Whipped oil stabilised by surfactant crystals

We describe a protocol for preparing very stable air-in-oil foams starting with a one-phase oil solution of a fatty acid (myristic acid) in high oleic sunflower oil at high temperature. Upon cooling below the solubility limit, a two-phase mixture consisting of fatty acid crystals (length around 50 μm) dispersed in an oil solution at its solubility is formed which, after whipping, coat air bubbles in the foam. Foams which do not drain, coalesce or coarsen may be produced either by increasing the fatty acid concentration at fixed temperature or aerating the mixtures at different temperatures at constant concentration. We prove that molecular fatty acid is not surface-active as no foam is possible in the one-phase region. Once the two-phase region is reached, fatty acid crystals are shown to be surface-active enabling foam formation, and excess crystals serve to gel the continuous oil phase enhancing foam stability. A combination of rheology, X-ray diffraction and pulsed nuclear magnetic resonance is used to characterise the crystals and oil gels formed before aeration. The crystal-stabilised foams are temperature-sensitive, being rendered completely unstable on heating around the melting temperature of the crystals. The findings are extended to a range of vegetable oil foams stabilised by a combination of adsorbed crystals and gelling of the oil phase, which destabilise at different temperatures depending on the composition and type of fatty acid chains in the triglyceride molecules

Hybrid thermocouple development program

The design and development of a hybrid thermocouple, having a segmented SiGe-PbTe n-leg encapsulated within a hollow cylindrical p-SiGe leg, is described. Hybrid couple efficiency is calculated to be 10% to 15% better than that of a all-SiGe couple. A preliminary design of a planar RTG, employing hybrid couples and a water heat pipe radiator, is described as an example of a possible system application. Hybrid couples, fabricated initially, were characterized by higher than predicted resistance and, in some cases, bond separations. Couples made later in the program, using improved fabrication techniques, exhibited normal resistances, both as-fabricated and after 700 hours of testing. Two flat-plate sections of the reference design thermoelectric converter were fabricated and delivered to NASA Lewis for testing and evaluation

Protracted Reproduction in Sunfish: the Temporal Dimension in Fish Recruitment Revisited

Understanding how life histories influence reproductive success under uncertain conditions is necessary to predict population dynamics. For many organisms, protracted reproduction may increase expected offspring recruitment in variable environments, requiring that temporal patterns of reproduction be considered when developing management or conservation strategies. We explored the interrelationships among birth date, production of embryos on nests, survival of larvae to the open-water stage, and survival of juveniles through the first fall and winter of life for bluegill and pumpkinseed sunfish (Lepomis macrochirus and L. gibbosus) in Lake Opinicon, Ontario, during May 1998 through May 1999. Age-0 sunfish were sampled with nesting surveys for embryos, surface tows for free-swimming larvae, and seining/trawling for juveniles. Age of juveniles (days post swim-up) was quantified using otoliths. The abundance of embryos on nests and the density of open-water larvae were unrelated across all dates and sites. Although 40% of larvae had appeared in the open water by 12 June, most juveniles sampled in the fall were produced after that time, suggesting that high mortality of early produced larvae occurred. Larval survival to the juvenile stage was generally unrelated to the abundance of edible zooplankton taxa during swim-up from nests. Larval survival was often highest at temperatures \u3e23.5°C. Fall length of age-0 sunfish increased with increasing age. Both age-specific length and mean lengths shifted positively between October 1998 and May 1999, suggesting that growth of all individuals and perhaps selective mortality of small juveniles occurred. Although early reproduction may increase sizes reached by fall and thereby improve overwinter survival, early hatched larvae are subject to variable environmental factors that may reduce survival. Late-hatched larvae may reach relatively smaller sizes by fall, but have higher survival probabilities during this life stage. Protracted reproduction appears to be a response to variable environmental factors influencing growth and survival across multiple life stages. As such, all reproducing adults, rather than those perceived to produce offspring during typically favorable times, must be protected from exploitation or other human-induced perturbations

Ground state energy fluctuations in the Nuclear Shell Model

Statistical fluctuations of the nuclear ground state energies are estimated using shell model calculations in which particles in the valence shells interact through well defined forces, and are coupled to an upper shell governed by random 2-body interactions. Induced ground-state energy fluctuations are found to be one order of magnitude smaller than those previously associated with chaotic components, in close agreement with independent perturbative estimates based on the spreading widths of excited states.Comment: 4 pages, 4 figures, to be published in Physics Leters