Properties of Phase transitions of a Higher Order

The following is a thermodynamic analysis of a III order (and some aspects of a IV order) phase transition. Such a transition can occur in a superconductor if the normal state is a diamagnet. The equation for a phase boundary in an H-T (H is the magnetic field, T, the temperature) plane is derived. by considering two possible forms of the gradient energy, it is possible to construct a field theory which describes a III or a IV order transition and permits a study of thermal fluctuations and inhomogeneous order parameters.Comment: 13 pages, revtex, no figure

Organic acids as cloud condensation nuclei: Laboratory studies of highly soluble and insoluble species

International audienceThe ability of sub-micron-sized organic acid particles to act as cloud condensation nuclei (CCN) has been examined at room temperature using a newly constructed continuous-flow, thermal-gradient diffusion chamber (TGDC). The organic acids studied were: oxalic, malonic, glutaric, oleic and stearic. The CCN properties of the highly soluble acids - oxalic, malonic and glutaric - match very closely Köhler theory predictions which assume full dissolution of the dry particle and a surface tension of the growing droplet equal to that of water. In particular, for supersaturations between 0.3 and 0.6, agreement between the dry particle diameter which gives 50% activation and that calculated from Köhler theory is to within 3nm on average. In the course of the experiments, considerable instability of glutaric acid particles was observed as a function of time and there is evidence that they fragment to some degree to smaller particles. Stearic acid and oleic acid, which are both highly insoluble in water, did not activate at supersaturations of 0.6% with dry diameters up to 140nm. Finally, to validate the performance of the TGDC, we present results for the activation of ammonium sulfate particles that demonstrate good agreement with Köhler theory if solution non-ideality is considered. Our findings support earlier studies in the literature that showed highly soluble organics to be CCN active but insoluble species to be largely inactive

Comparison of aerosol products retrieved from AERONET, MICROTOPS and MODIS over a tropical urban city, Pune, India

Aerosol Optical Depth (AOD) measurements from Aerosol Robotic NETwork (AERONET; level 2.0), Microtops - II sun-photometer and MODerate Resolution Imaging Spectroradiometer (MODIS) (Terra and Aqua; level 2, collection 5, dark target) were compared and used to characterize aerosols over Pune, India. AODs from Microtops and MODIS were compared with those measured by AERONET to evaluate the measurement quality. To the best of our knowledge, this is the first systematic comparison of MODIS aerosol products over Pune, India. The results of the analysis show that during 2008-10, 68 to 84 of the MODIS AODs fell within an expected error, as defined by the MODIS science team, and thus the retrievals from this system are validated and accepted. In addition, during pre-monsoon periods MODIS retrievals are better-matched with ground-based measurements. On the seasonal scale, MODIS retrievals corroborate well with ground-based measurements, with correlation coefficients ranging from 0.62 to 0.93. Despite an overall satellite-ground agreement, MODIS tends to under-estimate AOD during winter, and this may be due to improper assumptions of surface reflectance and the incorrect selection of aerosol types. AERONET retrieved single scattering albedo (SSA) values in winter (0.82-0.86), suggesting the dominance of absorbing aerosols, slightly increased (0.87-0.89) in pre-monsoon season, indicating more scattering type of aerosols. These values are about 8.9-1.1 lower than those of the assumed SSA values in the MODIS algorithm

Raman Evidence for Superconducting Gap and Spin-Phonon Coupling in Superconductor Ca(Fe0.95Co0.05)2As2

Inelastic light scattering studies on single crystal of electron-doped Ca(Fe0.95Co0.05)2As2 superconductor, covering the tetragonal to orthorhombic structural transition as well as magnetic transition at TSM ~ 140 K and superconducting transition temperature Tc ~ 23 K, reveal evidence for superconductivity-induced phonon renormalization; in particular the phonon mode near 260 cm-1 shows hardening below Tc, signaling its coupling with the superconducting gap. All the three Raman active phonon modes show anomalous temperature dependence between room temperature and Tc i.e phonon frequency decreases with lowering temperature. Further, frequency of one of the modes shows a sudden change in temperature dependence at TSM. Using first-principles density functional theory-based calculations, we show that the low temperature phase (Tc < T < TSM) exhibits short-ranged stripe anti-ferromagnetic ordering, and estimate the spin-phonon couplings that are responsible for these phonon anomalies

Effect of water-wall interaction potential on the properties of nanoconfined water

Much of the understanding of bulk liquids has progressed through study of the limiting case in which molecules interact via purely repulsive forces, such as a hard-core potential. In the same spirit, we report progress on the understanding of confined water by examining the behavior of water-like molecules interacting with planar walls via purely repulsive forces and compare our results with those obtained for Lennard-Jones (LJ) interactions between the molecules and the walls. Specifically, we perform molecular dynamics simulations of 512 water-like molecules which are confined between two smooth planar walls that are separated by 1.1 nm. At this separation, there are either two or three molecular layers of water, depending on density. We study two different forms of repulsive confinements, when the interaction potential between water-wall is (i) $1/r^9$ and (ii) WCA-like repulsive potential. We find that the thermodynamic, dynamic and structural properties of the liquid in purely repulsive confinements qualitatively match those for a system with a pure LJ attraction to the wall. In previous studies that include attractions, freezing into monolayer or trilayer ice was seen for this wall separation. Using the same separation as these previous studies, we find that the crystal state is not stable with $1/r^9$ repulsive walls but is stable with WCA-like repulsive confinement. However, by carefully adjusting the separation of the plates with $1/r^9$ repulsive interactions so that the effective space available to the molecules is the same as that for LJ confinement, we find that the same crystal phases are stable. This result emphasizes the importance of comparing systems only using the same effective confinement, which may differ from the geometric separation of the confining surfaces.Comment: 20 pages, 10 figure

Theory of a Higher Order Phase Transition: Superconducting Transition in BKBO

We describe here the properties expected of a higher (with emphasis on the order fourth) order phase transition. The order is identified in the sense first noted by Ehrenfest, namely in terms of the temperature dependence of the ordered state free energy near the phase boundary. We have derived an equation for the phase boundary in terms of the discontinuities in thermodynamic observables, developed a Ginzburg-Landau free energy and studied the thermodynamic and magnetic properties. We also discuss the current status of experiments on $Ba_{0.6}K_{0.4}BiO_3$ and other $BiO_3$ based superconductors, the expectations for parameters and examine alternative explanations of the experimental results.Comment: 18 pages, no figure