1,490 research outputs found
Next generation keyboards: The importance of cognitive compatibility
The computer keyboard of today is essentially the same as it has been for many years. Few advances have been made in keyboard design even though computer systems in general have made remarkable progress in improvements. This paper discusses the future of keyboards, their competition and compatibility with voice input systems, and possible special-application intelligent keyboards for controlling complex systems
The effect of a stellar magnetic variation on the jet velocity
Stellar jets are normally constituted by chains of knots with some
periodicity in their spatial distribution, corresponding to a variability of
order of several years in the ejection from the protostar/disk system. A widely
accepted theory for the presence of knots is related to the generation of
internal working surfaces due to variations in the jet ejection velocity. In
this paper we study the effect of variations in the inner disk-wind radius on
the jet ejection velocity. We show that a small variation in the inner
disk-wind radius produce a variation in the jet velocity large enough to
generate the observed knots. We also show that the variation in the inner
radius may be related to a variation of the stellar magnetic field.Comment: 5 pages, 3 figures, accepted for publication in Ap
Determination of a Wave Function Functional
In this paper we propose the idea of expanding the space of variations in
standard variational calculations for the energy by considering the wave
function to be a functional of a set of functions , rather than a function. In this manner a greater flexibility to
the structure of the wave function is achieved. A constrained search in a
subspace over all functions such that the wave function functional
satisfies a constraint such as normalization or the Fermi-Coulomb
hole charge sum rule, or the requirement that it lead to a physical observable
such as the density, diamagnetic susceptibility, etc. is then performed. A
rigorous upper bound to the energy is subsequently obtained by variational
minimization with respect to the parameters in the approximate wave function
functional. Hence, the terminology, the constrained-search variational method.
The \emph{rigorous} construction of such a constrained-search--variational wave
function functional is demonstrated by example of the ground state of the
Helium atom.Comment: 10 pages, 2 figures, changes made, references adde
Stereochemical and electronic interaction studies of 4′-substituted 2-(phenylselanyl)-2-(ethylsulfinyl)-acetophenones
Analysis of OPM potentials for multiplet states of 3d transition metal atoms
We apply the optimized effective potential method (OPM) to the multiplet
energies of the 3d transition metal atoms, where the orbital dependence of
the energy functional with respect to orbital wave function is the
single-configuration HF form. We find that the calculated OPM exchange
potential can be represented by the following two forms. Firstly, the
difference between OPM exchange potentials of the multiplet states can be
approximated by the linear combination of the potentials derived from the
Slater integrals and for the average
energy of the configuration. Secondly, the OPM exchange potential can be
expressed as the linear combination of the OPM exchange potentials of the
single determinants.Comment: 15 pages, 6 figures, to be published in J. Phys.
Electrochemical behaviour of gamma hydroxybutyric acid at a platinum electrode in acidic medium
The electrooxidation of Gamma Hydroxybutyric Acid (GHB) on a polycrystalline platinum electrode is studied by cyclic voltammetry in acidic medium. Two oxidation peaks, A and B, are obtained in the positive scan within the potential range of the double layer region and of the platinum oxide region, respectively. In the negative going potential sweep an inverted oxidation peak with an onset partially overlapping with the tail of the cathodic peak for the reduction of the platinum oxide formed during the anodic scan is obtained (peak C). This inverted peak can be observed at a potential close to +0.2 V (vs Ag/AgCl at pH 2) and separated 0.4 and 0.8 V from the two other oxidation peaks obtained during the anodic scan and in such conditions that the surface is particularly activated to favour this electrochemical process. The response obtained in the electronic current for the different peaks when GHB concentration and scan rate were changed to allows inferring that these are the result of a potential dependent mechanism. The behaviour observed is according with the oxidation of the alcohol group to the corresponding aldehyde and carboxylic acid (succinic acid) as main products
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