, to track the evolution of internal structural damage and thermal behaviour during initiation and propagation of thermal runaway in lithium-ion batteries. This diagnostic approach is applied to commercial lithium-ion batteries (LG 18650 NMC cells), yielding insights into key degradation modes including gas-induced delamination, electrode layer collapse and propagation of structural degradation. It is envisaged that the use of these techniques will lead to major improvements in the design of Li-ion batteries and their safety features