Non-chaotic dynamics in general-relativistic and scalar-tensor cosmology

In the context of scalar-tensor models of dark energy and inflation, the dynamics of vacuum scalar-tensor cosmology are analysed without specifying the coupling function or the scalar field potential. A conformal transformation to the Einstein frame is used and the dynamics of general relativity with a minimally coupled scalar field are derived for a generic potential. It is shown that the dynamics are non-chaotic, thus settling an existing debate.Comment: 20 pages, LaTeX, to appear in Class. Quantum Gra

Identificação de minerais do grupo das zeólitas por espectroscopia de reflectância, para aplicação como remineralizadores de solo.

A utilização de zeólitas para melhorar a qualidade do solo destinado à agricultura ganha espaço em todo o mundo. A elevada capacidade de troca catiônica das zeólitas favorece a conservação de nutrientes no solo e, a alta capacidade de retenção de água em seus retículos cristalinos faz destes minerais excelentes condicionadores de solo. A ausência de depósitos de zeólitas em exploração no Brasil torna os basaltos da Formação Serra Geral da Bacia do Paraná um alvo com grande potencial para a prospecção por zeólitas naturais. Pesquisas da CPRM destacam a significativa presença de zeólitas especialmente no contato entre os derrames inferiores da Formação Serra Geral e os arenitos eólicos da Formação Botucatu no Rio Grande do Sul. A espectroscopia de reflectância é uma ferramenta capaz de contribuir para a identificação de zeólitas em campo ou laboratório, utilizando-se de análises rápidas e de baixo custo. O conhecimento prévio do comportamento espectral das zeólitas é de grande utilidade na prospecção de alvos potenciais na Formação Serra Geral (pilhas de lobos e brechas de topo de derrames basálticos). Nestas ambiências foram reconhecidas macroscopicamente heulandita, escolecita, estilbita, laumontita e mordenita. O presente trabalho apresenta os resultados de leituras em amostras representativas das paragêneses que caracterizam os diferentes blocos determinados pelo Projeto Agrominerais Bacia do Paraná no Rio Grande do Sul-CPRM, com uso do espectrorradiômetro FieldSpec 3 Hi-Res© - ASD, de resolução espectral entre 0,35 e 2,5 μm. Foram identificadas curvas espectrais referentes à estilbita, heulandita, laumontita, mordenita e possivelmente analcima e clinoptilolita, localmente associadas à calcita. Por meio de assinaturas espectrais poderão ser construídos padrões para as zeólitas, para classificação de imagens de satélite, devendo-se considerar a relação entre a dimensão dos alvos e as resoluções espaciais e espectrais dos sensores orbitais e aeroportados disponíveis para o imageamento da área de pesquisa

The VZV/IE63-specific T cell response prevents herpes zoster in fingolimod-treated patients.

OBJECTIVE: To assess longitudinally the antiviral immune response of T cells from patients with multiple sclerosis (MS) treated with fingolimod (FTY) vs other disease-modifying treatments (DMTs). METHODS: We assessed cellular immune responses specific to influenza virus (FLU), JC virus (JCV), and varicella-zoster virus (VZV) using quantification of interferon-γ secretion by enzyme-linked immunospot in patients with MS on FTY (n = 31), including 2 with herpes zoster (HZ), natalizumab (n = 11), and other DMTs (n = 11). We used viral lysates for FLU and VZV and a pool of peptides for FLU, JCV (VP-1), and VZV (IE63). RESULTS: Besides an expected drop of T cells, we found that, proportionally to the number of CD3(+) T cells, only FTY-treated patients with MS exhibited an increased VZV/IE63-specific T cell response peaking 6 months into treatment, a response that returned to baseline after 12 and 24 months. Two FTY-treated patients developed an HZ 6 months into treatment, coinciding with an absent VZV/IE63-specific T cell response. However, cellular immune responses specific to VZV lysate, JCV, and FLU (lysate and pool of peptide epitopes) were similar between all 3 categories (FTY, natalizumab, and other DMTs) of study patients. CONCLUSIONS: FTY-treated patients with MS exhibit an increased VZV/IE63-specific cellular immune response after 6 months of treatment. FTY-treated patients who develop an HZ are not able to mount such a response, suggesting that a T cell response directed against this viral protein may be key in preventing the occurrence of HZ

Gauge-Invariant Initial Conditions and Early Time Perturbations in Quintessence Universes

We present a systematic treatment of the initial conditions and evolution of cosmological perturbations in a universe containing photons, baryons, neutrinos, cold dark matter, and a scalar quintessence field. By formulating the evolution in terms of a differential equation involving a matrix acting on a vector comprised of the perturbation variables, we can use the familiar language of eigenvalues and eigenvectors. As the largest eigenvalue of the evolution matrix is fourfold degenerate, it follows that there are four dominant modes with non-diverging gravitational potential at early times, corresponding to adiabatic, cold dark matter isocurvature, baryon isocurvature and neutrino isocurvature perturbations. We conclude that quintessence does not lead to an additional independent mode.Comment: Replaced with published version, 12 pages, 2 figure

A Geant4 simulation code for simulating optical photons in SPECT scintillation detectors

Geant4 is an object oriented toolkit created for the simulation of High-Energy Physics detectors. Geant4 allows an accurate modeling of radiation sources and detector devices, with easy configuration and friendly interface and at the same time with great accuracy in the simulation of physical processes. While most Monte Carlo codes do not allow the simulation of the transport and boundary characteristics for optical photons transport generated by scintillating crystal, Geant4 allows the simulation of the optical photons. In this paper we present an application of the Geant4 program for simulating optical photons in SPECT cameras. We aim to study the light transport within scintillators, photomultiplier tubes and coupling devices. To this end, we simulated a detector based on a scintillator, coupled to a photomultiplier tube through a glass window. We compared simulated results with experimental data and theoretical models, in order to verify the good matching with our simulations. We simulated a pencil beam of 140 keV photons impinging the crystal at different locations. For each condition, we calculated the value of the Pulse Height Centroid and the spread of the charge distribution, as read out by the anode array of the photomultiplier. Finally, the spatial and the energy resolutions of the camera have been estimated by simulated data. In all cases, we found that simulations agree very well with experimental data

Photochemistry of Furyl- and Thienyldiazomethanes: Spectroscopic Characterization of Triplet 3-Thienylcarbene

Photolysis (λ \u3e 543 nm) of 3-thienyldiazomethane (1), matrix isolated in Ar or N2 at 10 K, yields triplet 3-thienylcarbene (13) and α-thial-methylenecyclopropene (9). Carbene 13 was characterized by IR, UV/vis, and EPR spectroscopy. The conformational isomers of 3-thienylcarbene (s-E and s-Z) exhibit an unusually large difference in zero-field splitting parameters in the triplet EPR spectrum (|D/hc| = 0.508 cm–1, |E/hc| = 0.0554 cm–1; |D/hc| = 0.579 cm–1, |E/hc| = 0.0315 cm–1). Natural Bond Orbital (NBO) calculations reveal substantially differing spin densities in the 3-thienyl ring at the positions adjacent to the carbene center, which is one factor contributing to the large difference in D values. NBO calculations also reveal a stabilizing interaction between the sp orbital of the carbene carbon in the s-Z rotamer of 13 and the antibonding σ orbital between sulfur and the neighboring carbon—an interaction that is not observed in the s-E rotamer of 13. In contrast to the EPR spectra, the electronic absorption spectra of the rotamers of triplet 3-thienylcarbene (13) are indistinguishable under our experimental conditions. The carbene exhibits a weak electronic absorption in the visible spectrum (λmax = 467 nm) that is characteristic of triplet arylcarbenes. Although studies of 2-thienyldiazomethane (2), 3-furyldiazomethane (3), or 2-furyldiazomethane (4) provided further insight into the photochemical interconversions among C5H4S or C5H4O isomers, these studies did not lead to the spectroscopic detection of the corresponding triplet carbenes (2-thienylcarbene (11), 3-furylcarbene (23), or 2-furylcarbene (22), respectively)

Reconstruction of a scalar-tensor theory of gravity in an accelerating universe

The present acceleration of the Universe strongly indicated by recent observational data can be modeled in the scope of a scalar-tensor theory of gravity. We show that it is possible to determine the structure of this theory (the scalar field potential and the functional form of the scalar-gravity coupling) along with the present density of dustlike matter from the following two observable cosmological functions: the luminosity distance and the linear density perturbation in the dustlike matter component as functions of redshift. Explicit results are presented in the first order in the small inverse Brans-Dicke parameter 1/omega.Comment: 4 pages, LaTeX 2.09, REVTeX 3.0, two-column forma

The social life of Learning Analytics: cluster analysis and the ‘performance’ of algorithmic education

This paper argues that methods used for the classification and measurement of online education are not neutral and objective, but involved in the creation of the educational realities they claim to measure. In particular, the paper draws on material semiotics to examine cluster analysis as a ‘performative device’ that, to a significant extent, creates the educational entities it claims to objectively represent through the emerging body of knowledge of Learning Analytics (LA). It also offers a more critical and political reading of the algorithmic assemblages of LA, of which cluster analysis is a part. Our argument is that if we want to understand how algorithmic processes and techniques like cluster analysis function as performative devices, then we need methodological sensibilities that consider critically both their political dimensions and their technical-mathematical mechanisms. The implications for critical research in educational technology are discussed