Ionic liquids and organic ionic plastic crystals utilizing small phosphonium cations

The development of new liquid and solid state electrolytes is paramount for the advancement of electrochemical devices such as lithium batteries and solar cells. Ionic liquids have shown great promise in both these applications. Here we demonstrate the use of phosphonium cations with small alkyl chain substituents, in combination with a range of different anions, to produce a variety of new halide free ionic liquids that are fluid, conductive and with sufficient thermal stability for a range of electrochemical applications. Walden plot analysis of the new phosphonium ionic liquids shows that these can be classed as &quot;good&quot; ionic liquids, with low degrees of ion pairing and/or aggregation, and the lithium deposition and stripping from one of these ionic liquids has been demonstrated. Furthermore, for the first time phosphonium cations have been used to form a range of organic ionic plastic crystals. These materials can show significant ionic conductivity in the solid state and thus are of great interest as potential solid-state electrolyte materials. <br /

Cardiomyocyte-restricted overexpression of extracellular superoxide dismutase increases nitric oxide bioavailability and reduces infarct size after ischemia/reperfusion

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A cognitive science analysis of the Quaker Business Method: is how it works why it works?

The Quaker Business Method (QBM) has been in development for over 300 years. Quakers believe that the QBM is an effective means for making decisions. This paper develops a tripartite theoretical framework to analyze the QBM in order to examine its efficacy, both in terms of the quality of its processes and the morality of its decisions. The framework encompasses: (1) a decomposition of the QBM as a set of tools; (2) a selection of theories and models from cognitive science that explain how humans think; (3) a set of relational models that can be used to objectively judge the morality of different forms of human behavioural interactions. Overall, it appears that QBM tools may counter the deficits in natural human abilities to reason and solve problems, and that they may promote decision making practices that are moral and that the resulting decisions, themselves, may be moral

Graft Uptake and Hearing Outcomes in Myringoplasty by Conventional Temporalis Fascia Underlay Technique with and without Addition of Platelet Rich Fibrin (Prf): A Prospective, Randomised Double Blind Study

Myringoplasty is a crucial surgical technique employed to repair tympanic membrane perforations, safeguarding the middle ear cavity from external exposure and associated risks. While traditional graft materials such as temporalis fascia, cartilage, and vein grafts have shown graft uptake success rates ranging from 64% to 96%, challenges like graft failure persist. To address this, innovative methods such as the application of platelet-rich fibrin (PRF) have gained attention. PRF, a second-generation platelet concentrate, is rich in growth factors, cytokines, and glycoproteins, promoting accelerated wound healing, cellular proliferation, and matrix remodelling. As an autologous material, PRF offers significant advantages, including safety, cost-effectiveness, and ease of preparation. This study aims to evaluate the efficacy of PRF in enhancing graft uptake and hearing outcomes among patients undergoing myringoplasty. By exploring its potential, this research seeks to establish PRF as an ideal adjunct in surgical management, addressing current limitations and optimizing patient care outcomes

A rare case of posterior circulation stroke with anterior spinal artery involvement

A 36 year old gentlemen with diabetes mellitus and systemic hypertension with acute onset giddiness with weakness of both upper limbs, developed over a period of several hours with bilateral triceps weakness, wrist dorsiflexion and palmar flexion weakness with no sensory disturbance and cerebellar signs. MRI brain showed left cerebellar infarct, left lateral medullary infarct, non- visualization of left vertebral artery, T2 hyper-intensity of cervical cord from 4th cervical segment to 8th cervical segment, multiple areas are affected because of left vertebral artery occlusion

Nutraceutical therapies for atherosclerosis

Atherosclerosis is a chronic inflammatory disease affecting large and medium arteries and is considered to be a major underlying cause of cardiovascular disease (CVD). Although the development of pharmacotherapies to treat CVD has contributed to a decline in cardiac mortality in the past few decades, CVD is estimated to be the cause of one-third of deaths globally. Nutraceuticals are natural nutritional compounds that are beneficial for the prevention or treatment of disease and, therefore, are a possible therapeutic avenue for the treatment of atherosclerosis. The purpose of this Review is to highlight potential nutraceuticals for use as antiatherogenic therapies with evidence from in vitro and in vivo studies. Furthermore, the current evidence from observational and randomized clinical studies into the role of nutraceuticals in preventing atherosclerosis in humans will also be discussed

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Not AvailableArunachal Pradesh, the largest mountainous state of India, is situated in the northeastern part of the Himalayan region and characterized by high annual rainfall, forest vegetation and diversity in soils. Information on the soils of the state is essential for scientific land use planning and sustainable production. A soil resource inventory and subsequent database creation for thematic mapping using a Geographical Information System (GIS) is presented in this paper. Physiographically, Arunachal Pradesh can be divided into four distinct zones: snow-capped mountains (5500 m amsl); lower Himalayan ranges (3500 m amsl); the sub-Himalayan Siwalik hills (700 m amsl); and the eastern Assam plains. Soils occurring in these physiographic zones are lnceptisols (37 percent), Entisols (35 per- cent), Ultisols (14 percent) and Alfisols (0.5 percent). The remaining soils can be classed as miscellaneous. Soil resource inventory studies show that the soils of the warm perhumid eastern Himalayan ecosystem, with a ‘thermic’ temperature regime, are lnceptisols and Entisols; and that they are highly acidic in nature. Soils of the warm perhumid Siwalik hill ecosystem, with a ‘hyperthermic’ temperature regime, are also Entisols and lnceptisols with a high to moderate acidic condition. The dominant soils of the northeastern Purvachal hill ecosystem, with ‘hyperthermic’ and ‘thermic’ temperature regimes, are Ultisols and Inceptisols. lnceptisols and Entisols are the dominant soils in the hot and humid plain ecosystem. Steeply sloping landform and high rainfall are mainly responsible for a high erosion hazard in the state. The soil erosion map indicates that very severe (20 percent of TGA) to severe (25 percent of TGA) soil erosion takes place in the warm per-humid zone, whereas, moderate erosion takes place in the Siwalik hills and hot, humid plain areas. This is evident from the soil depth class distribution of Arunachal Pradesh, which shows that shallow soils cover 20 percent of the TGA of the state. Most of the the state is covered by hills and agri- cultural practices are limited to valley regions, However, the soils of other physiographic zones (lower altitudinal, moderately hilly terrain) provide scope for plantations, such as orange, banana and tea plantations.Not Availabl

Effects of a Mathematics Cognitive Acceleration Program on Student Achievement and Motivation

This paper presents the effects of a cognitive acceleration program in mathematics classes on Tongan students’ achievements, motivation and self-regulation. Cognitive Acceleration in Mathematics Education (CAME) is a program developed at King’s College and implemented worldwide with the aim of improving students’ thinking skills, mathematics performance and attitudes. The first author adapted the program materials to Tongan educational context and provided support to participating teachers for 8 months. This study employed a quasi-experimental design with 219 Year 8 students as the experimental group and 119 Year 8 students as the comparison group. There were a significant differences in the mean scores between the pre-test and post-test of the three instruments that were employed in the study, indicating that learning mathematics under the CAME program had a positive effect on levels of students’ self-regulation, motivation and mathematics achievement. Students also reported changes to the ways they learn mathematics

Accountability in the East Asian economic miracle, crisis and recovery

Despite claims that accountability enables 'good governance' proper, its specific origins, character and limitations are not yet fully clear. In order to explicate the nature of accountability better this paper will, therefore, formulate and apply its own comparative framework to the case of the East Asian economic miracle, crisis and recovery in particular. In so doing it finds that, even when accountability emerged as a mid-crisis issue that was dramatically reconfigured for any due recovery later, it was not itself then sufficiently explicated for all the implications and consequences to be realized fully. Once it is explicated more fully, however, the further implications and consequences of changing accountability for economic governance question precisely what is to be expected from accountability per se

Altitudinal variation in soil organic carbon stock in coniferous subtropical and broadleaf temperate forests in Garhwal Himalaya

<p>Abstract</p> <p>Background</p> <p>The Himalayan zones, with dense forest vegetation, cover a fifth part of India and store a third part of the country reserves of soil organic carbon (SOC). However, the details of altitudinal distribution of these carbon stocks, which are vulnerable to forest management and climate change impacts, are not well known.</p> <p>Results</p> <p>This article reports the results of measuring the stocks of SOC along altitudinal gradients. The study was carried out in the coniferous subtropical and broadleaf temperate forests of Garhwal Himalaya. The stocks of SOC were found to be decreasing with altitude: from 185.6 to 160.8 t C ha^-1and from 141.6 to 124.8 t C ha^-1in temperature (<it>Quercus leucotrichophora</it>) and subtropical (<it>Pinus roxburghii</it>) forests, respectively.</p> <p>Conclusion</p> <p>The results of this study lead to conclusion that the ability of soil to stabilize soil organic matter depends negatively on altitude and call for comprehensive theoretical explanation</p