21,961 research outputs found

    Space capsule ejection assembly Patent

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    Describing assembly for opening stabilizing and decelerating flaps of flight capsules used in space researc

    Diffusiophoresis in non-adsorbing polymer solutions: the Asakura-Oosawa model and stratification in drying films

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    A colloidal particle placed in an inhomogeneous solution of smaller non-adsorbing polymers will move towards regions of lower polymer concentration, in order to reduce the free energy of the interface between the surface of the particle and the solution. This phenomenon is known as diffusiophoresis. Treating the polymer as penetrable hard spheres, as in the Asakura-Oosawa model, a simple analytic expression for the diffusiophoretic drift velocity can be obtained. In the context of drying films we show that diffusiophoresis by this mechanism can lead to stratification under easily accessible experimental conditions. By stratification we mean spontaneous formation of a layer of polymer on top of a layer of the colloid. Transposed to the case of binary colloidal mixtures, this offers an explanation for the stratification observed recently in these systems [A. Fortini et al, Phys. Rev. Lett. 116, 118301 (2016)]. Our results emphasise the importance of treating solvent dynamics explicitly in these problems, and caution against the neglect of hydrodynamic interactions or the use of implicit solvent models in which the absence of solvent backflow results in an unbalanced osmotic force which gives rise to large but unphysical effects.Comment: 11 pages, 6 figure

    On the electrical double layer contribution to the interfacial tension of protein crystals

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    We study the electrical double layer at the interface between a protein crystal and a salt solution or a dilute solution of protein, and estimate the double layer's contribution to the interfacial tension of this interface. This contribution is negative and decreases in magnitude with increasing salt concentration. We also consider briefly the interaction between a pair of protein surfaces.Comment: 6 pages, 3 figures, revtex

    Assembly for recovering a capsule Patent

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    Assembly for opening flight capsule stabilizing and decelerating flaps with reference to capsule recover

    Distribution of the second virial coefficients of globular proteins

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    George and Wilson [Acta. Cryst. D 50, 361 (1994)] looked at the distribution of values of the second virial coefficient of globular proteins, under the conditions at which they crystallise. They found the values to lie within a fairly narrow range. We have defined a simple model of a generic globular protein. We then generate a set of proteins by picking values for the parameters of the model from a probability distribution. At fixed solubility, this set of proteins is found to have values of the second virial coefficient that fall within a fairly narrow range. The shape of the probability distribution of the second virial coefficient is Gaussian because the second virial coefficient is a sum of contributions from different patches on the protein surface.Comment: 5 pages, including 3 figure

    Fluid-fluid phase separation in hard spheres with a bimodal size distribution

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    The effect of polydispersity on the phase behaviour of hard spheres is examined using a moment projection method. It is found that the Boublik-Mansoori-Carnahan-Starling-Leland equation of state shows a spinodal instability for a bimodal distribution if the large spheres are sufficiently polydisperse, and if there is sufficient disparity in mean size between the small and large spheres. The spinodal instability direction points to the appearance of a very dense phase of large spheres.Comment: 7 pages, 3 figures, moderately REVISED following referees' comments (original was 4 pages, 3 postscript figures

    Feasibility study of a synthesis procedure for array feeds to improve radiation performance of large distorted reflector antennas

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    Virginia Tech has several activities which support the NASA Langley effort in the area of large aperture radiometric antenna systems. This semi-annual report discusses the major areas of research and progress made
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