The petrogenesis of sodic island arc magmas at Savo volcano, Solomon Islands

Savo, Solomon Islands, is a historically active volcano dominated by sodic, alkaline lavas, and pyroclastic rocks with up to 7.5 wt% Na2O, and high Sr, arc-like trace element chemistry. The suite is dominated by mugearites (plagioclase–clinopyroxene–magnetite ± amphibole ± olivine) and trachytes (plagioclase–amphibole–magnetite ± biotite). The presence of hydrous minerals (amphibole, biotite) indicates relatively wet magmas. In such melts, plagioclase is relatively unstable relative to iron oxides and ferromagnesian silicates; it is the latter minerals (particularly hornblende) that dominate cumulate nodules at Savo and drive the chemical differentiation of the suite, with a limited role for plagioclase. This is potentially occurring in a crustal “hot zone”, with major chemical differentiation occurring at depth. Batches of magma ascend periodically, where they are subject to decompression, water saturation and further cooling, resulting in closed-system crystallisation of plagioclase, and ultimately the production of sodic, crystal and feldspar-rich, high-Sr rocks. The sodic and hydrous nature of the parental magmas is interpreted to be the result of partial melting of metasomatised mantle, but radiogenic isotope data (Pb, Sr, Nd) cannot uniquely identify the source of the metasomatic agent. Electronic supplementary material The online version of this article (doi:10.1007/s00410-009-0410-9) contains supplementary material, which is available to authorized users

Petrogenesis of high-MgO lavas of the lower mull plateau group, Scotland: Insights from melt inclusions

Published data on Palaeogene flood basalts of the lower Mull Plateau Group (Scotland) show that the most primitive lavas (MgO > 8 wt %) have the greatest extent of crustal assimilation, inconsistent with a simple coupled assimilation-fractional crystallization (AFC) model. We present elemental data on rehomogenized olivine-hosted melt inclusions from four high-MgO flows to investigate the nature of crustal assimilation and melt aggregation processes during the initial stages of flood basalt magmatism on Mull. Whole-rock compositions have been variably modified by hydrothermal alteration associated with the nearby Central Complexes. Nd isotope compositions, which should be insensitive to this alteration, are lower than typical mantle values (ΕNd + 2.4 to -5.7), indicating variable modification by crustal assimilation in all four samples. Melt inclusions are protected against alteration effects within their host olivine crystals, and provide more robust estimates of magmatic liquid compositions than whole-rocks, particularly for the alkali elements Na, K and Ba. The whole-rock samples show limited variations in Na. 2O (2.4-2.8 wt %) and K2O (0.23-0.29 wt %), despite a wide range in immobile elements (e.g. Zr 62-126 ppm). In contrast, the melt inclusions show far greater variability in Na2O (1.8-4.0 wt %) and K2O (0.02-0.35 wt %) and positive correlations between K and Na. Melt inclusions from different samples show systematic correlations between alkalis (K + Na) and incompatible element ratios (e.g. Zr/Y), indicating that the inclusions record magmatic values for the fluid-mobile elements. For the two most incompatible-element-enriched samples, the whole-rock analyses are similar to the melt inclusions except for lower Na and higher Ba that are related to alteration. Therefore, the crustal assimilation in these magmas must have taken place prior to growth of the olivines. For the two more depleted samples, the inclusions have less contaminated compositions than the whole-rocks, and show broad trends of increasing K/Ti with decreasing Fo% of the host olivine. For these samples, crustal assimilation must have taken place both during and after growth of the olivines and in an AFC style in which assimilation is linked to magmatic differentiation. Melt inclusions from single samples show limited variability in Zr/Y compared with K/Ti, indicating that aggregation of melts from different parts of the melt column must have occurred at deeper levels prior to growth of the olivines in the samples. Although the whole-rock compositional variations capture the broad details of crustal assimilation and melting histories for the Mull lavas despite the variable effects of hydrothermal alteration, the melt inclusion data more clearly resolve significant details of these magmatic processes. The extent of assimilation and differentiation is linked to the depth of magma stalling: primitive, contaminated magmas in the lower crust vs. evolved, uncontaminated magmas at sub-Moho depths

Two mantle domains and the timescales of fluid transfer beneath the Vanuatu arc

U-Th isotope disequilibria can provide constraints on the time elapsed since fluid addition to the mantle wedge beneath island arcs. The Vanuatu arc offers new insights into these processes because Pb isotopes there are not dominated by components from the subducting plate and so preserve the signatures of the mantle wedge. The Pb isotope data document the presence of separate Pacific and Indian mantle domains beneath the arc volcanoes. The Indian mantle was brought beneath the central part of the arc from the backarc by collision with the D'Entrecasteaux Ridge, resulting in a slowing of subduction there. The distinction in the mantle wedge composition is also uniquely apparent in U-Th isotope data, which define two subparallel arrays on the U-Th equiline diagram, one anchored to high U/Th Pacific matle and the other to lower U/Th Indian mantle. These data provide clrear evidence of the effects of variaible mantle composition on U-Th isotope disequilibria. We argue that such arrays faithfully record the time elapsed since fluid release from the subducting plate. The data indicate that this occurred ca. 16 Ka in the area of collision and slow subduction, but ca. 60 ka where the rate of subduction is substantially faster. This suggests a link between the rate of subduction and the time elapsed since fluid release

Flow-by-flow chemical stratigraphy and evolution of thirteen Serra Geral Group basalt flows from Vista Alegre, southernmost Brazil

The geochemical characterization of thirteen Serra Geral Group flows in the Vista Alegre region (RS-SC), southern Brazil, displays the homogeneous basaltic composition near 50 wt.% SiO2. Each of the five basal flows (Pitanga-type, high-Ti/Y ~600, TiO2 > 3 wt.%) and eight upper flows (Paranapanema-type, medium Ti/Y ~400, TiO2 > 2 wt.%) can be identified from their chemical composition; sets of flows have parallel variation in chemical composition. The flow-by-flowcorrelation in four sections shows the horizontal position of the flows in three profiles and an approximately 200-m downdrop of the Itapiranga block with respect to the Frederico Westphalen block. The world-class amethyst geode mineralization and the systematic presence of native copper in the basalts make the correlation of great geological and economic significance.<br>A caracterização geoquímica de treze derrames do Grupo Serra Geral na região de Vista Alegre (RS e SC), sul do Brasil, exibe uma composição basáltica homogênea próxima a 50% de SiO2. Os cinco derrames basais são classificados quimicamente como tipo Pitanga (alto Ti/Y ~600 e TiO2 > 3 em peso percentual), os demais oito derrames possuem médio Ti/Y ~400 com TiO2 ~2.5 em peso percentual, sendo classificados como magma tipo Paranapanema. Cada derrame pode ser identificado através de sua composição química e correlacionado, com variação paralela entre os perfis estudados. A correlação derrame a derrame nos quatro perfis demonstra uma posição horizontal em três perfis e um rejeito vertical de aproximadamente 200 m do bloco Itapiranga em relação ao bloco Frederico Westphalen. A presença de jazidas de ametista em geodos e a sistemática ocorrência de cobre nativo nos basaltos da região tornam a correlação de grande significado geológico e econômico

The Prinsen af Wales Bjerge formation lavas, East Greenland: The transition from tholeiitic to alkalic magmatism during Palaeogene continental break-up

We present elemental and isotopic (Sr-Nd-Pb-Hf-Os-He) data on primitive alkalic lavas from the Prinsen af Wales Bjeige, East Greenland. Stratigraphical, compositional and Ar-40-Ar-39 data indicate that this inland alkalic activity was contemporaneous with the upper parts of the main tholeiitic plateau basalts and also postdated them. The alkalic rocks show a marked crustal influence, indicating establishment of new magmatic plumbing systems distinct from the long-lived coastal systems that fed the relatively uncontaminated plateau basalts. The least contaminated lavas have high He-3/He-4 isotope ratios (R/R-A 12.4-18.5), sub-chondritic Os-187/(OSi)-O-88 (0.120-0.126), low epsilonNd(i) (similar to + 4) and epsilonHf(i) (similar to+ 6) that plot below the 'Nd-Hf mantle array', and trace element characteristics similar to HIMU ocean. island basalt. (OIB). The uncontaminated magma is inferred to have more radiogenic Pb-206/Pb-204 values (>19.2) than the plateau basalts and Icelandic basalts, and thus represents a possible 'enriched' component to explain the compositional variations within the plateau basalts. One model to explain these compositional features is preferential melting of recycled material within the plume upwelling beneath the thick lithospheric cap, with He-3 contributed from volatile-rich fluids from elsewhere in the Icelandic plume. The exact nature of the recycled component is not yet resolved, although Hf isotope compositions rule out any significant role for recycled pelagic sediment, and the low Os-187/Os-188 limits the participation of recycled basaltic material and argues instead for a contribution from the mantle section of the recycled slab