Rocking motion induced charging of C60 on h-BN/Ni(111)

One monolayer of C60 on one monolayer of hexagonal boron nitride on nickel is investigated by photoemission. Between 150 and 250 K the work function decreases and the binding energy of the highest occupied molecular orbital (HOMO) increases by approx. 100 meV. In parallel, the occupancy of the, in the cold state almost empty, lowest unoccupied molecular orbital (LUMO) changes by 0.4 electrons. This charge redistribution is triggered by onset of molecular rocking motion, i.e. by orientation dependent tunneling between the LUMO of C60 and the substrate. The magnitude of the charge transfer is large and cannot be explained within a single particle picture. It is proposed to involve electron-phonon coupling where C60- polaron formation leads to electron self-trapping.Comment: 15 pages, 4 figure

Continuum Limit of 2D2D Spin Models with Continuous Symmetry and Conformal Quantum Field Theory

According to the standard classification of Conformal Quantum Field Theory (CQFT) in two dimensions, the massless continuum limit of the $O(2)$ model at the Kosterlitz-Thouless (KT) transition point should be given by the massless free scalar field; in particular the Noether current of the model should be proportional to (the dual of) the gradient of the massless free scalar field, reflecting a symmetry enhanced from $O(2)$ to $O(2)\times O(2)$. More generally, the massless continuum limit of a spin model with a symmetry given by a Lie group $G$ should have an enhanced symmetry $G\times G$. We point out that the arguments leading to this conclusion contain two serious gaps: i) the possibility of `nontrivial local cohomology' and ii) the possibility that the current is an ultralocal field. For the $2D$ $O(2)$ model we give analytic arguments which rule out the first possibility and use numerical methods to dispose of the second one. We conclude that the standard CQFT predictions appear to be borne out in the $O(2)$ model, but give an example where they would fail. We also point out that all our arguments apply equally well to any $G$ symmetric spin model, provided it has a critical point at a finite temperature.Comment: 19 page

Algebraic Quantum Theory on Manifolds: A Haag-Kastler Setting for Quantum Geometry

Motivated by the invariance of current representations of quantum gravity under diffeomorphisms much more general than isometries, the Haag-Kastler setting is extended to manifolds without metric background structure. First, the causal structure on a differentiable manifold M of arbitrary dimension (d+1>2) can be defined in purely topological terms, via cones (C-causality). Then, the general structure of a net of C*-algebras on a manifold M and its causal properties required for an algebraic quantum field theory can be described as an extension of the Haag-Kastler axiomatic framework. An important application is given with quantum geometry on a spatial slice within the causally exterior region of a topological horizon H, resulting in a net of Weyl algebras for states with an infinite number of intersection points of edges and transversal (d-1)-faces within any neighbourhood of the spatial boundary S^2.Comment: 15 pages, Latex; v2: several corrections, in particular in def. 1 and in sec.

Functional Integral Construction of the Thirring model: axioms verification and massless limit

We construct a QFT for the Thirring model for any value of the mass in a functional integral approach, by proving that a set of Grassmann integrals converges, as the cutoffs are removed and for a proper choice of the bare parameters, to a set of Schwinger functions verifying the Osterwalder-Schrader axioms. The corresponding Ward Identities have anomalies which are not linear in the coupling and which violate the anomaly non-renormalization property. Additional anomalies are present in the closed equation for the interacting propagator, obtained by combining a Schwinger-Dyson equation with Ward Identities.Comment: 55 pages, 9 figure

Deceleration of neutral molecules in macroscopic traveling traps

A new type of decelerator is presented where polar neutral molecules are guided and decelerated using the principle of traveling electric potential wells, such that molecules are confined in stable three-dimensional traps throughout. This new decelerator is superior to the best currently operational decelerator (Scharfenberg et al., Phys.Rev.A 79, 023410(2009)), providing a substantially larger acceptance even at higher accelerations. The mode of operation is described and experimentally demonstrated by guiding and decelerating CO molecules.Comment: 10 pages, 3 figure

Connes-Lott model building on the two-sphere

In this work we examine generalized Connes-Lott models on the two-sphere. The Hilbert space of the continuum spectral triple is taken as the space of sections of a twisted spinor bundle, allowing for nontrivial topological structure (magnetic monopoles). The finitely generated projective module over the full algebra is also taken as topologically non-trivial, which is possible over $S^2$. We also construct a real spectral triple enlarging this Hilbert space to include "particle" and "anti-particle" fields.Comment: 57 pages, LATE

Existence of the Bogoliubov S(g) operator for the (:ϕ4:)2(:\phi^4:)_2 quantum field theory

We prove the existence of the Bogoliubov S(g) operator for the $(:\phi^4:)_2$ quantum field theory for coupling functions $g$ of compact support in space and time. The construction is nonperturbative and relies on a theorem of Kisy\'nski. It implies almost automatically the properties of unitarity and causality for disjoint supports in the time variable.Comment: LaTeX, 24 pages, minor modifications, typos correcte

A traveling wave decelerator for neutral polar molecules

Recently, a decelerator for neutral polar molecules has been presented that operates on the basis of macroscopic, three-dimensional, traveling electrostatic traps (Osterwalder et al., Phys. Rev. A 81, 051401 (2010)). In the present paper, a complete description of this decelerator is given, with emphasis on the electronics and the mechanical design. Experimental results showing the transverse velocity distributions of guided molecules are shown and compared to trajectory simulations. An assessment of non-adiabatic losses is made by comparing the deceleration signals from 13-CO with those from 12-CO and with simulated signals.Comment: 10 pages, 7 figure

Constructing Hamiltonian quantum theories from path integrals in a diffeomorphism invariant context

Osterwalder and Schrader introduced a procedure to obtain a (Lorentzian) Hamiltonian quantum theory starting from a measure on the space of (Euclidean) histories of a scalar quantum field. In this paper, we extend that construction to more general theories which do not refer to any background, space-time metric (and in which the space of histories does not admit a natural linear structure). Examples include certain gauge theories, topological field theories and relativistic gravitational theories. The treatment is self-contained in the sense that an a priori knowledge of the Osterwalder-Schrader theorem is not assumed.Comment: Plain Latex, 25 p., references added, abstract and title changed (originally :``Osterwalder Schrader Reconstruction and Diffeomorphism Invariance''), introduction extended, one appendix with illustrative model added, accepted by Class. Quantum Gra