PIXE and ToF-SIMS analysis of streaker samplers filters

This paper presents methodological innovations introduced in the characterisation of urban aerosol collected in Italy in a recent campaign. Two complementary ion beam analysis (IBA) techniques were used to analyse Nuclepore filters used in continuous streaker samplers to collect airborne particles in four Italian towns. Na to Pb elemental concentrations were obtained by particle induced X-ray emission (PIXE), while time of flight secondary ion mass spectrometry (ToF-SIMS) produced, on the same samples, time trends for several elements and molecular fragments. In addition, light attenuation measurements were used as a tracer for black carbon. The data produced by these three techniques was merged into a unique data set to address the characterisation of particulate matter sources. Correlations between elemental concentration trends (PIXE) and relative trends for molecular fragments (ToF-SIMS) and black carbon (light attenuation) have been studied by cluster and principal component analysis

A TGA/FT-IR study for OC and EC quantification applied to carbonaceous aerosol collected in Milan (Italy)

International audienceCarbon analysis consists in the evaluation of the carbonaceous content of the aerosol (TC) but, more importantly, of its distribution between the two components EC (Elemental Carbon) and OC (Organic Carbon) that are characterized by different physical-chemical properties. In spite of the numerous studies focused on this topic, nowadays, a universal methodology for the determination of the two components EC and OC is not available. In fact OC and EC (also known as black carbon or soot) are operationally defined by the method of analysis and, as a consequence, different methods can produce different results. In this paper we present results on the application of TGA/FT-IR (Thermogravimetric Analysis/Fourier Transformed Infrared Spectroscopy) to the characterization of carbonaceous aerosols. The analytical methodology was applied to PM10 four-hour time resolution samples collected in Milan urban area. The method is a two-steps thermal one and bases itself on the different thermal behaviour of OC and EC. It has been set up analyzing suitable standards containing both organic and elemental carbon. Carbon quantification is achieved by on-line, continuous monitoring of CO2 infrared absorption at 2361 cm?1. A good separation between OC and EC on particulate matter samples has been obtained. Ranges and average values were respectively 12?70 µg/m3 and 20 µg/m3 for OC and 0.2?6 µg/m3 and 2 µg/m3 for EC. On average OC and EC made up respectively 29.3 (±12.8) % and 2.5 (±1.8) % of PM10 fraction. The method reliability has been verified by comparison with TOT (Thermal Optical Transmission) technique. OC and EC values determined for ambient samples of PM10 were also correlated with meteorological parameters as well as with Radon concentrations

Statistical mechanics of budget-constrained auctions

Finding the optimal assignment in budget-constrained auctions is a combinatorial optimization problem with many important applications, a notable example being the sale of advertisement space by search engines (in this context the problem is often referred to as the off-line AdWords problem). Based on the cavity method of statistical mechanics, we introduce a message passing algorithm that is capable of solving efficiently random instances of the problem extracted from a natural distribution, and we derive from its properties the phase diagram of the problem. As the control parameter (average value of the budgets) is varied, we find two phase transitions delimiting a region in which long-range correlations arise.Comment: Minor revisio

The resolved fraction of the Cosmic X-ray Background

We present the X-ray source number counts in two energy bands (0.5-2 and 2-10 keV) from a very large source sample: we combine data of six different surveys, both shallow wide field and deep pencil beam, performed with three different satellites (ROSAT, Chandra and XMM-Newton). The sample covers with good statistics the largest possible flux range so far: [2.4*10^-17 - 10^-11] cgs in the soft band and [2.1*10^-16 - 8*10^{-12}]cgs in the hard band. Integrating the flux distributions over this range and taking into account the (small) contribution of the brightest sources we derive the flux density generated by discrete sources in both bands. After a critical review of the literature values of the total Cosmic X--Ray Background (CXB) we conclude that, with the present data, the 94.3%, and 88.8% of the soft and hard CXB can be ascribed to discrete source emission. If we extrapolate the analytical form of the Log N--Log S distribution beyond the flux limit of our catalog in the soft band we find that the flux from discrete sources at ~3*10^-18 cgs is consistent with the entire CXB, whereas in the hard band it accounts for only 93% of the total CXB at most, hinting for a faint and obscured population to arise at even fainter fluxes.Comment: Accepted for publication in Ap

Canopy uptake dominates nighttime carbonyl sulfide fluxes in a boreal forest

Nighttime vegetative uptake of carbonyl sulfide (COS) can exist due to the incomplete closure of stomata and the light independence of the enzyme carbonic anhydrase, which complicates the use of COS as a tracer for gross primary productivity (GPP). In this study we derived nighttime COS fluxes in a boreal forest (the SMEAR II station in Hyytiälä, Finland; 61°51′ N, 24°17′ E; 181 m a.s.l.) from June to November 2015 using two different methods: eddy-covariance (EC) measurements (FCOS-EC) and the radon-tracer method (FCOS-Rn). The total nighttime COS fluxes averaged over the whole measurement period were −6.8 ± 2.2 and −7.9 ± 3.8 pmol m−2 s−1 for FCOS-Rn and FCOS-EC, respectively, which is 33–38 % of the average daytime fluxes and 21 % of the total daily COS uptake. The correlation of 222Rn (of which the source is the soil) with COS (average R2  =  0.58) was lower than with CO2 (0.70), suggesting that the main sink of COS is not located at the ground. These observations are supported by soil chamber measurements that show that soil contributes to only 34–40 % of the total nighttime COS uptake. We found a decrease in COS uptake with decreasing nighttime stomatal conductance and increasing vapor-pressure deficit and air temperature, driven by stomatal closure in response to a warm and dry period in August. We also discuss the effect that canopy layer mixing can have on the radon-tracer method and the sensitivity of (FCOS-EC) to atmospheric turbulence. Our results suggest that the nighttime uptake of COS is mainly driven by the tree foliage and is significant in a boreal forest, such that it needs to be taken into account when using COS as a tracer for GPP