1,053 research outputs found
Magnetic field generated resistivity maximum in graphite
In zero magnetic field, B, the electrical resistivity, rho(O,T) of highly oriented pyrolytic (polycrystalline) graphite drops smoothly with decreasing T, becoming constant below 4 K. However, in a fixed applied magnetic field B, the resistivity rho(B,T) goes through a maximum as a function of T, with larger maximum for larger B. The temperature of the maximum increases with B, but saturates to a constant value near 25 K (exact T depends on sample) at high B. In single crystal graphite a maximum in rho(B,T) as a function of T is also present, but has the effects of Landau level quantization superimposed. Several possible explanations for the rho(B,T) maximum are proposed, but a complete explanation awaits detailed calculations involving the energy band structure of graphite, and the particular scattering mechanisms involved
A simulational and theoretical study of the spherical electrical double layer for a size-asymmetric electrolyte: the case of big coions
Monte Carlo simulations of a spherical macroion, surrounded by a
size-asymmetric electrolyte in the primitive model, were performed. We
considered 1:1 and 2:2 salts with a size ratio of 2 (i.e., with coions twice
the size of counterions), for several surface charge densities of the
macrosphere. The radial distribution functions, electrostatic potential at the
Helmholtz surfaces, and integrated charge are reported. We compare these
simulational data with original results obtained from the Ornstein-Zernike
integral equation, supplemented by the hypernetted chain/hypernetted chain
(HNC/HNC) and hypernetted chain/mean spherical approximation (HNC/MSA)
closures, and with the corresponding calculations using the modified
Gouy-Chapman and unequal-radius modified Gouy-Chapman theories. The HNC/HNC and
HNC/MSA integral equations formalisms show good concordance with Monte Carlo
"experiments", whereas the notable limitations of point-ion approaches are
evidenced. Most importantly, the simulations confirm our previous theoretical
predictions of the non-dominance of the counterions in the size-asymmetric
spherical electrical double layer [J. Chem. Phys. 123, 034703 (2005)], the
appearance of anomalous curvatures at the outer Helmholtz plane and the
enhancement of charge reversal and screening at high colloidal surface charge
densities due to the ionic size asymmetry.Comment: 11 pages, 7 figure
The electrical double layer for a fully asymmetric electrolyte around a spherical colloid: an integral equation study
The hypernetted chain/mean spherical approximation (HNC/MSA) integral
equation is obtained and solved numerically for a totally asymmetric primitive
model electrolyte around a spherical macroparticle. The ensuing radial
distribution functions show a very good agreement when compared to our Monte
Carlo and molecular dynamics simulations for spherical geometry and with
respect to previous anisotropic reference HNC calculations in the planar limit.
We report an analysis of the potential vs charge relationship, radial
distribution functions, mean electrostatic potential and cumulative reduced
charge for representative cases of 1:1 and 2:2 salts with a size asymmetry
ratio of 2. Our results are collated with those of the Modified Gouy-Chapman
(MGC) and unequal radius Modified Gouy-Chapman (URMGC) theories and with those
of HNC/MSA in the restricted primitive model (RPM) to assess the importance of
size asymmetry effects. One of the most striking characteristics found is
that,\textit{contrary to the general belief}, away from the point of zero
charge the properties of an asymmetric electrical double layer (EDL) are not
those corresponding to a symmetric electrolyte with the size and charge of the
counterion, i.e. \textit{counterions do not always dominate}. This behavior
suggests the existence of a new phenomenology in the EDL that genuinely belongs
to a more realistic size-asymmetric model where steric correlations are taken
into account consistently. Such novel features can not be described by
traditional mean field theories like MGC, URMGC or even by enhanced formalisms,
like HNC/MSA, if they are based on the RPM.Comment: 29 pages, 13 figure
Missing and Quenched Gamow Teller Strength
Gamow-Teller strength functions in full spaces are calculated with
sufficient accuracy to ensure that all the states in the resonance region have
been populated. Many of the resulting peaks are weak enough to become
unobservable. The quenching factor necessary to bring into agreement the low
lying observed states with shell model predictions is shown to be due to
nuclear correlations. To within experimental uncertainties it is the same that
is found in one particle transfer and (e,e') reactions. Perfect consistency
between the observed peaks and the calculation is
achieved by assuming an observation threshold of 0.75\% of the total strength,
a value that seems typical in several experimentsComment: 11 pages, 6 figures avalaible upon request, RevTeX, FTUAM-94/0
Systemic sclerosis is associated with specific alterations in gastrointestinal microbiota in two independent cohorts.
ObjectiveTo compare faecal microbial composition in patients with systemic sclerosis (SSc) from 2 independent cohorts with controls and to determine whether certain genera are associated with SSc-gastrointestinal tract (GIT) symptoms.DesignAdult patients with SSc from the University of California, Los Angeles (UCLA) and Oslo University Hospital (OUH) and healthy controls participated in this study (1:1:1). All participants provided stool specimens for 16S rRNA sequencing. Linear discriminant analysis effect size demonstrated genera with differential expression in SSc. Differential expression analysis for sequence count data identified specific genera associated with GIT symptoms as assessed by the GIT 2.0 questionnaire.ResultsThe UCLA-SSc and OUH-SSc cohorts were similar in age (52.1 and 60.5 years, respectively), disease duration (median (IQR): 6.6 (2.5-16.4) and 7.0 (1.0-19.2) years, respectively), gender distribution (88% and 71%, respectively), and GIT symptoms (mean (SD) total GIT 2.0 scores of 0.7 (0.6) and 0.6 (0.5), respectively). Principal coordinate analysis illustrated significant microbial community differences between SSc and controls (UCLA: p=0.001; OUH: p=0.002). Patients with SSc had significantly lower levels of commensal genera deemed to protect against inflammation, such as Bacteroides (UCLA and OUH), Faecalibacterium (UCLA), Clostridium (OUH); and significantly higher levels of pathobiont genera, such as Fusobacterium (UCLA), compared with controls. Increased abundance of Clostridium was associated with less severe GIT symptoms in both cohorts.ConclusionsThe present analysis detected specific aberrations in the lower GIT microbiota of patients with SSc from 2 geographically and ethnically distinct cohorts. These findings suggest that GIT dysbiosis may be a pathological feature of the SSc disease state
An Anisotropic Ballistic Deposition Model with Links to the Ulam Problem and the Tracy-Widom Distribution
We compute exactly the asymptotic distribution of scaled height in a
(1+1)--dimensional anisotropic ballistic deposition model by mapping it to the
Ulam problem of finding the longest nondecreasing subsequence in a random
sequence of integers. Using the known results for the Ulam problem, we show
that the scaled height in our model has the Tracy-Widom distribution appearing
in the theory of random matrices near the edges of the spectrum. Our result
supports the hypothesis that various growth models in dimensions that
belong to the Kardar-Parisi-Zhang universality class perhaps all share the same
universal Tracy-Widom distribution for the suitably scaled height variables.Comment: 5 pages Revtex, 3 .eps figures included, new references adde
The Parallel Complexity of Growth Models
This paper investigates the parallel complexity of several non-equilibrium
growth models. Invasion percolation, Eden growth, ballistic deposition and
solid-on-solid growth are all seemingly highly sequential processes that yield
self-similar or self-affine random clusters. Nonetheless, we present fast
parallel randomized algorithms for generating these clusters. The running times
of the algorithms scale as , where is the system size, and the
number of processors required scale as a polynomial in . The algorithms are
based on fast parallel procedures for finding minimum weight paths; they
illuminate the close connection between growth models and self-avoiding paths
in random environments. In addition to their potential practical value, our
algorithms serve to classify these growth models as less complex than other
growth models, such as diffusion-limited aggregation, for which fast parallel
algorithms probably do not exist.Comment: 20 pages, latex, submitted to J. Stat. Phys., UNH-TR94-0
Homogenized dynamics of stochastic partial differential equations with dynamical boundary conditions
A microscopic heterogeneous system under random influence is considered. The
randomness enters the system at physical boundary of small scale obstacles as
well as at the interior of the physical medium. This system is modeled by a
stochastic partial differential equation defined on a domain perforated with
small holes (obstacles or heterogeneities), together with random dynamical
boundary conditions on the boundaries of these small holes.
A homogenized macroscopic model for this microscopic heterogeneous stochastic
system is derived. This homogenized effective model is a new stochastic partial
differential equation defined on a unified domain without small holes, with
static boundary condition only. In fact, the random dynamical boundary
conditions are homogenized out, but the impact of random forces on the small
holes' boundaries is quantified as an extra stochastic term in the homogenized
stochastic partial differential equation. Moreover, the validity of the
homogenized model is justified by showing that the solutions of the microscopic
model converge to those of the effective macroscopic model in probability
distribution, as the size of small holes diminishes to zero.Comment: Communications in Mathematical Physics, to appear, 200
Rethinking the exercise of sovereignty in the Anthropocene: From extraction to environmental protection in Arctic Svalbard
Optimal and Long-Term Dynamic Transport Policy Design: Seeking Maximum Social Welfare through a Pricing Scheme.
This article presents an alternative approach to the decision-making process in transport strategy design. The study explores the possibility of integrating forecasting,
assessment and optimization procedures in support of a decision-making process designed to reach the best achievable scenario through mobility policies.
Long-term evaluation, as required by a dynamic system such as a city, is provided by a strategic Land-Use and Transport Interaction (LUTI) model. The social welfare
achieved by implementing mobility LUTI model policies is measured through a cost-benefit analysis and maximized through an optimization process throughout the evaluation period. The method is tested by optimizing a pricing policy scheme in Madrid on a cordon toll in a context requiring system efficiency, social equity and environmental quality. The optimized scheme yields an appreciable increase in social surplus through a relatively low rate compared to other similar pricing toll schemes. The results highlight the different considerations regarding mobility impacts on the case study area, as well as the major contributors to social welfare surplus. This leads the authors to reconsider the cost-analysis approach, as defined in the study, as the best option for formulating sustainability measures
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