Chemostratigraphy of the Pliensbachian, Puesto Araya Formation (Neuquén Basin, Argentina)

In a preliminary attempt to establish an isotope stratigraphy, strontium, carbon and oxygen isotope ratios were determined from marine biogenic carbonates of Pliensbachian age, in the context of scheme of local ammonite Zones correlatable to the European Standard Zonation. Two sections, rio Atuel and arroyo Serrucho, of the mainly siliciclastic Puesto Araya Formation, Neuquen Basin, south-western Mendoza, Argentina, were studied. Specimens of the bivalve genera Weyla Bhom and Gryphaea Lamarck were selected for the isotopic determinations because of their low-Mg calcite original mineralogy and widespread presence. Scanning electron microscopy, X-ray diffraction and X-ray fluorescence spectrometry techniques were used to control the good degree of preservation of most of the biogenic material, as evidenced by pristine fabrics, 100% calcite composition and Sr, Mn and Fe concentrations. Although strontium isotope ratios are slightly scattered, it is possible to compare them with those of the Early Jurassic seawater reference curve. Carbon isotope signals show two relative maxima, correlatable with those recorded for the upper part of the Ibex Zone and the middle part of the Margaritatus Zone in various European sections, indicating the possible global significance of these events. d18O values were found to be unreliable for isotope stratigraphy, as they are largely depleted in comparison to those of coeval unaltered marine carbonates

Modelling the effects of the anode work function in PPV LED

Transparent conducting oxides are widely used as the transparent electrode in polymer light emitting diodes (PLEDs). The physical properties of these materials and consequently device performance strongly depend on their processing and surface treatment. The injection of charge from the transparent electrode into the polymer layer occurs by tunnelling through a potential barrier from the electrode to molecules close to it. This barrier is influenced by the difference in the relevant energy levels of electrode material and polymer molecules, the external applied potential, the Coulomb potential of the charges present in the polymer layer and the potential of their image charges on the electrodes, and may also be altered by electrode degradation effects. A better understanding of the effect of varying this potential barrier on the functioning of PLED is necessary to achieve further improvements in these applications. Here we present a theoretical study of the influence of changes in the potential barrier at the transparent electrode, on bipolar charge evolution through thin polymer layers, in the absence of defects and impurity states, while the other electrode functions as an ohmic contact. Results of a mesoscopic model provide insight into bipolar charge injection, charge and recombination distribution throughout the polymer layer, and may suggest new materials and processing methods to optimize these optoelectronic devices.FEDER.Fundação para a Ciência e a Tecnologia (FCT) – Programa Operacional “Ciência , Tecnologia, Inovação” – POCTI/CTM/41574/2001, CONC-REEQ/443/EEI/2005; SFRH/BD/22143/2005

Green tea as a promising extract of active food packaging

Introduction: Tea is one of the most popular and frequently consumed beverages in the world and its consumption dates back to more than 2000 years in China and then spread to other areas including Japan and later on to Europe (Zhao et al., 2014). Green tea is produced from Camellia sinensis (L.) Kuntze leaf infusion and is well known for its pleasant flavour and is associated with positive health effects. The biological activity of green tea is related with the considerable amount of catechins and other phenolic compounds, in particular flavonols and phenolic acids, present in its composition (Zhao et al., 2014). These phenolic compounds prevent the oxidative damage through their antioxidant activity and also reduce the risk of cancer, cardiovascular and neurodegenerative diseases (Lorenzo et al., 2014). The process of oxidation is one of the most common mechanisms of degradation of foodstuffs and it can alter food texture and colour, decrease nutritional quality, develop off-odours and also produce possible toxic compounds. As a consequence, the shelf-life and commercial acceptability of the food products decrease. Currently, one of the major concerns of the consumers is the impact of food on health. In line with this, food industry is trying to substitute synthetic additives by natural compounds. These can be directly added to food or incorporated in food packaging with the aim of being controlled released throughout the product shelf life. This concept is so-called Active packaging and allows the packaging to positively interact with foods to increase food shelf-life. This interaction can be due to the intended release of compounds from packaging to the foods or to their headspace, or due to the scavenging of compounds by the packaging from the packaged foods. Due to the antioxidant capacity of green tea, its extract can be proposed as an alternative to synthetic antioxidants (Giménez et al., 2013). In fact, it has already been applied in active food packaging. Material and Methods: The present review focuses on the application of green tea extract in active packaging. In this regard, an extensive bibliographic research was carried out in order to evaluate the polymers already used to incorporate green tea extract, as well as the mechanical and barrier properties and efficiency of these packaging systems in contact with foods. Results and Discussion: The chemical composition of tea leaves on active compounds with antioxidant activity is well documented. Bioactive constituents of the tea leaves include catechin gallates such as epigallocatechin gallate and gallocatechin gallate (López de Dicastillo et al., 2011). However the levels of these compounds depend on many factors, such as the edaphoclimatic conditions and drying conditions of the Camellia sinensis leaves. Moreover the extraction and analysis methods can also have a great influence in their content. Green tea extract has already been incorporated into different polymers. In fact, most of them are edible such as proteic films from distilled dry beans (Yang et al., 2016), agar (Lacey et al., 2014), chitosan (Siripatrawan et al., 2012; Siripatrawan et al., 2010) and gelatine (Hong et al (2009). Green tea extract (GTE) can offers protection against oxidation, significantly reducing rancidity and thereby extending the shelf-life of packaged foods. Moreover the sensory analysis also demonstrated that packaged food was unaffected by GTE (Carrizo et al., 2016). According to Yang et al. (2016), the incorporation of the GTE did not alter the physical properties of the films. According to Siripatrawan et al. (2010), the incorporation of GTE improved the mechanical and water vapour barrier properties. In general, GTE provides a very positive impact in the reduction of oxidation of all types of food, from aqueous to fatty (López de Dicastillo et al., 2011), although most of the studies selected meat (e.g. pork, pork sausages, pork loins), or fish products (e.g. fillets of hake, salted sardines) to test the efficiency of the active films. Conclusion: Green tea has great potential of application in active food packaging due to its antioxidant capacity. Therefore, in the near future, is it possible that new food packaging based on GTE will arise in the market. However, more studies are require to elucidate about the concentrations of GTE that do not affect or affect positively the mechanical or barrier properties of the packaging and that are effective as oxidation inhibitors of packaged foodsThis work was supported by the research project “Development of methodologies for the evaluation of polymeric food packaging components and determination of their structural and mechanical properties” (2016DAN 1289) funded by the National Institute of Health Dr Ricardo Jorge, I.P., Lisbon, Portugal.N/

The effect of the intramolecular properties in single-carrier polymer diodes

The electric behaviour of polymer diodes has the influence of several factors such as the electrodes work function, the experimental conditions used to deposit the active component or the chemistry of the polymer. Although experimentally it is possible to study the effect of some of these factors on the device performance, for instance by changing the chemical structure of the polymer used or the type of electrodes, it is impossible to study individually each one of these effects because changing one of them can influence the others. Quantum mechanical calculations have shown that depending on the chemical structure of the polymer, its intramolecular properties (e.g. ionization potential, electron affinity or intramolecular charge mobility) can be changed. To understand the effect of the intramolecular properties in the performance of polymer diodes we use a generalized dynamical Monte Carlo method that considers the nanostructure of the polymer layer and the main electronic processes involved in diode functioning. Our results show that the influence of the intramolecular properties on the electric behaviour of pristine polymer-diodes with ohmic contacts depends on the morphology of the polymer layer at nanoscale that can alter not only hole and electron current density for the same applied electric field but also charge density and charge distribution inside the polymer layer.Fundação para a Ciência e a Tecnologia (FCT) – POCTI/CTM/41574/2001; CONC-REEQ/443/EEI/2005; SFRH/BD/22143/2005FEDE

Modelling the effect of non-planarity on luminescence energy of conjugated polymers

We present theoretical investigations of structural and electronic properties of ground-state and low-lying excited singlet states in isolated chains of conjugated polymers using a self-consistent quantum molecular dynamics method. With this approach, we have determined the energy of both states as function of the twist angle between two planar segments of the same polymer chain, for polymer chains with variable length. The conjugated polymers investigated here are poly(para-phenylene vinylene) (PPV) and polydiacetylene (PDA). Our results show that the energy of the excited-state increases more than that of the ground-state, as the twist angle increases up to 90º degrees. The change in the twist angle of both polymers leads to a blueshift in luminescence transition energy, the effect being stronger in PPV when the planar segments have similar sizes. The predicted blueshift in both polymers is dependent on the chain length, the effect being more pronounced for shorter-chains.Comunidade Europeia (CE). Fundo Europeu de Desenvolvimento Regional (FEDER)Fundação para a Ciência e a Tecnologia (FCT) - Programa Operacional “Ciência , Tecnologia, Inovação” – POCTI/CTM/41574/2001, CONC-REEQ/443/2001 e SFRH/BD/11231/200

Avaliação da maturação em azeitona ‘Cobrançosa’ e ‘Galega Vulgar’ com recurso a diferentes metodologias baseadas na cor dos frutos

No presente trabalho estudaram-se três métodos de avaliação do estado de Maturação da azeitona, baseados na coloração dos frutos das cultivares ‘Cobrançosa’ e ‘Galega Vulgar’ em estados precoces de maturação, bem como a sua relação com a acumulação de gordura. Os métodos estudados foram: IM – índice de maturação de Jaén (com 8 grupos de cor); IMS – índice de maturação simplificado com apenas três classes de cor; CI – índice de cor (Colour Index) utilizando o Sistema CIE de cor L*a*b*. Os resultados obtidos revelaram que os índices de maturação baseados na cor dos frutos são úteis para caracterizar a evolução do teor em gordura durante a maturação da azeitona. O método simplificado apresentou uma elevada correlação com o índice de Jaén, sendo bastante mais rápido e de mais fácil utilização pelo olivicultor

Filme ativo com extrato de chá verde: eficácia contra a oxidação lipídica

As embalagens ativas têm como objetivo proteger e prolongar a vida útil dos alimentos, aumentando a sua qualidade, segurança e integridade. Na industria alimentar, este conceito de embalagem ativa foi aplicado como forma de controlar o fenomeno da oxidacao lipidica em alimentos com alto teor de gordura, sendo que esta e uma das principais causas de perda de qualidade destes alimentos. A composição química do chá verde tem revelado um grande interesse no que diz respeito a prevenção da oxidação lipídica. Na sua constituição, as folhas de chá verde possuem um teor elevado de compostos fenólicos, que tem sido associados a sua atividade antioxidante. Devido às suas propriedades, o chá verde e considerado um ótimo agente antioxidante natural. O poli (acido láctico) ou ácido poliláctico (PLA) e um polímero alifático cujo monómero e derivado de recursos renováveis, como amido de milho, raízes de tapioca e cana de açúcar. O polímero e formado através da fermentação de amido e condensação de ácido láctico. No presente estudo, fatias de salmão fumado foram embaladas com um filme de PLA, com extrato de chá verde incorporado em diferentes concentrações, 1% e 2%, e, posteriormente, armazenadas durante 7, 15, 30, 45 e 60 dias, em refrigeração. Um filme de PLA sem o extrato de chá verde foi usado como controlo. Para avaliar a eficácia do filme ativo contra a oxidação lipídica, utilizou-se o teste de Substancias Reativas ao Ácido Tiobarbiturico (TBARS). Este ensaio mede o conteudo de malonaldeido (MDA) que e formado durante a oxidação lipídica pela decomposição dos ácidos gordos polinsaturados em hidroperoxidos. Os resultados foram expressos em mg de MDA por kg de salmão fumado. Os resultados mostraram que as fatias de salmão fumado embaladas com o filme de PLA/chá verde apresentaram menor teor de MDA do que aquelas embaladas com o filme controlo. As fatias de salmão fumado embaladas com o PLA/chá verde2% apresentaram menor quantidade de MDA em todos os momentos de contacto, exceto apos 15 dias, onde se verificou menor teor de MDA nas fatias de salmão embaladas com o filme ativo com 1% de extrato de chá verde. Estes resultados mostraram que a incorporação do extrato de chá verde no PLA protege o salmão fumado da oxidação lipídica. Contudo, devem ser realizados estudos adicionais para confirmar a inibição da oxidação lipídica, como o índice de peróxido, o valor de p-anisidina e a determinação do hexanal.Este trabalho foi financiado pelo projeto de investigação “Development of methodologies for the evaluation of polymeric food packaging components and determination of their structural and mechanical properties (2016DAN 1289)” financiado pelo Instituto Nacional de Saúde Doutor Ricardo Jorge (INSA, I.P.). Mariana Andrade agradece a bolsa de investigação (2016/iFILM/BM) no âmbito do projeto iFILM.N/

Fine-Tuning Solution for Hybrid Inflation in Dissipative Chaotic Dynamics

We study the presence of chaotic behavior in phase space in the pre-inflationary stage of hybrid inflation models. This is closely related to the problem of initial conditions associated to these inflationary type of models. We then show how an expected dissipative dynamics of fields just before the onset of inflation can solve or ease considerably the problem of initial conditions, driving naturally the system towards inflation. The chaotic behavior of the corresponding dynamical system is studied by the computation of the fractal dimension of the boundary, in phase space, separating inflationary from non-inflationary trajectories. The fractal dimension for this boundary is determined as a function of the dissipation coefficients appearing in the effective equations of motion for the fields.Comment: 10 pages, 4 eps figures (uses epsf), Revtex. Replaced with version to match one in press Physical Review

Super-Hubbard models and applications

We construct XX- and Hubbard- like models based on unitary superalgebras gl(N|M) generalising Shastry's and Maassarani's approach of the algebraic case. We introduce the R-matrix of the gl(N|M) XX model and that of the Hubbard model defined by coupling two independent XX models. In both cases, we show that the R-matrices satisfy the Yang--Baxter equation, we derive the corresponding local Hamiltonian in the transfer matrix formalism and we determine the symmetry of the Hamiltonian. Explicit examples are worked out. In the cases of the gl(1|2) and gl(2|2) Hubbard models, a perturbative calculation at two loops a la Klein and Seitz is performed.Comment: 26 page

ARXPS analysis of a GaAs/GaInP heterointerface with application in III-V multijunction solar cells

In this contribution, angle-resolved X-ray photoelectron spectroscopy is used to explore the extension and nature of a GaAs/GaInP heterointerface. This bilayer structure constitutes a very common interface in a multilayered III-V solar cell. Our results show a wide indium penetration into the GaAs layer, while phosphorous diffusion is much less important. The physico-chemical nature of such interface and its depth could deleteriously impact the solar cell performance. Our results probe the formation of spurious phases which may profoundly affect the interface behavior