The use of aero-magnetics to enhance a numerical groundwater model of the Lagan Valley aquifer, Northern Ireland

Peer reviewedPublisher PD

Soil-Geochemical Factors controlling the Distribution and Oral Bioaccessibility of Nickel, Vanadium and Chromium in Northern Ireland Soils

Geogenic nickel (Ni), vanadium (V) and chromium (Cr) are present at elevated levels in soils in Northern Ireland. Whilst Ni, V and Cr total soil concentrations share common geological origins, their respective levels of oral bioaccessibility are influenced by different soil-geochemical factors. Oral bioaccessibility extractions were carried out on 145 soil samples overlying 9 different bedrock types to measure the bioaccessible portions of Ni, V and Cr. Principal component analysis identified two components (PC1 and PC2) accounting for 69% of variance across 13 variables from the Northern Ireland Tellus Survey geochemical data. PC1 was associated with underlying basalt bedrock, higher bioaccessible Cr concentrations and lower Ni bioaccessibility. PC2 was associated with regional variance in soil chemistry and hosted factors accounting for higher Ni and V bioaccessibility. Eight per cent of total V was solubilised by gastric extraction on average across the study area. High median proportions of bioaccessible Ni were observed in soils overlying sedimentary rock types. Whilst Cr bioaccessible fractions were low (max = 5.4%), the highest measured bioaccessible Cr concentration reached 10.0 mg kg-1, explained by factors linked to PC1 including high total Cr concentrations in soils overlying basalt bedrock

Mapping a waste disposal site using Tellus airborne geophysical data

Leakage of fluids from unregulated and/or poorly engineered waste disposal sites poses a significant direct risk to groundwater quality. Characterisation and monitoring of waste disposal sites and potentially associated groundwater contaminant plumes are generally invasive, time-consuming and expensive, particularly when the extent of the plume is unknown. This study examines the value of incorporating of Tellus and Tellus Border airborne electromagnetic (AEM) data into current assessment protocols for the characterisation and monitoring of contaminant sources and subsurface contaminant plumes. The findings demonstrate the feasibility of using airborne and ground-based non-invasive geophysical data as part of existing tiered assessment protocols for prioritising suspected sites and for guiding targeted intrusive investigations and subsequent remediation efforts

Effect of volcanic dykes on coastal groundwater flow and saltwater intrusion : a field-scale multiphysics approach and parameter evaluation

Acknowledgments This research was primarily based on research grant‐aided by the Irish Department of Communications, Energy and Natural Resources under the National Geoscience Programme 2007–2013. It also benefited from complementary funding from the Scottish Alliance for Geoscience, Environment and Society (SAGES). We acknowledge the contribution in data acquisition of the MSc students in Environmental Engineering at Queen's University Belfast, the landowner for access to the inland fields and the Department of Geography, Archaeology and Paleoecology at QUB for provision of the tidal model of Belfast Lough. The data used are listed in the references, tables, and figures and are available from the corresponding author upon demand. We acknowledge the constructive comments by the Associate Editor and three reviewers, which helped in improving the final manuscript.Peer reviewedPublisher PD

Analysis of groundwater-level response to rainfall and recharge estimates in fractured hard rock aquifers, NW Ireland

Despite fractured hard rock aquifers underlying over 65% of Ireland, knowledge of key processes controlling groundwater recharge in these bedrock systems is inadequately constrained. In this study, we examined 19 groundwater-level hydrographs from two Irish hillslope sites underlain by hard rock aquifers. Water-level time-series in clustered monitoring wells completed at the subsoil, soil/bedrock interface, shallow and deep bedrocks were continuously monitored hourly over two hydrological years. Correlation methods were applied to investigate groundwater-level response to rainfall, as well as its seasonal variations. The results reveal that the direct groundwater recharge to the shallow and deep bedrocks on hillslope is very limited. Water-level variations within these geological units are likely dominated by slow flow rock matrix storage. The rapid responses to rainfall (⩽2 h) with little seasonal variations were observed to the monitoring wells installed at the subsoil and soil/bedrock interface, as well as those in the shallow or deep bedrocks at the base of the hillslope. This suggests that the direct recharge takes place within these units. An automated time-series procedure using the water-table fluctuation method was developed to estimate groundwater recharge from the water-level and rainfall data. Results show the annual recharge rates of 42–197 mm/yr in the subsoil and soil/bedrock interface, which represent 4–19% of the annual rainfall. Statistical analysis of the relationship between the rainfall intensity and water-table rise reveal that the low rainfall intensity group (⩽1 mm/h) has greater impact on the groundwater recharge rate than other groups (>1 mm/h). This study shows that the combination of the time-series analysis and the water-table fluctuation method could be an useful approach to investigate groundwater recharge in fractured hard rock aquifers in Ireland

Quantification of groundwater storage heterogeneity in weathered/fractured basement rock aquifers using electrical resistivity tomography : sensitivity and uncertainty associated with petrophysical modelling

Acknowledgments: We thank the National Council of Science and Technology and Secretariat of Energy of México (CONACYT-SENER) for funding this research, and the Geological Survey of Ireland and MSc students at Queen’s University of Belfast for assistance in data collection. We appreciate the insightful and constructive comment by P. Lachassagne and two anonymous reviewers which contributed to improve the manuscript.Peer reviewedPostprin

Joint use of singular value decomposition and Monte-Carlo simulation for estimating uncertainty in surface NMR inversion

This work was supported by a grant from Labex OSUG@2020 (Investissements d'avenir – ANR10 LABX56). We also thank the French National Program (ANR)” Investment for Future - Excellency Equipment” project EQUIPEX CRITEX (grant # ANR-11-EQPX-0011) for providing MRS equipment. The Geological Survey of Ireland (GSI) provided financial support for the fieldwork in the framework of the Geoscience Research Program (2016).Peer reviewedPostprin

Groundwater in fractured bedrock environments: managing catchment and subsurface resources – an introduction

Hard rocks, including crystalline igneous, metamorphic and strongly cemented sedimentary and carbonate rocks, cover about 50% of the Earth's land surface (Singhal & Gupta 2010). Globally, the volume of groundwater contained in hard rock aquifers is not well constrained (Comte et al. 2012) but locally they can be important aquifers (MacDonald et al. 2012), albeit with low groundwater storage and poor primary porosity and permeability. Groundwater flow in these hard rocks is commonly observed to be associated with water-bearing discontinuities, such as fractures, joints and faults (Mazurek 2000; Berkowitz 2002; Font-Capo et al. 2012), and in the weathered regolith (Wright 1992; Chilton & Foster 1995; Deyassa et al. 2014). Structural elements such as fault zones also strongly govern the behaviour of these systems (Forster & Evans 1991; López & Smith 1995; Bense et al. 2013). The nature, abundance, orientation and connectivity of these water-bearing features are largely governed by the history and nature of structural deformation of the bedrock, and commonly impose strong anisotropic flow and transport parameters on these bedrock aquifers (Hsieh et al. 1985; Bour & Davy 1997; Mortimer et al. 2011). Weathering processes furthermore lead to an alteration of bedrock composition and associated aquifer properties resulting in enhanced fracture connectivity and an overall vertical stratification/zonation of bulk aquifer properties, ranging from highly altered shallow regolith horizons to more competent sparsely fractured bedrock at depth (Dewandel et al. 2006; Krásný & Sharp 2007; Lachassagne et al. 2011)

Evaluating Groundwater Nitrate Status across the River Ythan Catchment (Scotland) following Two Decades of Nitrate Vulnerable Zone Designation

Publication history: Accepted - 14 April 2023; Published - 18 April 2023.Diffuse agricultural pollution is one of the greatest challenges to achieving good chemical and ecological status of Scotland’s water bodies. The River Ythan in Aberdeenshire was designated a Nitrate Vulnerable Zone (NVZ) in the year 2000, due to the eutrophication of the Ythan Estuary and rising nitrate trends in Private Water Supply (PWS) groundwater abstractions. The third River Basin Management Plan (RBMP) for Scotland reported the Ellon groundwater body of the River Ythan catchment to be of poor chemical status as of 2021 with respect to nitrate, and forecasted groundwater recovery beyond 2027. Following two decades of NVZ designation, we investigated the drivers of groundwater nitrate across the River Ythan catchment through an analysis of long-term (2009–2018) groundwater quality monitoring data collected by the Scottish Environmental Protection Agency (SEPA) and a recent synoptic groundwater nitrate sampling survey of PWSs. Groundwater nitrate was found to remain elevated across the catchment area, and appeared to be highly sensitive to agricultural practices and meteorological forcing, indicating a high sensitivity of groundwater quality to environmental change. Further hydrogeological characterisation is recommended to better understand the effects of agricultural practices on groundwater quality, and to facilitate achievement of future RBMP goals under a changing climate.This research was supported by the Natural Environment Research Council and the QUADRAT Doctoral Training Partnership [NE/S007377/1]