32 research outputs found
Rhodium(I) complexes of the conformationally rigid IBioxMe4Ligand : isolation of a stable low-coordinate T-shaped complex
Get PDFThe isolation, characterization and reactivity of a T-shaped rhodium(I) complex containing Glorius’ bioxazoline derived N-heterocyclic carbene ligand IBioxMe4 is described: [Rh(IBioxMe4)3][BArF4] (1). 1 represents a rare example of a solution-stable “naked” 14-electron complex and is characterized in the solid state by highly distorted ligand geometries and Rh···C distances >3.1 Å for the IBioxMe4 alkyl substituents. Consistent with the bulky nature of the NHC ligand, no reaction was observed with excess IBioxMe4, PCy3, or norbornadiene. Reaction of 1 with CO, however, led to coordinatively saturated [Rh(IBioxMe4)3(CO)][BArF4] (2)
School Administrators and Physical Educators: A Scoping Review of Perceptions and Partnerships From 2000 to 2020
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Synthesis of the 13-Vertex Rhodacarborane Anion [4-(1, 2:5, 6-h-cod)-closo-4, 1, 6-RhC2B10H12]- and Its Reactions with Electrophiles
No full textRedesigning a Large Enrollment Course: The Impact on Academic Performance, Course Completion and Student Perceptions in Introductory Psychology
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