Prussian Blue-coated interdigitated array electrodes for possible analytical application

Thin films of iron(III) hexacyanoferrate(II) (Prussian Blue) were electrochemically deposited on interdigitated array (IDA) electrodes, yielding systems which can be considered as chemiresistors in sensing alkali metal ion concentrations in an adjacent electrolyte. This is due to the fact that the conductivity of the film being measured by a steady-state current on application of a voltage to the two-fingered electrodes of the IDA depends on both the redox stare of the film and the cation concentration in the electrolyte. From the dependence of the steady-state current on the electrode (bias) potential at variable cation concentrations for different alkali metal ions and for mixtures of alkali metal ions, the possibilities of analytical application were elucidated. In addition, by using the methods of staircase coulometry and scanning conductivity, the electron diffusion coefficient De was determined as a function of the redox state of Prussian Blue. It is concluded that Prussian Blue-coated IDA electrodes are, in principle, suitable as chemiresistors for the determination of alkali metal ion concentrations with increasing selectivity in the series Li < Na < K < Rb < Cs

Can type II Semi-local cosmic strings form?

We present the simplest possible model for a semi-local string defect in which a U(1) gauged subgroup of an otherwise global SU(2) is broken to produce local cosmic strings endowed with current-carrying properties. Restricting attention to type II vortices for which the non current-carrying state is unstable, we show that a condensate must form microscopically and macroscopically evolve towards a chiral configuration. It has been suggested that such configurations could potentially exist in a stable state, thereby inducing large cosmological consequences based on equilibrium angular momentum supported loop configurations (vortons). Here we show that the current itself induces a macroscopic (longitudinal) instability: we conclude that type II semi-local cosmic strings cannot form in a cosmological context.Comment: 11 pages, 5 figure

THE ECONOMIC IMPLICATIONS OF CHEMICAL USE RESTRICTIONS IN AGRICULTURE

Agricultural and Food Policy, Crop Production/Industries,

Molecular Dynamics in grafted layers of poly(dimethylsiloxane) (PDMS)

Dielectric relaxation spectroscopy 10^-1 Hz to 10^6 Hz) is employed to study the molecular dynamics of poly(dimethylsiloxane) (PDMS, Mw=1.7 10^5 g/mol and Mw=9.6 10^4 g/mol as grafted films with thicknesses d below and above the radius of gyration Rg. For d smaller than Rg the molecular dynamics becomes faster by up to three orders of magnitude with respect to the bulk resulting in a pronounced decrease of the Vogel temperature T0 and hence the calorimetric glass transition temperature Tg. For d larger than Rg the molecular dynamics is comparable to that of the bulk melt. The results are interpreted in terms of a chain confinement effect and compared with the findings for low molecular eight glass forming liquids contained in nanoporous glasses and zeolites. Crystallization effects - well known for PDMS - are observed for films of thicknesses above and below Rg.Comment: 20 pages, 4 figure

Higher harmonics of the magnetoplasmon in strongly coupled Coulomb and Yukawa systems

The generation of higher harmonics of the magnetoplasmon frequency which has recently been reported in strongly coupled two-dimensional Yukawa systems is investigated in detail and, in addition, extended to two-dimensional Coulomb systems. We observe higher harmonics over a much larger frequency range than before and compare the theoretical prediction with the simulations. The influence of the coupling, structure, and thermal energy on the excitation of these modes is examined in detail. We also report on the effect of friction on the mode spectra to make predictions about the experimental observability of this new effect