Laser-cooling-assisted mass spectrometry

Mass spectrometry is used in a wide range of scientific disciplines including proteomics, pharmaceutics, forensics, and fundamental physics and chemistry. Given this ubiquity, there is a worldwide effort to improve the efficiency and resolution of mass spectrometers. However, the performance of all techniques is ultimately limited by the initial phase-space distribution of the molecules being analyzed. Here, we dramatically reduce the width of this initial phase-space distribution by sympathetically cooling the input molecules with laser-cooled, co-trapped atomic ions, improving both the mass resolution and detection efficiency of a time-of-flight mass spectrometer by over an order of magnitude. Detailed molecular dynamics simulations verify the technique and aid with evaluating its effectiveness. Our technique appears to be applicable to other types of mass spectrometers.Comment: 6 pages, 4 figure

Recent Efforts Enabling Martian Rotorcraft Missions

The Mars Helicopter (MH), launching as a part of the Mars 2020 mission, will begin a new era of planetary exploration. Mars research has historically been conducted through landers, rovers, and satellites. As both government and private industries prepare for human exploration of the Martian surface within two decades, more in depth knowledge of what awaits on the surface is critical. Planetary aerial vehicles increase the range of terrain that can be examined, compared to traditional landers and rovers and have more near surface capability than orbiters. The Jet Propulsion Laboratory (JPL) and NASA Ames are currently exploring possibilities for a Mars Science Helicopter (MSH), a second-generation Mars rotorcraft with the capability of conducting science investigations independently of a lander or rover (although this type of vehicle could also be used assist rovers or landers in future missions). Preliminary designs of coaxial-helicopter and hexacopter configurations have targeted the minimum capability of lifting a payload in the range of two to three kilograms with an overall vehicle mass of approximately twenty kilograms. These MSH designs sizes are constrained by the aeroshell dimensions(currently focused on employing legacy Pathfinder or MSL aeroshells), rather than vehicle structural or aeroperformance limitations. Feasibility of the MSH configurations has been investigated considering packaging/deployment, rotor aerodynamics, and structural analysis studies. Initial findings suggest not only the overall feasibility of MSH configurations but also indicate that improvements up to 11.1 times increase in range or 1.3 times increase in hover time might be achievable, even with an additional science payload, compared to the current design of the MH

Sensitivity of the South Asian monsoon to elevated and non-elevated heating

Elevated heating by the Tibetan Plateau was long thought to drive the South Asian summer monsoon, but recent work showed this monsoon was largely unaffected by removal of the plateau in a climate model, provided the narrow orography of adjacent mountain ranges was preserved. There is debate about whether those mountain ranges generate a strong monsoon by insulating the thermal maximum from cold and dry extratropical air or by providing a source of elevated heating. Here we show that the strength of the monsoon in a climate model is more sensitive to changes in surface heat fluxes from non-elevated parts of India than it is to changes in heat fluxes from adjacent elevated terrain. This result is consistent with the hypothesis that orography creates a strong monsoon by serving as a thermal insulator, and suggests that monsoons respond most strongly to heat sources coincident with the thermal maximum.Engineering and Applied Science

Molecular ion trap-depletion spectroscopy of BaCl+^+

We demonstrate a simple technique for molecular ion spectroscopy. BaCl$^+$ molecular ions are trapped in a linear Paul trap in the presence of a room-temperature He buffer gas and photodissociated by driving an electronic transition from the ground X$^1\Sigma^+$ state to the repulsive wall of the A$^1\Pi$ state. The photodissociation spectrum is recorded by monitoring the induced trap loss of BaCl$^+$ ions as a function of excitation wavelength. Accurate molecular potentials and spectroscopic constants are determined. Comparison of the theoretical photodissociation cross-sections with the measurement shows excellent agreement. This study represents the first spectroscopic data for BaCl$^+$ and an important step towards the production of ultracold ground-state molecular ions.Comment: 5 pages, 5 figure

Generalized Log-Normal Chain-Ladder

We propose an asymptotic theory for distribution forecasting from the log normal chain-ladder model. The theory overcomes the difficulty of convoluting log normal variables and takes estimation error into account. The results differ from that of the over-dispersed Poisson model and from the chain-ladder based bootstrap. We embed the log normal chain-ladder model in a class of infinitely divisible distributions called the generalized log normal chain-ladder model. The asymptotic theory uses small $\sigma$ asymptotics where the dimension of the reserving triangle is kept fixed while the standard deviation is assumed to decrease. The resulting asymptotic forecast distributions follow t distributions. The theory is supported by simulations and an empirical application

The Causal Boundary of spacetimes revisited

We present a new development of the causal boundary of spacetimes, originally introduced by Geroch, Kronheimer and Penrose. Given a strongly causal spacetime (or, more generally, a chronological set), we reconsider the GKP ideas to construct a family of completions with a chronology and topology extending the original ones. Many of these completions present undesirable features, like those appeared in previous approaches by other authors. However, we show that all these deficiencies are due to the attachment of an ``excessively big'' boundary. In fact, a notion of ``completion with minimal boundary'' is then introduced in our family such that, when we restrict to these minimal completions, which always exist, all previous objections disappear. The optimal character of our construction is illustrated by a number of satisfactory properties and examples.Comment: 37 pages, 10 figures; Definition 6.1 slightly modified; multiple minor changes; one figure added and another replace