Excitation Mechanisms of the Nitrogen First‐Positive and First‐Negative Radiation at High Temperature

The kinetic mechanisms responsible for the excitation of the first-positive and first-negative emission of nitrogen have been investigated in a re-examination of previously reported shock-tube measurements of the nonequilibrium radiation for these systems. The rate coefficients of the collisional quenching reactions, N_2(A^(3)Σ^(+)_u)(^(k^(N)_(-2))⇒) N_2(X^(1)Σ^(+)_g) + N(^(4)S) and N^(+)_2(B^(2)Σ^(+)_u) + N_2(X^(1)Σ^(+)_g)(^(k^(N)_(q))⇒) N^(+)_2(X^(2)Σ^(+)_g) or N^(+)_2(A(^(2)II_u)+N_2(X^(1)Σ^(+)_g) were found to be given by the empirical expressions, k_(2^(N))=5.1x10^(-3)T^(-2.23) cm^3 sec^(-1) and k_(q^(N_2))=1.9x10^(-2)T^(-2.33)cm^3 sec^(-1), respectively, over the approximate temperature range 6000-14 000°K

Shock-tube measurements of carbon to oxygen atom ratios for incipient soot formation with C2H2, C2H4 and C2H6 fuels

The critical atomic carbon to oxygen ratios, Phi sub C, for incipient soot formation in shock heated acetylene, ethylene, ethane/oxygen/ argon mixtures was measured over the temperature range 2000 K to 2500 K for reactant partial pressures between 0.1 and 0.4 atoms. Absorption of light from a He-Ne laser at 6328A was was used to detect soot. It was observed that the values of Phi sub C for all three fuels increased uniformly with temperature such that at the highest temperatures Phi sub C was considerably greater than unity, i.e. greater than the value of about unity at which solid carbon should have been precipitated on a thermochemical equilibrium basis. Observations were made over periods extending up to about one millisecond, which was well in excess of the time required for the major heat release of the combustion reactions. The relevance of these experimental findings to the problem of soot formation in gas turbine combustion chambers is discussed

H2 formation and excitation in the Stephan's Quintet galaxy-wide collision

Context. The Spitzer Space Telescope has detected a powerful (L(H2)~10^41 erg s-1) mid-infrared H2 emission towards the galaxy-wide collision in the Stephan's Quintet (SQ) galaxy group. This discovery was followed by the detection of more distant H2-luminous extragalactic sources, with almost no spectroscopic signatures of star formation. These observations set molecular gas in a new context where one has to describe its role as a cooling agent of energetic phases of galaxy evolution. Aims. The SQ postshock medium is observed to be multiphase, with H2 gas coexisting with a hot (~ 5 10^6 K), X-ray emitting plasma. The surface brightness of H2 lines exceeds that of the X-rays and the 0-0 S(1) H2 linewidth is ~ 900 km s-1, of the same order of the collision velocity. These observations raise three questions we propose to answer: (i) Why H2 is present in the postshock gas ? (ii) How can we account for the H2 excitation ? (iii) Why H2 is a dominant coolant ? Methods. We consider the collision of two flows of multiphase dusty gas. Our model quantifies the gas cooling, dust destruction, H2 formation and excitation in the postshock medium. Results. (i) The shock velocity, the post-shock temperature and the gas cooling timescale depend on the preshock gas density. The collision velocity is the shock velocity in the low density volume filling intercloud gas. This produces a ~ 5 10^6 K, dust-free, X-ray emitting plasma. The shock velocity is smaller in clouds. We show that gas heated to temperatures less than 10^6 K cools, keeps its dust content and becomes H2 within the SQ collision age (~ 5 10^6 years). (ii) Since the bulk kinetic energy of the H2 gas is the dominant energy reservoir, we consider that the H2 emission is powered by the dissipation of kinetic turbulent energy. (Abridged)Comment: 19 pages, 12 figures. Accepted for publication in Astronomy & Astrophysics Minor editing and typo

A Study of Heating and Cooling of the ISM in NGC 1097 with Herschel-PACS and Spitzer-IRS

NGC 1097 is a nearby Seyfert 1 galaxy with a bright circumnuclear starburst ring, a strong large-scale bar, and an active nucleus. We present a detailed study of the spatial variation of the far-infrared (FIR) [C II]158 μm and [O I]63 μm lines and mid-infrared H_2 emission lines as tracers of gas cooling, and of the polycyclic aromatic hydrocarbon (PAH) bands as tracers of the photoelectric heating, using Herschel-PACS and Spitzer-IRS infrared spectral maps. We focus on the nucleus and the ring, and two star-forming regions (Enuc N and Enuc S). We estimated a photoelectric gas heating efficiency ([C II]158 μm+[O I]63 μm)/PAH in the ring about 50% lower than in Enuc N and S. The average 11.3/7.7 μm PAH ratio is also lower in the ring, which may suggest a larger fraction of ionized PAHs, but no clear correlation with [C II]158 μm/PAH(5.5-14 μm) is found. PAHs in the ring are responsible for a factor of two more [C II]158 μm and [O I]63 μm emission per unit mass than PAHs in the Enuc S. spectral energy distribution (SED) modeling indicates that at most 25% of the FIR power in the ring and Enuc S can come from high-intensity photodissociation regions (PDRs), in which case G_0 ~ 10^(2.3) and n_H ~ 10^(3.5) cm^(–3) in the ring. For these values of G_0 and n_H, PDR models cannot reproduce the observed H2 emission. Much of the H2 emission in the starburst ring could come from warm regions in the diffuse interstellar medium that are heated by turbulent dissipation or shocks

A stochastic model of turbulent mixing with chemical reaction: Nitric oxide formulation in a plug-flow burner

A stochastic model of turbulent mixing was developed for a reactor in which mixing is represented by n-body fluid particle interactions. The model was used to justify the assumption (made in previous investigations of the role of turbulent mixing on burner generated thermal nitric oxide and carbon monoxide emissions) that for a simple plug flow reactor, composition nonuniformities can be described by a Gaussian distribution function in the local fuel:air equivalence ratio. Recent extensions of this stochastic model to include the combined effects of turbulent mixing and secondary air entrainment on thermal generation of nitric oxide in gas turbine combustors are discussed. Finally, rate limited upper and lower bounds of the nitric oxide produced by thermal fixation of molecular nitrogen and oxidation of organically bound fuel nitrogen are estimated on the basis of the stochastic model for a plug flow burner; these are compared with experimental measurements obtained using a laboratory burner operated over a wide range of test conditions; good agreement is obtained

Multi-waveband observations of colliding galaxies

Colliding galaxies represent a major challenge to both theorists and observers because of the large variety of phenomena which are expected to come into play during the interaction. Strong gravitational fluctuations may drive non-linear waves and instabilities throughout the stars and gas leading to enhanced star formation, nuclear activity and ultimately a mixing of the morphological components of the original galaxies. One relatively uncomplicated class of colliding galaxy where stellar waves play an important role in star formation are ring galaxies. Ring galaxies are probably formed when a companion galaxy passes through the center of a disk system driving circular waves through the disk (Lynds and Toomre 1976, Toomre 1978, Struck-Marcell 1990). Off-center collisions can generate non-circular waves and can be loosely described as banana-shaped although they may exhibit more complex forms as the waves expand into the disk. The propagation of such stellar and gaseous waves through the disk leads to enhanced star formation (e.g., Appleton and Struck-Marcell 1987a; Jeske 1986) and provides a unique probe of the response of the interstellar medium (ISM) to a propagating wave (see Appleton and Struck-Marcell 1987b). Here, the authors report results for 3 systems; the irregular ring Arp 143 (=VV 117); Wakamatsu's Seyfert ring (A0959-755; see Wakamatsu and Nishida 1987) and the brighter member of the pair of ring galaxies comprising of AM 1358-221. The most complete multi-wavelength data is for Arp 143. Optical charge coupled device (CCD) observations made with the 60 inch Palomar telescope at BV and r band, near-IR images at J (1.25 microns), H (1.65 microns) and k (2.2 microns) bands from the infrared camera (IRCAM) InSb array camera on the 3.8m United Kingdon Infrared Telescope (UKIRT) telescope and very large array (VLA) observations at 20cm in both the neutral hydrogen line and radio continuum are described. The observations of Wakamatsu's ring and AM 1358 were made only in the near-IR, and a comparison is made with available optical plate material

Enhanced dust heating in the bulges of early-type spiral galaxies

Stellar density and bar strength should affect the temperatures of the cool (T ~ 20–30 K) dust component in the inner regions of galaxies, which implies that the ratio of temperatures in the circumnuclear regions to the disk should depend on Hubble type. We investigate the differences between cool dust temperatures in the central 3 kpc and disk of 13 nearby galaxies by fitting models to measurements between 70 and 500 μm. We attempt to quantify temperature trends in nearby disk galaxies, with archival data from Spitzer/MIPS and new observations with Herschel/SPIRE, which were acquired during the first phases of the Herschel observations for the KINGFISH (Key Insights on Nearby Galaxies: a Far-Infrared Survey with Herschel) sample. We fit single-temperature modified blackbodies to far-infrared and submillimeter measurements of the central and disk regions of galaxies to determine the temperature of the component(s) emitting at those wavelengths. We present the ratio of central-region-to-disk-temperatures of the cool dust component of 13 nearby galaxies as a function of morphological type. We find a significant temperature gradient in the cool dust component in all galaxies, with a mean center-to-disk temperature ratio of 1.15 ± 0.03. The cool dust temperatures in the central ~3 kpc of nearby galaxies are 23 (±3)% hotter for morphological types earlier than Sc, and only 9 (±3)% hotter for later types. The temperature ratio is also correlated with bar strength, with only strongly barred galaxies having a ratio over 1.2. The strong radiation field in the high stellar density of a galactic bulge tends to heat the cool dust component to higher temperatures, at least in early-type spirals with relatively large bulges, especially when paired with a strong bar

Soot oxidation rates in gas turbine engines

A basis is proposed for extrapolating soot oxidation rate measurements obtained in laboratory flames to the more extreme operating conditions of gas turbine combustion chambers. The proposal is based on the observation that, within probable experimental uncertainty, the limited soot oxidation measurements correlate with the more extensive measurements of the surface oxidation rates of macroscopic samples of pyrographite. The soot oxidation rates thus determined for the conditions of a typical gas turbine combustion chamber are considerably lower than estimates which were based on simple extrapolations of the flame data