Anomalous temperature dependence of the band-gap in Black Phosphorus

Black Phosphorus (BP) has gained renewed attention due to its singular anisotropic electronic and optical properties that might be exploited for a wide range of technological applications. In this respect, the thermal properties are particularly important both to predict its room temperature operation and to determine its thermoelectric potential. From this point of view, one of the most spectacular and poorly understood phenomena is, indeed, the BP temperature-induced band-gap opening: when temperature is increased the fundamental band-gap increases instead of decreasing. This anomalous thermal dependence has also been observed, recently, in its monolayer counterpart. In this work, based on \textit{ab-initio} calculations, we present an explanation for this long known, and yet not fully explained, effect. We show that it arises from a combination of harmonic and lattice thermal expansion contributions, which are, in fact, highly interwined. We clearly narrow down the mechanisms that cause this gap opening by identifying the peculiar atomic vibrations that drive the anomaly. The final picture we give explains both the BP anomalous band-gap opening and the frequency increase with increasing volume (tension effect).Comment: Published in Nano Letter

Quasiparticle Electronic structure of Copper in the GW approximation

We show that the results of photoemission and inverse photoemission experiments on bulk copper can be quantitatively described within band-structure theory, with no evidence of effects beyond the single-quasiparticle approximation. The well known discrepancies between the experimental bandstructure and the Kohn-Sham eigenvalues of Density Functional Theory are almost completely corrected by self-energy effects. Exchange-correlation contributions to the self-energy arising from 3s and 3p core levels are shown to be crucial.Comment: 4 pages, 2 figures embedded in the text. 3 footnotes modified and 1 reference added. Small modifications also in the text. Accepted for publication in PR

The mechanical resistance of saturated stones

This paper aims at investigating the effect of the presence of water on the mechanical resistance of stones. The presence of water, connected to the intrinsic properties of the stone (mineralogical composition, fabric, texture, etc.) and to the conditions of use (anchoring systems, climatic parameters, etc ), is the main cause of stone decay. However, the presence of water alone inside stone could cause a decrease in mechanical resistance . The obtained data could in fact be useful to correct the safety coefficient and should be taken into account in the planning of structural stonework. Moreover, useful suggestions can be drawn for the in situ monitoring, taking into account that non destructive tests, together with conventional mechanical methods, are influenced by the presence of water in stones and should be corrected. Three kinds of stones, which have historically been used for structural purposes, have been studied: Pietra di Luserna (gneiss, Piedmont, Italy), Pietra Verde Argento (gneiss, Piedmont, Italy) and Pietra di Courtil (mica-schist, Aosta Valley, Italy). The flexural strength, rupture energy, open porosity and ultrasonic pulse velocity (UPV) have been determined on specimens in dried and saturated conditions at different accelerated ageing steps. As far as the UPV test is concerned, its results are well correlated with the flexural strength values but, without other parameters, it cannot give information on whether the specimen is filled with water, therefore suitable procedures to correct the UPV value obtained in situ are suggested. Destructive methods, and in particular the flexural strength method, instead, give lower resistance values for saturated specimens than dried ones, thus confirming the weakness of the stone due to the water insid

Efficacy of Two Common Methods of Application of Residual Insecticide for Controlling the Asian Tiger Mosquito, Aedes albopictus (Skuse), in Urban Areas

After its first introduction in the 1980's the Asian tiger mosquito, Aedes albopictus (Skuse), has spread throughout Southern Europe. Ae. albopictus is considered an epidemiologically important vector for the transmission of many viral pathogens such as the yellow fever virus, dengue fever and Chikungunya fever, as well as several filarial nematodes such as Dirofilaria immitis or D. repens. It is therefore crucial to develop measures to reduce the risks of disease transmission by controlling the vector populations. The aim of the study was to compare the efficacy of two application techniques (mist vs. stretcher sprayer) and two insecticides (Etox based on the nonester pyrethroid Etofenprox vs. Microsin based on the pyrethroid type II Cypermetrin) in controlling adult tiger mosquito populations in highly populated areas. To test the effect of the two treatments pre- and post-treatment human landing rate counts were conducted for two years. After one day from the treatment we observed a 100% population decrease in mosquito abundance with both application methods and both insecticides. However, seven and 14 days after the application the stretcher sprayer showed larger population reductions than the mist sprayer. No effect of insecticide type after one day and 14 days was found, while Etox caused slightly higher population reduction than Microsin after seven days. Emergency measures to locally reduce the vector populations should adopt adulticide treatments using stretcher sprayers. However, more research is still needed to evaluate the potential negative effects of adulticide applications on non-target organisms

A Soluble Phase Field Model

The kinetics of an initially undercooled solid-liquid melt is studied by means of a generalized Phase Field model, which describes the dynamics of an ordering non-conserved field phi (e.g. solid-liquid order parameter) coupled to a conserved field (e.g. thermal field). After obtaining the rules governing the evolution process, by means of analytical arguments, we present a discussion of the asymptotic time-dependent solutions. The full solutions of the exact self-consistent equations for the model are also obtained and compared with computer simulation results. In addition, in order to check the validity of the present model we confronted its predictions against those of the standard Phase field model and found reasonable agreement. Interestingly, we find that the system relaxes towards a mixed phase, depending on the average value of the conserved field, i.e. on the initial condition. Such a phase is characterized by large fluctuations of the phi field.Comment: 13 pages, 8 figures, RevTeX 3.1, submitted to Physical Review

Peningkatan Motivasi Belajar Siswa melalui Penerapan Pendekatan Realistic Mathematics Education (Rme)

The purpose of this study is to describe the learning process with the approach of Realistic Mathematics Education (RME), which can increase the motivation to learn mathematics student in materials Systems of Linear Equations in Two Variables on VIII-C students of SMP IT Ash-Shadhili. This research was a Classroom Action Research consisting of four stages, namely planning, action, observation and reflection. In the RME approach, teachers initiate learning by giving realistic problems. Students are asked to understand the problem and then solve it by discussing based on their knowledge and experience on teacher guidance. Students are then asked to discuss and compare answers through presentation activities during class discussions. Teachers motivate students to ask questions, give feedback or feedback. At the end of the learning the students are given the opportunity to deduce the material they have learned. The results showed that the RME approach learning can increase student motivation. This was proven by the percentage of observation results of students' learning motivation classically reached 83.33%, while the average percentage of observation results every meeting of two observers reached 80.37% in either category.Tujuan penelitian ini adalah untuk mendeskripsikan proses pembelajaran dengan pendekatan Realistic Mathematics Education (RME) yang dapat meningkatkan motivasi belajar matematika siswa pada materi Sistem Persamaan Linier Dua Variabel di kelas VIII-C SMP IT Asy-Syadzili. Penelitian ini merupakan Penelitian Tindakan Kelas yang terdiri atas empat tahapan, yaitu perencanaan, tindakan, pengamatan dan refleksi. Pada pendekatan RME, guru mengawali pembelajaran dengan memberikan masalah realistik. Siswa diminta untuk memahami masalah kemudian menyelesaikannya dengan cara berdiskusi berdasarkan pengetahuan dan pengalaman mereka atas bimbingan guru. Selanjutnya siswa diminta untuk mendiskusikan dan membandingkan jawaban melalui kegiatan presentasi pada saat diskusi kelas. Guru memotivasi siswa untuk berani bertanya, memberikan masukan atau tanggapan. Diakhir pembelajaran siswa diberi kesempatan untuk menyimpulkan materi yang telah dipelajari. Hasil penelitian menunjukkan bahwa pembelajaran dengan pendekatan RME dapat meningkatkan motivasi belajar siswa. Hal ini dibuktikan dengan persentase hasil observasi motivasi belajar siswa secara klasikal mencapai 83,33%, sedangkan rata-rata persentase hasil observasi setiap pertemuan dari dua orang observer mencapai 80,37% pada kategori baik

A methodology for near net shape process feasibility assessment

Manufacturing engineers are frequently asked to select the best process for creating components but often the judgement is qualitative rather than quantitative. This paper presents a methodology (DCFA – Differential Cost and Feasibility Analysis) for assessing the technological and economic feasibility of using Near Net Shape (NNS) processes for the manufacturing of specific components. The methodology examines changes in raw material usage and finish processes (e.g. machining processes) that would result from adaption of a new manufacturing process. To illustrate the method, a case study that assesses the feasibility of using centrifugal casting for the production of valve cages is detailed. The case study concludes that the application of this process to the current manufacturing lines could result in significant cost reductions (particularly in machining time and reduction of scrappage). The feasibility methodology is generic and can potentially be used to investigate the application of a broad range of NNS processes in general manufacturing applications. Further, the developed cost models also allow the economic impact of a new process to be assessed, even at the early stages of product design

Non-equilibrium fluctuations in a driven stochastic Lorentz gas

We study the stationary state of a one-dimensional kinetic model where a probe particle is driven by an external field E and collides, elastically or inelastically, with a bath of particles at temperature T. We focus on the stationary distribution of the velocity of the particle, and of two estimates of the total entropy production \Delta s_tot. One is the entropy production of the medium \Delta s_m, which is equal to the energy exchanged with the scatterers, divided by a parameter \theta, coinciding with the particle temperature at E=0. The other is the work W done by the external field, again rescaled by \theta. At small E, a good collapse of the two distributions is found: in this case the two quantities also verify the Fluctuation Relation (FR), indicating that both are good approximations of \Delta s_tot. Differently, for large values of E, the fluctuations of W violate the FR, while \Delta s_m still verifies it.Comment: 6 pages, 4 figure

Pressure in an exactly solvable model of active fluid

We consider the pressure in the steady-state regime of three stochastic models characterized by self-propulsion and persistent motion and widely employed to describe the behavior of active particles, namely the Active Brownian particle (ABP) model, the Gaussian colored noise (GCN) model and the unified colored noise model (UCNA). Whereas in the limit of short but finite persistence time the pressure in the UCNA model can be obtained by different methods which have an analog in equilibrium systems, in the remaining two models only the virial route is, in general, possible. According to this method, notwithstanding each model obeys its own specific microscopic law of evolution, the pressure displays a certain universal behavior. For generic interparticle and confining potentials, we derive a formula which establishes a correspondence between the GCN and the UCNA pressures. In order to provide explicit formulas and examples, we specialize the discussion to the case of an assembly of elastic dumbbells confined to a parabolic well. By employing the UCNA we find that, for this model, the pressure determined by the thermodynamic method coincides with the pressures obtained by the virial and mechanical methods. The three methods when applied to the GCN give a pressure identical to that obtained via the UCNA. Finally, we find that the ABP virial pressure exactly agrees with the UCNA and GCN result.Comment: 12 pages, 1 figure Submitted for publication 23rd of January 2017 The introduction has been modifie