Temperature measurements on ES steel sheets subjected to perforation by hemispherical projectiles

In this paper is reported a study on the behaviour of ES mild steel sheets subjected to perforation by hemispherical projectiles. Experiments have been conducted using a pneumatic cannon within the range of impact velocities 5m/s<=V0<=60m/s. The experimental setup allowed evaluating initial velocity, failure mode and post-mortem deflection of the plates. The tests have been recorded using high speed infrared camera. It made possible to obtain temperature contours of the specimen during impact. Thus, special attention is focussed on the thermal softening of the material which is responsible for instabilities and failure. Assuming adiabatic conditions of deformation, the increase of temperature may be related to the plastic deformation. The critical strain leading to target-failure is evaluated coupling temperature measurements with numerical simulations and with analytical predictions obtained by means of the Rusinek-Klepaczko constitutive relation [Rusinek, A., Klepaczko, J.R. Shear testing of sheet steel at wide range of strain rates and a constitutive relation with strain rate and temperature dependence of the flow stress. Int J Plasticity. 2001; 17, 87-115]. It has been estimated that the process of localization of plastic deformation which leads to target-failure involves local values close to for the boundary value problem approached. Subsequently, this failure strain level has been applied to simulate the perforation process and the numerical results obtained show satisfactory agreement with the experiments in terms of ballistic limit, temperature increase and failure mode of the target.The researchers of the University Carlos III of Madrid are indebted to the Comunidad Autónoma de Madrid (Project CCG08 UC3M/MAT 4464) and to the Ministerio de Ciencia e Innovación de España (Project DPI/2008 06408)Publicad

Probing the role of Co substitution in the electronic structure of iron-pnictides

The role of Co substitution in the low-energy electronic structure of Ca(Fe$_{0.944}$Co$_{0.056}$)$_2$As$_2$ is investigated by resonant photoemission spectroscopy and density functional theory. The Co 3d-state center-of-mass is observed at 250 meV higher binding energy than Fe's, indicating that Co posses one extra valence electron, and that Fe and Co are in the same 2+ oxidation state. Yet, significant Co character is detected for the Bloch wavefunctions at the chemical potential, revealing that the Co 3d electrons are part of the Fermi sea determining the Fermi surface. This establishes the complex role of Co substitution in CaFe2As2, and the inadequacy of a rigid-band shift description.Comment: 4 pages, 4 figure

Pathways into services for offenders with intellectual disabilities : childhood experience, diagnostic information and offence variables

The patterns and pathways into intellectual disability (ID) offender services were studied through case file review for 477 participants referred in one calendar year to community generic, community forensic, and low, medium, and maximum secure services. Data were gathered on referral source, demographic information, index behavior, prior problem behaviors, diagnostic information, and abuse or deprivation. Community referrers tended to refer to community services and secure service referrers to secure services. Physical and verbal violence were the most frequent index behaviors, whereas contact sexual offenses were more prominent in maximum security. Age at first incident varied with security, with the youngest in maximum secure services. Attention-deficit/hyperactivity disorder or conduct disorder was the most frequently recorded diagnosis, and severe deprivation was the most frequent adverse developmental experience. Fire starting, theft, and road traffic offenses did not feature prominently. Generic community services accepted a number of referrals with forensic-type behavior and had higher proportions of both women and people with moderate or severe ID

Unveiling the intruder deformed 02+^+_2 state in 34^{34}Si

The 0$^+_2$ state in $^{34}$Si has been populated at the {\sc Ganil/Lise3} facility through the $\beta$-decay of a newly discovered 1$^+$ isomer in $^{34}$Al of 26(1) ms half-life. The simultaneous detection of $e^+e^-$ pairs allowed the determination of the excitation energy E(0$^+_2$)=2719(3) keV and the half-life T$_{1/2}$=19.4(7) ns, from which an electric monopole strength of $\rho^2$(E0)=13.0(0.9)$\times10^{-3}$ was deduced. The 2$^+_1$ state is observed to decay both to the 0$^+_1$ ground state and to the newly observed 0$^+_2$ state (via a 607(2) keV transition) with a ratio R(2$^+_1$$\rightarrow0^+_1/2^+_1$$\rightarrow0^+_2$)=1380(717). Gathering all information, a weak mixing with the 0$^+_1$ and a large deformation parameter of $\beta$=0.29(4) are found for the 0$^+_2$ state, in good agreement with shell model calculations using a new {\sc sdpf-u-mix} interaction allowing \textit{np-nh} excitations across the N=20 shell gap.Comment: 5 pages, 3 figures, accepted for publication in Physical Review Letter

Structure of Tagatose-1,6-bisphosphate Aldolase. Insight into chiral discrimination, mechanism, and specificity of class II aldolases

Tagatose-1,6-bisphosphate aldolase (TBPA) is a tetrameric class II aldolase that catalyzes the reversible condensation of dihydroxyacetone phosphate with glyceraldehyde 3-phosphate to produce tagatose 1,6-bisphosphate. The high resolution (1.45 Å) crystal structure of the Escherichia coli enzyme, encoded by the agaY gene, complexed with phosphoglycolohydroxamate (PGH) has been determined. Two subunits comprise the asymmetric unit, and a crystallographic 2-fold axis generates the functional tetramer. A complex network of hydrogen bonds position side chains in the active site that is occupied by two cations. An unusual Na(+) binding site is created using a interaction with Tyr(183) in addition to five oxygen ligands. The catalytic Zn(2+) is five-coordinate using three histidine nitrogens and two PGH oxygens. Comparisons of TBPA with the related fructose-1,6-bisphosphate aldolase (FBPA) identifies common features with implications for the mechanism. Because the major product of the condensation catalyzed by the enzymes differs in the chirality at a single position, models of FBPA and TBPA with their cognate bisphosphate products provide insight into chiral discrimination by these aldolases. The TBPA active site is more open on one side than FBPA, and this contributes to a less specific enzyme. The availability of more space and a wider range of aldehyde partners used by TBPA together with the highly specific nature of FBPA suggest that TBPA might be a preferred enzyme to modify for use in biotransformation chemistry

Imaging and controlling electron transport inside a quantum ring

Traditionally, the understanding of quantum transport, coherent and ballistic1, relies on the measurement of macroscopic properties such as the conductance. While powerful when coupled to statistical theories, this approach cannot provide a detailed image of "how electrons behave down there". Ideally, understanding transport at the nanoscale would require tracking each electron inside the nano-device. Significant progress towards this goal was obtained by combining Scanning Probe Microscopy (SPM) with transport measurements2-7. Some studies even showed signatures of quantum transport in the surrounding of nanostructures4-6. Here, SPM is used to probe electron propagation inside an open quantum ring exhibiting the archetype of electron wave interference phenomena: the Aharonov-Bohm effect8. Conductance maps recorded while scanning the biased tip of a cryogenic atomic force microscope above the quantum ring show that the propagation of electrons, both coherent and ballistic, can be investigated in situ, and even be controlled by tuning the tip potential.Comment: 11 text pages + 3 figure

Analytical and Numerical Demonstration of How the Drude Dispersive Model Satisfies Nernst's Theorem for the Casimir Entropy

In view of the current discussion on the subject, an effort is made to show very accurately both analytically and numerically how the Drude dispersive model, assuming the relaxation is nonzero at zero temperature (which is the case when impurities are present), gives consistent results for the Casimir free energy at low temperatures. Specifically, we find that the free energy consists essentially of two terms, one leading term proportional to T^2, and a next term proportional to T^{5/2}. Both these terms give rise to zero Casimir entropy as T -> 0, thus in accordance with Nernst's theorem.Comment: 11 pages, 4 figures; minor changes in the discussion. Contribution to the QFEXT07 proceedings; matches version to be published in J. Phys.

Casimir-Polder force between an atom and a dielectric plate: thermodynamics and experiment

The low-temperature behavior of the Casimir-Polder free energy and entropy for an atom near a dielectric plate are found on the basis of the Lifshitz theory. The obtained results are shown to be thermodynamically consistent if the dc conductivity of the plate material is disregarded. With inclusion of dc conductivity, both the standard Lifshitz theory (for all dielectrics) and its generalization taking into account screening effects (for a wide range of dielectrics) violate the Nernst heat theorem. The inclusion of the screening effects is also shown to be inconsistent with experimental data of Casimir force measurements. The physical reasons for this inconsistency are elucidated.Comment: 10 pages, 1 figure; improved discussion; to appear in J. Phys. A: Math. Theor. (Fast Track Communications

On the selection and design of proteins and peptide derivatives for the production of photoluminescent, red-emitting gold quantum clusters

Novel pathways of the synthesis of photoluminescent gold quantum clusters (AuQCs) using biomolecules as reactants provide biocompatible products for biological imaging techniques. In order to rationalize the rules for the preparation of red-emitting AuQCs in aqueous phase using proteins or peptides, the role of different organic structural units was investigated. Three systems were studied: proteins, peptides, and amino acid mixtures, respectively. We have found that cysteine and tyrosine are indispensable residues. The SH/S-S ratio in a single molecule is not a critical factor in the synthesis, but on the other hand, the stoichiometry of cysteine residues and the gold precursor is crucial. These observations indicate the importance of proper chemical behavior of all species in a wide size range extending from the atomic distances (in the AuI-S semi ring) to nanometer distances covering the larger sizes of proteins assuring the hierarchical structure of the whole self-assembled system