Picosecond Laser Ablation of Polyhydroxyalkanoates (PHAs): Comparative Study of Neat and Blended Material Response

Polyhydroxyalkanoates (PHAs) have emerged as a promising biodegradable and biocompatible material for scaffold manufacturing in the tissue engineering field and food packaging. Surface modification is usually required to improve cell biocompatibility and/or reduce bacteria proliferation. Picosecond laser ablation was applied for surface micro structuring of short- and medium-chain length-PHAs and its blend. The response of each material as a function of laser energy and wavelength was analyzed. Picosecond pulsed laser modified the surface topography without affecting the material properties. UV wavelength irradiation showed halved ablation thresholds compared to visible (VIS) wavelength, revealing a greater photochemical nature of the ablation process at ultraviolet (UV) wavelength. Nevertheless, the ablation rate and, therefore, ablation efficiency did not show a clear dependence on beam wavelength. The different mechanical behavior of the considered PHAs did not lead to different ablation thresholds on each polymer at a constant wavelength, suggesting the interplay of the material mechanical parameters to equalize ablation thresholds. Blended-PHA showed a significant reduction in the ablation threshold under VIS irradiation respect to the neat PHAs. Picosecond ablation was proved to be a convenient technique for micro structuring of PHAs to generate surface microfeatures appropriate to influence cell behavior and improve the biocompatibility of scaffolds in tissue engineerin

Scaling relations of the colour-detected cluster RzCS 052 at z=1.016 and of some other high redshift clusters

We report on the discovery of the z=1.016 cluster RzCS 052 using a modified red sequence method, followup spectroscopy and X-ray imaging. This cluster has a velocity dispersion of 710+-150 km/s, a virial mass of 4.0e14 Msol (based on 21 spectroscopically confirmed members) and an X-ray luminosity of (0.68+- 0.47)e44 ergs/s in the [1-4] keV band. This optically selected cluster appears to be of richness class 3 and to follow the known L_X-sigma_v relation for high redshift X-ray selected clusters. Using these data, we find that the halo occupation number for this cluster is only marginally consistent with what expected assuming a self-similar evolution of cluster scaling relations, suggesting perhaps a break of them at z~1. We also rule out a strong galaxy merging activity between z=1 and today. Finally, we present a Bayesian approach to measuring cluster velocity dispersions and X-ray luminosities in the presence of a background: we critically reanalyze recent claims for X-ray underluminous clusters using these techniques and find that the clusters can be accommodated within the existing L_X -sigma_v relation.Comment: MNRAS, in pres

Chemical fractionation of siderophile elements in impactites from Australian meteorite craters

The abundance pattern of siderophile elements in terrestrial and lunar impact melt rocks was used extensively to infer the nature of the impacting projectiles. An implicit assumption made is that the siderophile abundance ratios of the projectiles are approximately preserved during mixing of the projectile constituents with the impact melts. As this mixture occurs during flow of strongly shocked materials at high temperatures, however there are grounds for suspecting that the underlying assumption is not always valid. In particular, fractionation of the melted and partly vaporized material of the projectile might be expected because of differences in volatility, solubility in silicate melts, and other characteristics of the constituent elements. Impactites from craters with associated meteorites offer special opportunities to test the assumptions on which projectile identifications are based and to study chemical fractionation that occurred during the impact process

X-ray Over-Luminous Elliptical Galaxies: A New Class of Mass Concentrations in the Universe?

We detect four isolated, X-ray over-luminous (Lx>2e43 [h/0.5]**-2 erg/s) elliptical galaxies (OLEGs) in our 160 square degree ROSAT PSPC survey. The extent of their X-ray emission, total X-ray luminosity, total mass, and mass of the hot gas in these systems correspond to poor clusters, and the optical luminosity of the central galaxies (M_R<-22.5 + 5 lg h) is comparable to that of cluster cDs. However, there are no detectable fainter galaxy concentrations around the central elliptical. The mass-to-light ratio within the radius of detectable X-ray emission is in the range 250-450 Msun/Lsun, which is 2-3 times higher than typically found in clusters or groups. These objects can be the result of galaxy merging within a group. However, their high M/L values are difficult to explain in this scenario. OLEGs must have been undisturbed for a very long time, which makes them the ultimate examples of systmes in hydrostatic equilibrium. The number density of OLEGs is n=2.4(+3.1-1.2}x10**-7 (h/0.5)**-3 Mpc**-3 at the 90% confidence. They comprise 20% of all clusters and groups of comparable X-ray luminosity, and nearly all galaxies brighter than M_R=-22.5. The estimated contirubution of OLEGs to the total mass density in the Universe is close to that of T>7 keV clusters.Comment: 4 pages, 2 figures, uses emulateapj.sty, submitted to ApJ Letter

Climate Modeling of a Potential ExoVenus

The planetary mass and radius sensitivity of exoplanet discovery capabilities has reached into the terrestrial regime. The focus of such investigations is to search within the Habitable Zone where a modern Earth-like atmosphere may be a viable comparison. However, the detection bias of the transit and radial velocity methods lies close to the host star where the received flux at the planet may push the atmosphere into a runaway greenhouse state. One such exoplanet discovery, Kepler-1649b, receives a similar flux from its star as modern Venus does from the Sun, and so was categorized as a possible exoVenus. Here we discuss the planetary parameters of Kepler-1649b with relation to Venus to establish its potential as a Venus analog. We utilize the general circulation model ROCKE-3D to simulate the evolution of the surface temperature of Kepler-1649b under various assumptions, including relative atmospheric abundances. We show that in all our simulations the atmospheric model rapidly diverges from temperate surface conditions towards a runaway greenhouse with rapidly escalating surface temperatures. We calculate transmission spectra for the evolved atmosphere and discuss these spectra within the context of the James Webb Space Telescope (JWST) Near-Infrared Spectrograph (NIRSpec) capabilities. We thus demonstrate the detectability of the key atmospheric signatures of possible runaway greenhouse transition states and outline the future prospects of characterizing potential Venus analogs.Comment: 11 pages, 4 figures, 1 table, accepted for publication in the Astrophysical Journal. The data from this paper are open source and are available from the following data portals: https://portal.nccs.nasa.gov/GISS_modelE/ROCKE-3D/Climate_Modeling_of_a_Potential_ExoVenus https://archive.org/details/Climate_Modeling_of_a_Potential_ExoVenu

Light to Mass Variations with Environment

Large and well defined variations exist between the distribution of mass and the light of stars on extragalactic scales. Mass concentrations in the range 10^12 - 10^13 M_sun manifest the most light per unit mass. Group halos in this range are typically the hosts of spiral and irregular galaxies with ongoing star formation. On average M/L_B ~ 90 M_sun/L_sun in these groups . More massive halos have less light per unit mass. Within a given mass range, halos that are dynamically old as measured by crossing times and galaxy morphologies have distinctly less light per unit mass. At the other end of the mass spectrum, below 10^12 M_sun, there is a cutoff in the manifestation of light. Group halos in the range 10^11 - 10^12 M_sun can host dwarf galaxies but with such low luminosities that M/L_B values can range from several hundred to several thousand. It is suspected that there must be completely dark halos at lower masses. Given the form of the halo mass function, it is the low relative luminosities of the high mass halos that has the greatest cosmological implications. Of order half the clustered mass may reside in halos with greater than 10^14 M_sun. By contrast, only 5-10% of clustered mass would lie in entities with less than 10^12 M_sun.Comment: 15 pages, 9 figures, 2 tables, Accepted Astrophysical Journal 619, 000, 2005 (Jan 1

Photometric observations of Southern Abell Cluster Redshifts Survey Clusters: Structure of galaxies in the inner region of clusters of galaxies

We analyze photometric properties of 1384 cluster galaxies as a function of the normalized distance to cluster center. These galaxies were selected in the central region ($r/r_{200} \leq$ 0.8) of 14 southern Abell clusters chosen from the Southern Abell Cluster Redshifts Survey (SARS). For 507 of these galaxies we also obtained their luminosity profiles. We have studied the morphology-clustercentric distance relation on the basis of the shape parameter $n$ of the S\'ersic's law. We also have analyzed the presence of a possible segregation in magnitude for both, the galaxy total luminosity and that of their components (i.e. the bulge and the disk). Results show a marginal ($2\sigma$ level) decrease of the total luminosity as a function of normalized radius. However, when bulges are analyzed separately, a significant luminosity segregation is found ($3\sigma$ and $2\sigma$ for galaxies in projection and member galaxies respectively). The fraction of bulges brighter than $M_B \leq -22$ is three times larger in the core of clusters than in the outer region. Our analysis of the disk component suggests that disks are, on average, less luminous in the cluster core than at $r/r_{200} \sim 0.8$. In addition, we found that the magnitude-size relation as a function of $r/r_{200}$ indicates (at $2\sigma$ level) that disks are smaller and centrally brighter in the core of clusters. However, the Kormendy relation (the bulge magnitude-size relation) appears to be independent of environment.Comment: To appear in the A

Representaciones subyacentes de un mundo insustentable

La relación entre la humanidad y la crisis ambiental, se encuentra en un punto de inflexión, con problemas que se manifiestan en los niveles local, regional y global. Cuando se piensa en el futuro, existe una tendencia a extrapolar linealmente lo que viene sucediendo; sin embargo, son numerosos los casos en los que las .situaciones futuras no son necesariamente una continuación de lo que venía ocurriendo. Existen virajes, reacciones desproporcionadas, colapsos y discontinuidades en los sistemas naturales y sociales en respuesta a muchas de las actividades humanas a las que son sometidos