129 research outputs found

    Observations of transient high temperature vortical microstructures in solids during adiabatic shear banding

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    By using a unique infrared high-speed camera especially constructed for recording highly transient temperature fields at the microscale, we are able to reveal the spatial and temporal microstructure within dynamically growing shear bands in metals. It is found that this structure is highly nonuniform and possesses a transient, short range periodicity in the direction of shear band growth in the form of an array of intense "hot spots" reminiscent of the well-known, shear-induced hydrodynamic instabilities in fluids. This is contrary to the prevailing classical view that describes the deformations and the temperatures within shear bands as being essentially one-dimensional fields. These observations are also reminiscent of the nonuniform structure of localized shear regions believed to exist, at an entirely different length scale, in the earth's lower crust and upper mantle

    Real-time Measurement of Stress and Damage Evolution During Initial Lithiation of Crystalline Silicon

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    Crystalline to amorphous phase transformation during initial lithiation in (100) silicon-wafers is studied in an electrochemical cell with lithium metal as the counter and reference electrode. It is demonstrated that severe stress jumps across the phase boundary lead to fracture and damage, which is an essential consideration in designing silicon based anodes for lithium ion batteries. During initial lithiation, a moving phase boundary advances into the wafer starting from the surface facing the lithium electrode, transforming crystalline silicon into amorphous LixSi. The resulting biaxial compressive stress in the amorphous layer is measured in situ and it was observed to be ca. 0.5 GPa. HRTEM images reveal that the crystalline-amorphous phase boundary is very sharp, with a thickness of ~ 1 nm. Upon delithiation, the stress rapidly reverses, becomes tensile and the amorphous layer begins to deform plastically at around 0.5 GPa. With continued delithiation, the yield stress increases in magnitude, culminating in sudden fracture of the amorphous layer into micro-fragments and the cracks extend into the underlying crystalline silicon.Comment: 12 pages, 5 figure

    Investigation of Initial Lithiation of Silicon (100) Using Solid-State 7Li NMR

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    Structural changes in amorphous LixSi during the initial lithiation of single crystal Si to amorphous LixSi were investigated as a function of Li flux and total charge using solid-state 7Li nuclear magnetic resonance (NMR) spectroscopy. Single crystal (100) Si wafers were used as a model system in this study, as the Li flux could be precisely controlled and uniformly distributed across the surface of the wafer. It was observed that peak shifts in solid-state 7Li NMR spectra varied as a function of the Li flux during the initial lithiation and stayed constant for samples of the same Li flux regardless of the total charge applied to the electrodes. We conclude from these results that the Li concentration in LixSi stays constant for a given flux regardless of the total coulombic charge applied to the electrode. The results from this study help better understand the kinetics, the reaction mechanisms, and the kinetic modeling of chemical reactions at the reaction front during the initial lithiation of Si (100).Comment: 17 pages, 7 figure

    High-rate deposition of nano-crystalline silicon thin films on plastics

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    Nanocrystalline silicon (nc-Si:H) is commonly used in the bottom cell of tandem solar cells. With an indirect bandgap, nc-Si:H requires thicker (∼1 µm) films for efficient light harvesting than amorphous Si (a-Si:H) does. Therefore, thin-film high deposition rates are crucial for further cost reduction of highly efficient a–Si:H based photovoltaic technology. Plastic substrates allow for further cost reduction by enabling roll-to-roll inline deposition. In this work, high nc-Si:H deposition rates on plastic were achieved at low substrate temperature (150 °C) by standard Radio-frequency (13.56 MHz) Plasma Enhanced Chemical Vapor Deposition. Focus was on the influence of deposition pressure, inter-electrode distance (1.2 cm) and high power coupled to the plasma, on the hydrogen-to-silane dilution ratios (HD) necessary to achieve the amorphous-to-nanocrystalline phase transition and on the resulting film deposition rate. For each pressure and rf-power, there is a value of HD for which the films start to exhibit a certain amount of crystalline fraction. For constant rf-power, this value increases with pressure. Within the parameter range studied the deposition rate was highest (0.38 nm/s) for nc-Si:H films deposited at 6 Torr, 700 mW/cm2 using HD of 98.5 %. Decreasing the pressure to 3 Torr (1.5 Torr) and rf-power to 350 mW/cm2 using HD – 98.5 % deposition rate is 0.12 nm/s (0.076 nm/s). Raman crystalline fraction of these films is 72, 62 and 53 % for the 6, 3 and 1.5 Torr films, respectively.Fundação para a Ciência e a Tecnologia (FCT)DREBM/PICS_CNRS/201

    Efficient Built In Self Repair Strategy for Embedded SRAM with selecteble redundancy

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    Built-in self -test (BIST) refers to those testing techniques where additional hardware is added to a design so that testing is accomplished without the aid of external hardware. Usually, a pseudo-random generator is used to apply test vectors to the circuit under test and a data compactor is used to produce a signature. To increase the reliability and yield of embedded memories, many redundancy mechanisms have been proposed. All the redundancy mechanisms bring penalty of area and complexity to embedded memories design. Considered that compiler is used to configure SRAM for different needs, the BISR had better bring no change to other modules in SRAM. To solve the problem, a new redundancy scheme is proposed in this paper. Some normal words in embedded memories can be selected as redundancy instead of adding spare words, spare rows, spare columns or spare blocks. Built-In Self-Repair (BISR) with Redundancy is an effective yield-enhancement strategy for embedded memories. This paper proposes an efficient BISR strategy which consists of a Built-In Self-Test (BIST) module, a Built-In Address-Analysis (BIAA) module and a Multiplexer (MUX) module. The BISR is designed flexible that it can provide four operation modes to SRAM users. Each fault address can be saved only once is the feature of the proposed BISR strategy. In BIAA module, fault addresses and redundant ones form a one- to- one mapping to achieve a high repair speed. Besides, instead of adding spare words, rows, columns or blocks in the SRAMs, users can select normal words as redundancy

    Ethno-Cultural Identity of Northeast India with Reference to Temsula Ao’s Select Poems

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    Northeast part of India is known for its ethnogenic significance which has many roots of civilization, and it is distinct from the other part of the country. Therefore, the culture of Northeast India faces tremendous challenges due to its vast ethnographic diversity. Temsula Ao, is one of the most widely read and studied women writers of North-East India. She has been the recipient of many awards including the Padma Shri in 2007 and the Sahitya Akademi award in 2013.  She is also a pioneer writer from Nagaland. The main aim of this study is to explore ethno-cultural aesthetics of the Northeast Indian region which exists in Temsula Ao’s poetry. For that purpose, fifteen of her poems are selected from her anthology titled Books of Songs. The select poems were analysed qualitatively.  This descriptive qualitative research methodology deals how Ao-Naga regional people know about human values, beliefs, behavious, and social conditions within their own environmental contexts. The major finding of this paper is in what way Temsula Ao revitalizes Ao-Naga culture and tradition by picturising her region, history and condition of women relating them with nature through her poems. Implications were identified for the people of diverse cultural backgrounds. And, it is concluded that the beauty of a region is retained by the people who have a staunch belief in their traditional cultural values and ethics

    Josephson supercurrent through a topological insulator surface state

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    Topological insulators are characterized by an insulating bulk with a finite band gap and conducting edge or surface states, where charge carriers are protected against backscattering. These states give rise to the quantum spin Hall effect without an external magnetic field, where electrons with opposite spins have opposite momentum at a given edge. The surface energy spectrum of a threedimensional topological insulator is made up by an odd number of Dirac cones with the spin locked to the momentum. The long-sought yet elusive Majorana fermion is predicted to arise from a combination of a superconductor and a topological insulator. An essential step in the hunt for this emergent particle is the unequivocal observation of supercurrent in a topological phase. Here, we present the first measurement of a Josephson supercurrent through a topological insulator. Direct evidence for Josephson supercurrents in superconductor (Nb) - topological insulator (Bi2Te3) - superconductor e-beam fabricated junctions is provided by the observation of clear Shapiro steps under microwave irradiation, and a Fraunhofer-type dependence of the critical current on magnetic field. The dependence of the critical current on temperature and length shows that the junctions are in the ballistic limit. Shubnikov-de Haas oscillations in magnetic fields up to 30 T reveal a topologically non-trivial two-dimensional surface state. We argue that the ballistic Josephson current is hosted by this surface state despite the fact that the normal state transport is dominated by diffusive bulk conductivity. The lateral Nb-Bi2Te3-Nb junctions hence provide prospects for the realization of devices supporting Majorana fermions

    Effect of loading rate on fracture morphology in a high strength ductile steel

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    Fracture experiments in a high-strength ductile steel (2.3Ni-1.3Cr-0.17C) were conducted under static and dynamic loading conditions in a three-point bend and a one-point bend configurations. A qualitative description of the influence of loading rate on the microscopic features of the fracture surfaces and their role in the fracture initiation process was considered. The fracture surfaces consist of tunneled region and shear lips. The size of the shear lips increases wit increasing loading rate and is characterized by microvoids and cell structures. The tunneled region consists of large voids and micro-voids that coalesce by impingement. At high loading rates, localized molten zones are observed at the tunnel-shear lip interface

    Effect of human immunodeficiency virus on blood-brain barrier integrity and function: an update

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    The blood-brain barrier (BBB) is a diffusion barrier that has an important role in maintaining a precisely regulated microenvironment protecting the neural tissue from infectious agents and toxins in the circulating system. Compromised BBB integrity plays a major role in the pathogenesis of retroviral associated neurological diseases. Human Immunodeficiency Virus (HIV) infection in the Central Nervous System (CNS) is an early event even before the serodiagnosis for HIV positivity or the initiation of antiretroviral therapy (ART), resulting in neurological complications in many of the infected patients. Macrophages, microglia and astrocytes (in low levels) are the most productively/latently infected cell types within the CNS. In this brief review, we have discussed about the effect of HIV infection and viral proteins on the integrity and function of BBB, which may contribute to the progression of HIV associated neurocognitive disorders
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