Excitation Spectrum and Superexchange Pathways in the Spin Dimer VODPO_4 . 1/2 D_2O

Magnetic excitations have been investigated in the spin dimer material VODPO_4 \cdot 1/2 D_2O using inelastic neutron scattering. A dispersionless magnetic mode was observed at an energy of 7.81(4) meV. The wavevector dependence of the scattering intensityfrom this mode is consistent with the excitation of isolated V^{4+} spin dimers with a V-V separation of 4.43(7) \AA. This result is unexpected since the V-V pair previously thought to constitute themagnetic dimer has a separation of 3.09 \AA. We identify an alternative V-V pair as the likely magnetic dimer, which involves superexchange pathways through a covalently bonded PO_4 group. This surprising result casts doubt on the interpretation of (VO)_2P_2O_7 as a spin ladder.Comment: 4 pages, 4 postscript figures - identical to previous paper but figure 2 and 3 hopefully more compatible .p

Hybrid PIPSO-SQP algorithm for real power loss minimization in radial distribution systems with optimal placement of distributed generation

This paper proposes the hybrid sequential quadratic programming (SQP) technique based on active set method for identifying the optimal placement and rating of distribution generation (DG) incorporated in radial distribution systems (RDS) for minimizing the real power loss satisfying power balance equations and voltage limits. SQP runs quadratic programming sequentially as a sub-program to obtain the best solution by using an active set method. In this paper, the best optimal solution is selected with less computation time by combining the benefits of both classical and meta-heuristic methods. SQP is a classical method that is more sensitive to initial value selection and the evolutionary methods give approximate solution. Hence, the initial values for the SQP technique were obtained from the meta–heuristic method of Parameter Improved Particle Swarm Optimization (PIPSO) algorithm. The proposed hybrid PIPSO–SQP method was implemented in IEEE 33-bus RDS, IEEE 69-bus RDS, and IEEE 118-bus RDS under different loading conditions. The results show that the proposed method has efficient reduction in real power loss minimization through the enhancement of the bus voltage profile

Application of higher-order spectra for signal processing in electrical power engineering

In power spectrum estimation, the signal under consideration is processed in such a way, that the distribution of power among its frequency is estimated and phase relations between the frequency components are suppressed. Higher order statistics and their associated Fourier transforms reveal not only amplitude information about a signal, but also phase information. If a non-Gaussian signal is received along with additive Gaussian noise, a transformation to higher order cumulant domain eliminates the noise. These are some methods for estimation of signal components, based on HOS. In the paper we apply the MUSIC method both for the correlation and the 4th order cumulant, to investigate the state of asynchronous running of synchronous machines and the fault operation of inverter-fed induction motors. When the investigated signal is distorted by a coloured noise, more exact results can be achieved by applying cumulants

DC Grid for Domestic Electrification

Various statistics indicate that many of the parts of India, especially rural and island areas have either partial or no access to electricity. The main reason for this scenario is the immense expanse of which the power producing stations and the distribution hubs are located from these rural and distant areas. This emphasizes the significance of subsidiarity of power generation by means of renewable energy resources. Although in current energy production scenario electricity supply is principally by AC current, a large variety of the everyday utility devices like cell phone chargers, computers, laptop chargers etc. all work internally with DC power. The count of intermediate energy transfer steps are significantly abridged by providing DC power to mentioned devices. The paper also states other works that prove the increase in overall system efficiency and thereby cost reduction. With an abundance of solar power at disposal and major modification in the area of power electronic conversion devices, this article suggests a DC grid that can be used for a household in a distant or rural area to power the aforementioned, utilizing Solar PV. A system was designed for a household which is not connected to the main grid and was successfully simulated for several loads totaling to 250 W with the help of an isolated flyback converter at the front end and suitable power electronic conversion devices at each load points. Maximum abstraction of operational energy from renewable sources at a residential and commercial level is intended with the suggested direct current systems

Combined harmonic reduction and DC voltage regulation of a single DC source five-level multilevel inverter for wind electric system

Wind power generation has increased in the past twenty years due to the development of power electronic converters. Power generation through wind has advantages over other renewable sources, such as having more efficiency, being pollution-free, and its abundant availability. Power electronic converters play a vital role in the wind energy conversion system. This paper presents a wind-electric system with a permanent magnet synchronous generator, diode rectifier, DC-DC converter (buck-Boost or Cuk converter), and a three-phase five-level inverter. The five-level inverter is a modified form of a cascaded H-bridge inverter that uses a single DC source as an input irrespective of several levels and phases. As the wind speed changes, the Permanent Magnet Synchronous Generator (PMSG) voltage and frequency changes, but for practical applications, these changes should not be allowed; hence, a voltage controller is used that maintains the output voltage of a DC converter, andthus a constant AC output is obtained. The DClink voltage is maintained at the desired voltage by a Proportional plus Integral (PI)-based voltage controller. The DC link voltage fed to the multilevel inverter (MLI) is converted to AC to feed the load. The MLI is controlled with a new Selected Harmonic Elimination (SHE), which decreases the total harmonic distortion (THD). The system is simulated with an Resistive plus Inductive (RL) load and is tested experimentally with the same load;the results prove that the Cuk converter has a better efficiency compared to the Buck-Boost converter, and the system has less THD when compared with the conventional SHE Pulse Width Modulation (PWM) technique

Optimal operation of an integrated hybrid renewable energy system with demand-side management in a rural context

A significant portion of the Indian population lives in villages, some of which are located in grid-disconnected remote areas. The supply of electricity to these villages is not feasible or cost-effective, but an autonomous integrated hybrid renewable energy system (IHRES) could be a viable alternative. Hence, this study proposed using available renewable energy resources in the study area to provide electricity and freshwater access for five un-electrified grid-disconnected villages in the Odisha state of India. This study concentrated on three different kinds of battery technologies such as lithium-ion (Li-Ion), nickel-iron (Ni-Fe), and lead-acid (LA) along with a diesel generator to maintain an uninterrupted power supply. Six different configurations with two dispatch strategies such as load following (LF) and cycle charging (CC) were modelled using nine metaheuristic algorithms to achieve an optimally configured IHRES in the MATLAB (c) environment. Initially, these six configurations with LF and CC strategies were evaluated with the load demands of a low-efficiency appliance usage-based scenario, i.e., without demand-side management (DSM). Later, the optimal configuration obtained from the low-efficiency appliance usage-based scenario was further evaluated with LF and CC strategies using the load demands of medium and high-efficiency appliance usage-based scenarios, i.e., with DSM. The results showed that the Ni-Fe battery-based IHRES with LF strategy using the high-efficiency appliance usage-based scenario had a lower life cycle cost of USD 522,945 as compared to other battery-based IHRESs with LF and CC strategies, as well as other efficiency-based scenarios. As compared to the other algorithms used in the study, the suggested Salp Swarm Algorithm demonstrated its fast convergence and robustness effectiveness in determining the global best optimum values. Finally, the sensitivity analysis was performed for the proposed configuration using variable input parameters such as biomass collection rate, interest rate, and diesel prices. The interest rate fluctuations were found to have a substantial impact on the system's performance.Web of Science1514art. no. 517

Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D

[EN] Single metal atoms and metal clusters have attracted much attention thanks to their advantageous capabilities as heterogeneous catalysts. However, the generation of stable single atoms and clusters on a solid support is still challenging. Herein, we report a new strategy for the generation of single Pt atoms and Pt clusters with exceptionally high thermal stability, formed within purely siliceous MCM-22 during the growth of a two-dimensional zeolite into three dimensions. These subnanometric Pt species are stabilized by MCM-22, even after treatment in air up to 540 degrees C. Furthermore, these stable Pt species confined within internal framework cavities show size-selective catalysis for the hydrogenation of alkenes. High-temperature oxidation-reduction treatments result in the growth of encapsulated Pt species to small nanoparticles in the approximate size range of 1 to 2 nm. The stability and catalytic activity of encapsulated Pt species is also reflected in the dehydrogenation of propane to propylene.This work was funded by the Spanish Government (Consolider Ingenio 2010-MULTICAT (CSD2009-00050) and MAT2014-52085-C2-1-P) and by the Generalitat Valenciana (Prometeo). The Severo Ochoa Program (SEV-2012-0267) is gratefully acknowledged. L.L. thanks ITQ for a contract. The authors also thank the Microscopy Service of UPV for the TEM and STEM measurements. The HAADF-HRSTEM works were conducted in the Laboratorio de Microscopias Avanzadas (LMA) at the Instituto de Nanociencia de Aragon (INA)-Universidad de Zaragoza (Spain), a Spanish ICTS National Facility. Some of the research leading to these results has received funding from the European Union Seventh Framework Program under Grant Agreement 312483-ESTEEM2 (Integrated Infrastructure Initiative-I3). 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