20,357 research outputs found

    The influence of the extent of excluded volume interactions on the linear viscoelastic properties of dilute polymer solutions

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    The Rouse model has recently been modified to take into account the excluded volume interactions that exist between various parts of a polymer chain by incorporating a narrow Gaussian repulsive potential between pairs of beads on the Rouse chain (cond-mat/0002448). The narrow Gaussian potential is characterized by two parameters: z* - which accounts for the strength of the interaction, and d* - which accounts for the extent of the interaction. In the limit of d* going to zero, the narrow Gaussian potential tends to the more commonly used delta-function repulsive potential. The influence of the parameter d*, in the limit of infinite chain length, on equilibrium and linear viscoelastic properties, and on universal ratios involving these properties, is examined here. A renormalization group calculation of the end-to-end vector suggests that the value chosen for the variable d* will not affect critical exponents, or universal ratios. A similar trend is also observed for results obtained with an approximate solution, which is based on the assumption that the non-equilibrium configurational distribution function is Gaussian.Comment: 23 pages, 6 figures, LaTe

    Spontaneous Recovery of Superhydrophobicity on Nanotextured Surfaces

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    Rough or textured hydrophobic surfaces are dubbed superhydrophobic due to their numerous desirable properties, such as water repellency and interfacial slip. Superhydrophobicity stems from an aversion for water to wet the surface texture, so that a water droplet in the superhydrophobic "Cassie state", contacts only the tips of the rough hydrophobic surface. However, superhydrophobicity is remarkably fragile, and can break down due to the wetting of the surface texture to yield the "Wenzel state" under various conditions, such as elevated pressures or droplet impact. Moreover, due to large energetic barriers that impede the reverse (dewetting) transition, this breakdown in superhydrophobicity is widely believed to be irreversible. Using molecular simulations in conjunction with enhanced sampling techniques, here we show that on surfaces with nanoscale texture, water density fluctuations can lead to a reduction in the free energetic barriers to dewetting by circumventing the classical dewetting pathways. In particular, the fluctuation-mediated dewetting pathway involves a number of transitions between distinct dewetted morphologies, with each transition lowering the resistance to dewetting. Importantly, an understanding of the mechanistic pathways to dewetting and their dependence on pressure, allows us to augment the surface texture design, so that the barriers to dewetting are eliminated altogether and the Wenzel state becomes unstable at ambient conditions. Such robust surfaces, which defy classical expectations and can spontaneously recover their superhydrophobicity, could have widespread importance, from underwater operation to phase change heat transfer applications

    Kaon Condensation in Neutron Star Matter with Hyperons

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    Based on the Kaplan-Nelson Lagrangian, we investigate kaon condensation in dense neutron star matter allowing for the explicit presence of hyperons. Using various models we find that the condensate threshold is sensitive to the behavior of the scalar density; the more rapidly it increases with baryon density, the lower is the threshold for condensation. The presence of hyperons, particularly the Σ\Sigma^-, shifts the threshold for KK^- condensation to a higher density. In the mean field approach, with hyperons, the condensate amplitude grows sufficiently rapidly that the nucleon effective mass vanishes at a finite density and a satisfactory treatment of the thermodynamics cannot be achieved. Thus, calculations of kaon-baryon interactions beyond the mean field level appear to be necessary.Comment: 13 pages, latex, 3 figures by fax/mail from [email protected]
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