Mechanically assisted electrochemical degradation of alumina-TiC composites

Alumina-TiC composite material is a tough ceramic composite with excellent hardness, wear resistance and oxidation resistance in dry and high-temperature conditions. In aqueous conditions, however, it is likely to be electrochemically active facilitating charge transfer processes due to the conductive nature of TiC. For application as an orthopedic biomaterial, it is crucial to assess the electrochemical behavior of this composite, especially under a combined mechanical and electrochemical environment. In this study, we examined the mechanically assisted electrochemical performance of alumina-TiC composite in an aqueous environment. The spontaneous electrochemical response to brushing abrasion was measured. Changes in the magnitude of electrochemical current with abrasion test conditions and possible causal relationship to the alteration in surface morphology were examined. Results showed that the alumina matrix underwent abrasive wear with evidence of microploughing and grain boundary damage. Chemical analysis revealed TiO2 formation in the abraded region, indicating oxidation of the conductive TiC domain. Furthermore, wear debris from alumina abrasion appeared to affect reaction kinetics at the composite-electrolyte interface. From this work, we established that the composite undergoes abrasion assisted electrochemical degradation even in gentle abrasive conditions and the severity of degradation is related to temperature and conditions of test environment

Surface temperature measurement of a copper anode submitted to a non-stationary electric arc in air

This work concerns the assessment of the surface temperature of copper anodes submitted to an electric arc in a non-stationary regime in air at atmospheric pressure. An infrared camera is used to measure the decrease of the surface temperature just after a very fast controlled arc extinction. Results are presented for different mean values of the arc current intensity (30, 70 and 130 A) with an electric arc duration in the range of 2–5 ms. The temperature decrease after the arc extinction allows an assessment of the surface temperature just at the moment of the arc switching off. In the present experimental conditions the mean temperatures reached for copper anodes are in the range of 750–1200 °C according to the arc current intensity values. Comparison between experimental results and a numerical modeling of the electrode heating allowed one to assess the surface power balance. The values for the volt equivalent are found about 12 V and the values for the surface power density are found to be near 2 × 109 W/m2

MIP-3α expression in macrophages is NOD dependent

Background: The first identified susceptibility gene for Crohn's disease, NOD2, acts as a sensor for the bacterial-wall peptidoglycan fragment muramyl dipeptide (MDP) and activates the transcription factor nuclear factor-κB (NF-κB). Upon NF-κB activation, intestinal macrophages (IMACs) induce expression of macrophage inflammatory protein (MIP)-3α to attract memory T lymphocytes. We therefore investigated the influence of NOD2 ligation of IMAC differentiation and functional MIP-3α induction. Methods: Human embryonal kidney HEK293 cells were transfected with NOD2 wild-type (NOD2(WT)) and the NOD2 SNP13 variant (NOD2(L1007fsinsC)) and stimulated with MDP. Recruitment of CD45R0(+) and Th17 cells was determined by immunohistochemistry. Results: Endogenous NOD2 stimulation was followed by a dose-dependent increase in MIP-3α secretion in MONO-MAC-6 (MM6) cells. MIP-3α mRNA was also significantly (* p < 0.05) induced in HEK293 transfected with NOD2(WT) via MDP ligation. In vivo cell-cell contacts between IMACs and CD45R0(+) memory T cells as well as recruitment of Th17 cells in patients of NOD2 variants were unchanged as compared to wild-type patients. Conclusion: Our data demonstrate a dose-dependent increase in MIP-3α secretion in the human myeloid cell line MM6 upon MDP. However, MIP-3α-driven recruitment of Th17 cells or CD45R0(+) memory T lymphocytes is not affected in patients carrying heterozygous NOD2 variants

Machinability of ZTA-TiC Ceramics by Electrical Discharge Drilling

AbstractElectric discharge machining of ceramics becomes principally feasible if the ceramic material has a sufficiently high electric conductivity. This can be achieved by adding transition metal carbides, borides or nitrides such as titanium carbide. In case of electric discharge drilling the small electrode dimensions lead to higher current densities compared to die sinking. In order to avoid bursting of the ceramics by thermal shock machining parameters have to be well adjusted and the material should have a high thermal conductivity. A parameter study was carried out to observe the removal behavior depending on machine parameters such as discharge energy, pulse form and flushing conditions

PROGRESS IN SATELLITE TRACKING CRANES

We review the history of tracking cranes with satellite telemetry and identify some of the difficulties in designing satellite transmitters and harnesses for cranes. Miniaturization of these transmitters and a plethora of harnessing experiments since 1989 allow us to recommend limited application of this technology to all species of cranes. We are still uncertain, however, if cranes harnessed with satellite telemetry devices are able to reproduce after migration. Because of this uncertainty, we urge caution in the use of this technology, especially with breeding adults in severely endangered popUlations. This manuscript also describes continuing research needs