Kondo effect and channel mixing in oscillating molecules

We investigate the electronic transport through a molecule in the Kondo regime. The tunneling between the electrode and the molecule is asymmetrically modulated by the oscillations of the molecule, i.e., if the molecule gets closer to one of the electrodes the tunneling to that electrode will increase while for the other electrode it will decrease. The system is described by a two-channel Anderson model with phonon-assisted hybridization, which is solved with the Wilson numerical renormalization group method. The results for several functional forms of tunneling modulation are presented. For a linearized modulation the Kondo screening of the molecular spin is caused by the even or odd conduction channel. At the critical value of the electron-phonon coupling an unstable two-channel Kondo fixed point is found. For a realistic modulation the spin at the molecular orbital is Kondo screened by the even conduction channel even in the regime of strong coupling. A universal consequence of the electron-phonon coupling is the softening of the phonon mode and the related instability to perturbations that break the left-right symmetry. When the frequency of oscillations decreases below the magnitude of such perturbation, the molecule is abruptly attracted to one of the electrodes. In this regime, the Kondo temperature is enhanced and, simultaneously, the conductance through the molecule is suppressed.Comment: published versio

Lutte biologique contre Hoplochelus marginalis (Coleopt., Melolonthinae) à l'aide de Beauveria brongniartii (Deuteromycotina, Hyphomycete)

Depuis 1989, trois essais menés sur canne à sucre ont permis de comparer divers traitements à base de Beauveria brongniartii contre Hoplochelus marginalis (Coleoptera, Melolonthinae), ravageur polyphage introduit accidentellement de Madagascar à La Réunion. Les résultats montrent que le champignon s'installe dès la première année et réduit progressivement les populations de vers blancs au-dessous d'un seuil de nuisibilité économique après une seule application initiale à dose économiquement viable

Low temperature magnetic phase diagram of the cubic non-Fermi liquid system CeIn_(3-x)Sn_x

In this paper we report a comprehensive study of the magnetic susceptibility (\chi), resistivity (\rho), and specific heat (C_P), down to 0.5 K of the cubic CeIn_(3-x)Sn_x alloy. The ground state of this system evolves from antiferromagnetic (AF) in CeIn_3(T_N=10.2 K) to intermediate-valent in CeSn_3, and represents the first example of a Ce-lattice cubic non-Fermi liquid (NFL) system where T_N(x) can be traced down to T=0 over more than a decade of temperature. Our results indicate that the disappearance of the AF state occurs near x_c ~ 0.7, although already at x ~ 0.4 significant modifications of the magnetic ground state are observed. Between these concentrations, clear NFL signatures are observed, such as \rho(T)\approx \rho_0 + A T^n (with n<1.5) and C_P(T)\propto -T ln(T) dependencies. Within the ordered phase a first order phase transition occurs for 0.25 < x < 0.5. With larger Sn doping, different weak \rho(T) dependencies are observed at low temperatures between x=1 and x=3 while C_P/T shows only a weak temperature dependence.Comment: 7 pages, 7 figures. Accepted in Eur. J. Phys.

Quantum Criticality in doped CePd_1-xRh_x Ferromagnet

CePd_1-xRh_x alloys exhibit a continuous evolution from ferromagnetism (T_C= 6.5 K) at x = 0 to a mixed valence (MV) state at x = 1. We have performed a detailed investigation on the suppression of the ferromagnetic (F) phase in this alloy using dc-(\chi_dc) and ac-susceptibility (\chi_ac), specific heat (C_m), resistivity (\rho) and thermal expansion (\beta) techniques. Our results show a continuous decrease of T_C (x) with negative curvature down to T_C = 3K at x*= 0.65, where a positive curvature takes over. Beyond x*, a cusp in cac is traced down to T_C* = 25 mK at x = 0.87, locating the critical concentration between x = 0.87 and 0.90. The quantum criticality of this region is recognized by the -log(T/T_0) dependence of C_m/T, which transforms into a T^-q (~0.5) one at x = 0.87. At high temperature, this system shows the onset of valence instability revealed by a deviation from Vegard's law (at x_V~0.75) and increasing hybridization effects on high temperature \chi_dc and \rho. Coincidentally, a Fermi liquid contribution to the specific heat arises from the MV component, which becomes dominant at the CeRh limit. In contrast to antiferromagnetic systems, no C_m/T flattening is observed for x > x_cr rather the mentioned power law divergence, which coincides with a change of sign of \beta. The coexistence of F and MV components and the sudden changes in the T dependencies are discussed in the context of randomly distributed magnetic and Kondo couplings.Comment: 11 pages, 11 figure

Crystal-field effects in the mixed-valence compounds Yb2M3Ga9 (M= Rh, Ir)

Magnetic susceptibility, heat capacity, and electrical resistivity measurements have been carried out on single crystals of the intermediate valence compounds Yb2Rh3Ga9 and Yb2Ir3Ga9. These measurements reveal a large anisotropy due apparently to an interplay between crystalline electric field (CEF) and Kondo effects. The temperature dependence of magnetic susceptibility can be modelled using the Anderson impurity model including CEF within an approach based on the Non-Crossing Approximation.Comment: Accepted to Phys. Rev.

Transport in Quantum Dots from the Integrability of the Anderson Model

In this work we exploit the integrability of the two-lead Anderson model to compute transport properties of a quantum dot, in and out of equilibrium. Our method combines the properties of integrable scattering together with a Landauer-Buttiker formalism. Although we use integrability, the nature of the problem is such that our results are not generically exact, but must only be considered as excellent approximations which nonetheless are valid all the way through crossover regimes. The key to our approach is to identify the excitations that correspond to scattering states and then to compute their associated scattering amplitudes. We are able to do so both in and out of equilibrium. In equilibrium and at zero temperature, we reproduce the Friedel sum rule for an arbitrary magnetic field. At finite temperature, we study the linear response conductance at the symmetric point of the Anderson model, and reproduce Costi et al.'s numerical renormalization group computation of this quantity. We then explore the out-of-equilibrium conductance for a near-symmetric Anderson model, and arrive at quantitative expressions for the differential conductance, both in and out of a magnetic field. We find the expected splitting of the differential conductance peak into two in a finite magnetic field, $H$. We determine the width, height, and position of these peaks. In particular we find for H >> T_k, the Kondo temperature, the differential conductance has maxima of e^2/h occuring for a bias V close to but smaller than H. The nature of our construction of scattering states suggests that our results for the differential magneto-conductance are not merely approximate but become exact in the large field limit.Comment: 88 pages, 16 figures, uses harvmac.te

Thermodynamic analysis of the Quantum Critical behavior of Ce-lattice compounds

A systematic analysis of low temperature magnetic phase diagrams of Ce compounds is performed in order to recognize the thermodynamic conditions to be fulfilled by those systems to reach a quantum critical regime and, alternatively, to identify other kinds of low temperature behaviors. Based on specific heat ($C_m$) and entropy ($S_m$) results, three different types of phase diagrams are recognized: i) with the entropy involved into the ordered phase ($S_{MO}$) decreasing proportionally to the ordering temperature ($T_{MO}$), ii) those showing a transference of degrees of freedom from the ordered phase to a non-magnetic component, with their $C_m(T_{MO})$ jump ($\Delta C_m$) vanishing at finite temperature, and iii) those ending in a critical point at finite temperature because their $\Delta C_m$ do not decrease with $T_{MO}$ producing an entropy accumulation at low temperature. Only those systems belonging to the first case, i.e. with $S_{MO}\to 0$ as $T_{MO}\to 0$, can be regarded as candidates for quantum critical behavior. Their magnetic phase boundaries deviate from the classical negative curvature below $T\approx 2.5$\,K, denouncing frequent misleading extrapolations down to T=0. Different characteristic concentrations are recognized and analyzed for Ce-ligand alloyed systems. Particularly, a pre-critical region is identified, where the nature of the magnetic transition undergoes significant modifications, with its $\partial C_m/\partial T$ discontinuity strongly affected by magnetic field and showing an increasing remnant entropy at $T\to 0$. Physical constraints arising from the third law at $T\to 0$ are discussed and recognized from experimental results

Thermodynamics of the dissipative two-state system: a Bethe Ansatz study

The thermodynamics of the dissipative two-state system is calculated exactly for all temperatures and level asymmetries for the case of Ohmic dissipation. We exploit the equivalence of the two-state system to the anisotropic Kondo model and extract the thermodynamics of the former by solving the thermodynamic Bethe Ansatz equations of the latter. The universal scaling functions for the specific heat $C_{\alpha}(T)$ and static dielectric susceptibility $\chi_{\alpha}(T)$ are extracted for all dissipation strengths $0<\alpha<1$ for both symmetric and asymmetric two-state systems. The logarithmic corrections to these quantities at high temperatures are found in the Kondo limit $\alpha\to 1^{-}$, whereas for $\alpha< 1$ we find the expected power law temperature dependences with the powers being functions of the dissipative coupling $\alpha$. The low temperature behaviour is always that of a Fermi liquid.Comment: 24 pages, 32 PS figures. Typos corrected, final versio

FREE ORAL COMMUNICATIONS 2: ALCOHOL AND LIVER—CLINICAL RESEARCHO2.1RAPID DECLINE OF LIVER STIFFNESS WITH ALCOHOL WITHDRAWAL IN HEAVY DRINKERS

Background and aims. Measurement of liver stiffness using real-time elastography appears as a promising tool to evaluate the severity of chronic liver diseases. Previous studies in patients with alcoholic liver disease have suggested that fibrosis was the only histological parameter to influence liver stiffness. To challenge this hypothesis, we have prospectively tested the short-term impact of alcohol withdrawal on liver stiffness value. Methods. All patients hospitalized for alcohol withdrawal in our Liver Unit between September 2008 and December 2010 had a liver stiffness determination (using a FibroScan® device) at entry (D0) and 7 days after alcohol withdrawal (D7). Stiffness values were compared using non-parametric test for paired-values. We compared (i) the 10 measures performed at D0 and at D7 for each patient; (ii) the variation of the median result of all patients (using Wilcoxon test in both cases). Results. A total of 138 patients were included in the study [median alcohol consumption: 150g/day (range: 40-400); hepatitis C: n=22 (15.9%); cirrhosis: n=29 (21.0%)]. From D0 to D7, the liver stiffness decreased significantly in 61 patients (44.2%) and increased significantly in 18 (13.0%). Considering all patients, median liver stiffness value decreased from 7.25 to kPa (P<0.001). The stage of fibrosis indicated by liver stiffness changed in 47 patients between D0 and D7 (decrease in 33 and increase in 14). Conclusion. Liver stiffness decreases significantly in nearly half of alcoholic patients after only 7 days of abstinence. This result strongly suggests that non-fibrotic lesions (such as inflammatory ones) may influence liver stiffness. From a practical point of view, it also shows that variation in alcohol consumption must be taken into account for the interpretation of liver stiffness valu

RGTA® or ReGeneraTing Agents mimic heparan sulfate in regenerative medicine: from concept to curing patients

The importance of extracellular matrix (ECM) integrity in maintaining normal tissue function is highlighted by numerous pathologies and situations of acute and chronic injury associated with dysregulation or destruction of ECM components. Heparan sulfate (HS) is a key component of the ECM, where it fulfils important functions associated with tissue homeostasis. Its degradation following tissue injury disrupts this delicate equilibrium and may impair the wound healing process. ReGeneraTing Agents (RGTA®s) are polysaccharides specifically designed to replace degraded HS in injured tissues. The unique properties of RGTA® (resistance to degradation, binding and protection of ECM structural and signaling proteins, like HS) permit the reconstruction of the ECM, restoring both structural and biochemical functions to this essential substrate, and facilitating the processes of tissue repair and regeneration. Here, we review 25 years of research surrounding this HS mimic, supporting the mode of action, pre-clinical studies and therapeutic efficacy of RGTA® in the clinic, and discuss the potential of RGTA® in new branches of regenerative medicine