Incidental phosphorus and nitrogen loss from grassland plots receiving chemically amended dairy cattle slurry

peer-reviewedChemical amendment of dairy cattle slurry has been shown to effectively reduce incidental phosphorus (P) losses in runoff; however, the effects of amendments on incidental nitrogen (N) losses are not as well documented. This study examined P and N losses in runoff during three simulated rainfall events 2, 10 and 28 days after a single application of unamended/chemically amended dairy cattle slurry. Twenty-five hydraulically isolated plots, each measuring 0.9 m by 0.4 m and instrumented with runoff collection channels, were randomly assigned the following treatments: (i) grass-only, (ii) slurry-only (the study-control), (iii) slurry amended with industrial grade liquid alum comprising 8% Al2O3, (iv) slurry amended with industrial grade liquid poly-aluminum chloride (PAC) comprising 10% Al2O3, and (v) slurry amended with lime. During the first rainfall event, lime was ineffective but alum and PAC effectively reduced dissolved reactive P (DRP) (by 95 and 98%, respectively) and total P (TP) flow-weighted-mean-concentrations (by 82 and 93%, respectively) in runoff compared to the study-control. However, flow-weighted-mean-concentrations of ammonium–N (NH4–N) in runoff were increased with alum- (81%) and lime-treated (11%) slurry compared to the study-control whereas PAC reduced the NH4–N by 82%. Amendments were not observed to have a significant effect on NO3–N losses during this study. Slurry amendments reduced P losses for the duration of the study, whereas the effect of amendments on N losses was not significant following the first event. Antecedent volumetric water content of the soil or slope of the plots did not appear to affect runoff volume. However, runoff volumes (and consequently loads of P and N) were observed to increase for the chemically amended plots compared to the control and soil-only plots. This work highlights the importance of considering both P and N losses when implementing a specific nutrient mitigation measure.Teagasc Walsh Fellowship Schem

Forecasting the decline of excess soil phosphorus in agricultural catchments

Measures within the European Union Nitrates Directive National Action Programmes in many member states aim to reduce soil phosphorus (P) levels from excessive to agronomically optimum. This is to reduce the risk of diffuse P losses to water and ultimately help achieve the Water Framework Directive targets of good water quality status. In this study, a 'Soil P Decline' model was used to evaluate this expectation for soils in four intensive agricultural catchments. Realistic annual P-balance scenario deficits (-30, -15, -7 kg P/ha) were used to estimate the average time required for soils to decline to optimum levels in two predominantly arable and two grassland catchments with excessive soil test P (STP). Depending on the STP concentration and total P reserves, for the smallest field P deficit scenario (-7 kg P/ha), the model predictions were for an average of between 5 and 20 yr for agronomically optimum levels to be reached. Under the largest P deficit scenario (-30 kg P/ha), it was forecast to take between 2 and 10 yr. These predictions highlight the likely time lag that exists between implementation of soil P mitigation regulations and the desired outcome of few or no fields with excessive soil P. Expectations for water quality improvement through diffuse P source mitigation must also factor in additional time for P decline model uncertainty, land management variability and time for P sources to transfer to and within river networks