Anomalous temperature dependence of the band-gap in Black Phosphorus

Black Phosphorus (BP) has gained renewed attention due to its singular anisotropic electronic and optical properties that might be exploited for a wide range of technological applications. In this respect, the thermal properties are particularly important both to predict its room temperature operation and to determine its thermoelectric potential. From this point of view, one of the most spectacular and poorly understood phenomena is, indeed, the BP temperature-induced band-gap opening: when temperature is increased the fundamental band-gap increases instead of decreasing. This anomalous thermal dependence has also been observed, recently, in its monolayer counterpart. In this work, based on \textit{ab-initio} calculations, we present an explanation for this long known, and yet not fully explained, effect. We show that it arises from a combination of harmonic and lattice thermal expansion contributions, which are, in fact, highly interwined. We clearly narrow down the mechanisms that cause this gap opening by identifying the peculiar atomic vibrations that drive the anomaly. The final picture we give explains both the BP anomalous band-gap opening and the frequency increase with increasing volume (tension effect).Comment: Published in Nano Letter

The mechanical resistance of saturated stones

This paper aims at investigating the effect of the presence of water on the mechanical resistance of stones. The presence of water, connected to the intrinsic properties of the stone (mineralogical composition, fabric, texture, etc.) and to the conditions of use (anchoring systems, climatic parameters, etc ), is the main cause of stone decay. However, the presence of water alone inside stone could cause a decrease in mechanical resistance . The obtained data could in fact be useful to correct the safety coefficient and should be taken into account in the planning of structural stonework. Moreover, useful suggestions can be drawn for the in situ monitoring, taking into account that non destructive tests, together with conventional mechanical methods, are influenced by the presence of water in stones and should be corrected. Three kinds of stones, which have historically been used for structural purposes, have been studied: Pietra di Luserna (gneiss, Piedmont, Italy), Pietra Verde Argento (gneiss, Piedmont, Italy) and Pietra di Courtil (mica-schist, Aosta Valley, Italy). The flexural strength, rupture energy, open porosity and ultrasonic pulse velocity (UPV) have been determined on specimens in dried and saturated conditions at different accelerated ageing steps. As far as the UPV test is concerned, its results are well correlated with the flexural strength values but, without other parameters, it cannot give information on whether the specimen is filled with water, therefore suitable procedures to correct the UPV value obtained in situ are suggested. Destructive methods, and in particular the flexural strength method, instead, give lower resistance values for saturated specimens than dried ones, thus confirming the weakness of the stone due to the water insid

Monopolistic competition, expected inflation and contract length

Monopoly

Ambiguity resolution for satellite Doppler positioning systems

A test for ambiguity resolution was derived which was the most powerful in the sense that it maximized the probability of a correct decision. When systematic error sources were properly included in the least squares reduction process to yield an optimal solution, the test reduced to choosing the solution which provided the smaller valuation of the least squares loss function. When systematic error sources were ignored in the least squares reduction, the most powerful test was a quadratic form comparison with the weighting matrix of the quadratic form obtained by computing the pseudo-inverse of a reduced rank square matrix. A formula is presented for computing the power of the most powerful test. A numerical example is included in which the power of the test is computed for a situation which may occur during an actual satellite aided search and rescue mission

Raman spectroscopy study of the interface structure in (CaCuO2)n/(SrTiO3)m superlattices

Raman spectra of CaCuO2/SrTiO3 superlattices show clear spectroscopic marker of two structures formed in CaCuO2 at the interface with SrTiO3. For non-superconducting superlattices, grown in low oxidizing atmosphere, the 425 cm-1 frequency of oxygen vibration in CuO2 planes is the same as for CCO films with infinite layer structure (planar Cu-O coordination). For superconducting superlattices grown in highly oxidizing atmosphere, a 60 cm-1 frequency shift to lower energy occurs. This is ascribed to a change from planar to pyramidal Cu-O coordination because of oxygen incorporation at the interface. Raman spectroscopy proves to be a powerful tool for interface structure investigation

Besoins en eau de Cenchrus ciliaris, plante fourragère dans l'Ouest de Madagascar

L'étude des besoins en eau de Cenchrus ciliaris plante fourragère très bien appétée par le zébu malgache a été réalisée au cours de 2 campagnes à l'aide de la méthode neutronique de mesure de l'humidité des sols. On a défini un cofficient égal au rapport de l'évapotranspiration réelle maximale (ETRM) à l'évaporation d'un bac classe A (Ev. Bac), est égal à 0,40 pour les 10 premiers jours du cycle et à 0,80 pour les 30 jours suivants. Une culture de Cenchrus irriguée dans ces conditions pendant 4 années successives a donné une production de matière sèche égale à 18,7 kg par ha et par mm d'eau utile reçu

Efficacy of Two Common Methods of Application of Residual Insecticide for Controlling the Asian Tiger Mosquito, Aedes albopictus (Skuse), in Urban Areas

After its first introduction in the 1980's the Asian tiger mosquito, Aedes albopictus (Skuse), has spread throughout Southern Europe. Ae. albopictus is considered an epidemiologically important vector for the transmission of many viral pathogens such as the yellow fever virus, dengue fever and Chikungunya fever, as well as several filarial nematodes such as Dirofilaria immitis or D. repens. It is therefore crucial to develop measures to reduce the risks of disease transmission by controlling the vector populations. The aim of the study was to compare the efficacy of two application techniques (mist vs. stretcher sprayer) and two insecticides (Etox based on the nonester pyrethroid Etofenprox vs. Microsin based on the pyrethroid type II Cypermetrin) in controlling adult tiger mosquito populations in highly populated areas. To test the effect of the two treatments pre- and post-treatment human landing rate counts were conducted for two years. After one day from the treatment we observed a 100% population decrease in mosquito abundance with both application methods and both insecticides. However, seven and 14 days after the application the stretcher sprayer showed larger population reductions than the mist sprayer. No effect of insecticide type after one day and 14 days was found, while Etox caused slightly higher population reduction than Microsin after seven days. Emergency measures to locally reduce the vector populations should adopt adulticide treatments using stretcher sprayers. However, more research is still needed to evaluate the potential negative effects of adulticide applications on non-target organisms

A Soluble Phase Field Model

The kinetics of an initially undercooled solid-liquid melt is studied by means of a generalized Phase Field model, which describes the dynamics of an ordering non-conserved field phi (e.g. solid-liquid order parameter) coupled to a conserved field (e.g. thermal field). After obtaining the rules governing the evolution process, by means of analytical arguments, we present a discussion of the asymptotic time-dependent solutions. The full solutions of the exact self-consistent equations for the model are also obtained and compared with computer simulation results. In addition, in order to check the validity of the present model we confronted its predictions against those of the standard Phase field model and found reasonable agreement. Interestingly, we find that the system relaxes towards a mixed phase, depending on the average value of the conserved field, i.e. on the initial condition. Such a phase is characterized by large fluctuations of the phi field.Comment: 13 pages, 8 figures, RevTeX 3.1, submitted to Physical Review

The inelastic hard dimer gas: a non-spherical model for granular matter

We study a two-dimensional gas of inelastic smooth hard dimers. Since the collisions between dimers are dissipative, being characterized by a coefficient of restitution $\alpha<1$, and no external driving force is present, the energy of the system decreases in time and no stationary state is achieved. However, the resulting non equilibrium state of the system displays several interesting properties in close analogy with systems of inelastic hard spheres, whose relaxational dynamics has been thoroughly explored. We generalise to inelastic systems a recently method introduced [G.Ciccotti and G.Kalibaeva, J. Stat. Phys. {\bf 115}, 701 (2004)] to study the dynamics of rigid elastic bodies made up of different spheres hold together by rigid bonds. Each dimer consists of two hard disks of diameter $d$, whose centers are separated by a fixed distance $a$. By describing the rigid bonds by means of holonomic constraints and deriving the appropriate collision rules between dimers, we reduce the dynamics to a set of equations which can be solved by means of event driven simulation. After deriving the algorithm we study the decay of the total kinetic energy, and of the ratio between the rotational and the translational kinetic energy of inelastic dimers. We show numerically that the celebrated Haff's homogeneous cooling law $t^{-2}$, describing how the kinetic energy of an inelastic hard sphere system with constant coefficient of restitution decreases in time, holds even in the case of these non spherical particles. We fully characterize this homogeneous decay process in terms of appropriate decay constants and confirm numerically the scaling behavior of the velocity distributions.Comment: 21 pages, 6 figures and 2 tables, submitted to JC