Neutral and cationic half-sandwich arene ruthenium, Cp*Rh and Cp*Ir oximato and oxime complexes: Synthesis, structural, DFT and biological studies

The reaction of [(p-cymene)RuCl2]2 and [Cp*MCl2]2 (M = Rh/Ir) with chelating ligand 2-pyridylcyanoxime {pyC(CN)NOH} leads to the formation of neutral oximato complexes having the general formula [(arene)M{pyC(CN)NO}Cl] {arene = p-cymene, M = Ru, (1); Cp*, M = Rh (2);Cp*, M = Ir (3)}. Whereas the reaction of 2-pyridyl phenyloxime {pyC(Ph)NOH} and 2-thiazolyl methyloxime {tzC(Me)NOH} with precursor compounds afforded the cationic oxide complexes bearing formula [(arene)M{pyC(ph)NOH}Cl]+ and [(arene)M{tzC(Me)NOH}Cl]+{arene = p-cymene M = Ru, (4), (7); Cp*, M = Rh (5), (8); Cp*, M = Ir (6), (9)}. The cationic complexes were isolated as their hexafluorophosphate salts. All these complexes were fully characterized by analytical, spectroscopic and X-ray diffraction studies. The molecular structures of the complexes revealed typical piano stool geometry around the metal center within which the ligand acts as a NNʹ donor chelating ligand. The Chemo-sensitivity activities of the complexes evaluated against HT-29 (human colorectal cancer), and MIAPaCa-2 (human pancreatic cancer) cell line showed that the iridium-based complexes are much more potent than the ruthenium and rhodium analogues. Theoretical studies were carried out to have a deeper understanding about the charge distribution pattern and the various electronic transitions occurring in the complexes

Low-Temperature Specific Heat of an Extreme-Type-II Superconductor at High Magnetic Fields

We present a detailed study of the quasiparticle contribution to the low-temperature specific heat of an extreme type-II superconductor at high magnetic fields. Within a T-matrix approximation for the self-energies in the mixed state of a homogeneous superconductor, the electronic specific heat is a linear function of temperature with a linear-$T$ coefficient $\gamma_s(H)$ being a nonlinear function of magnetic field $H$. In the range of magnetic fields H\agt (0.15-0.2)H_{c2} where our theory is applicable, the calculated $\gamma_s(H)$ closely resembles the experimental data for the borocarbide superconductor YNi$_2$B$_2$C.Comment: 7 pages, 2 figures, to appear in Physical Review

On Parity-Violating Three-Nucleon Interactions and the Predictive Power of Few-Nucleon EFT at Very Low Energies

We address the typical strengths of hadronic parity-violating three-nucleon interactions in "pion-less" Effective Field Theory in the nucleon-deuteron (iso-doublet) system. By analysing the superficial degree of divergence of loop diagrams, we conclude that no such interactions are needed at leading order. The only two linearly independent parity-violating three-nucleon structures with one derivative mix two-S and two-P-half waves with iso-spin transitions Delta I = 0 or 1. Due to their structure, they cannot absorb any divergence ostensibly appearing at next-to-leading order. This observation is based on the approximate realisation of Wigner's combined SU(4) spin-isospin symmetry in the two-nucleon system, even when effective-range corrections are included. Parity-violating three-nucleon interactions thus only appear beyond next-to-leading order. This guarantees renormalisability of the theory to that order without introducing new, unknown coupling constants and allows the direct extraction of parity-violating two-nucleon interactions from three-nucleon experiments.Comment: 20 pages LaTeX2e, including 9 figures as .eps file embedded with includegraphicx. Minor modifications and stylistic corrections. Version accepted for publication in Eur. Phys. J.

Parity-violating neutron spin rotation in hydrogen and deuterium

We calculate the (parity-violating) spin rotation angle of a polarized neutron beam through hydrogen and deuterium targets, using pionless effective field theory up to next-to-leading order. Our result is part of a program to obtain the five leading independent low-energy parameters that characterize hadronic parity-violation from few-body observables in one systematic and consistent framework. The two spin-rotation angles provide independent constraints on these parameters. Using naive dimensional analysis to estimate the typical size of the couplings, we expect the signal for standard target densities to be 10^-7 to 10^-6 rad/m for both hydrogen and deuterium targets. We find no indication that the nd observable is enhanced compared to the np one. All results are properly renormalized. An estimate of the numerical and systematic uncertainties of our calculations indicates excellent convergence. An appendix contains the relevant partial-wave projectors of the three-nucleon system.Comment: 44 pages, 17 figures; minor corrections; to be published in EPJ

Collective dynamics of internal states in a Bose gas

Theory for the Rabi and internal Josephson effects in an interacting Bose gas in the cold collision regime is presented. By using microscopic transport equation for the density matrix the problem is mapped onto a problem of precession of two coupled classical spins. In the absence of an external excitation field our results agree with the theory for the density induced frequency shifts in atomic clocks. In the presence of the external field, the internal Josephson effect takes place in a condensed Bose gas as well as in a non-condensed gas. The crossover from Rabi oscillations to the Josephson oscillations as a function of interaction strength is studied in detail.Comment: 18 pages, 2 figure

Breaking CPT by mixed non-commutativity

The mixed component of the non-commutative parameter \theta_{\mu M}, where \mu = 0,1,2,3 and M is an extra dimensional index may violate four-dimensional CPT invariance. We calculate one and two-loop induced couplings of \theta_{\mu 5} with the four-dimensional axial vector current and with the CPT odd dim=6 operators starting from five-dimensional Yukawa and U(1) theories. The resulting bounds from clock comparison experiments place a stringent constraint on \theta_{\mu 5}, |\theta_{\mu 5}|^{-1/2} > 5\times 10^{11} GeV. The orbifold projection and/or localization of fermions on a 3-brane lead to CPT-conserving physics, in which case the constraints on \theta{\mu 5} are softened.Comment: 4 pages, latex, 1 figur

Tomato: a crop species amenable to improvement by cellular and molecular methods

Tomato is a crop plant with a relatively small DNA content per haploid genome and a well developed genetics. Plant regeneration from explants and protoplasts is feasable which led to the development of efficient transformation procedures. In view of the current data, the isolation of useful mutants at the cellular level probably will be of limited value in the genetic improvement of tomato. Protoplast fusion may lead to novel combinations of organelle and nuclear DNA (cybrids), whereas this technique also provides a means of introducing genetic information from alien species into tomato. Important developments have come from molecular approaches. Following the construction of an RFLP map, these RFLP markers can be used in tomato to tag quantitative traits bred in from related species. Both RFLP's and transposons are in the process of being used to clone desired genes for which no gene products are known. Cloned genes can be introduced and potentially improve specific properties of tomato especially those controlled by single genes. Recent results suggest that, in principle, phenotypic mutants can be created for cloned and characterized genes and will prove their value in further improving the cultivated tomato.